Articles | Volume 34, issue 3
https://doi.org/10.5194/ejm-34-285-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-34-285-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
11 May 2022
Research article |
| 11 May 2022
| 11 May 2022
Crystallographic orientation mapping of lizardite serpentinite by Raman spectroscopy
Matthew S. Tarling
CORRESPONDING AUTHOR
Department of Earth and Planetary Sciences, McGill University,
Montreal, Quebec, Canada
Department of Geology, University of Otago, Dunedin, New Zealand
Matteo Demurtas
Department of Earth Science, University of Bergen, Bergen, Norway
Steven A. F. Smith
Department of Geology, University of Otago, Dunedin, New Zealand
Jeremy S. Rooney
Department of Chemistry, University of Otago, Dunedin, New Zealand
Marianne Negrini
Department of Geology, University of Otago, Dunedin, New Zealand
Cecilia Viti
Dipartimento di Scienze Fisiche, della Terra e dell'Ambiente,
Università degli Studi di Siena, Siena, Italy
Jasmine R. Petriglieri
Department of Earth Sciences, Università di Torino, Torino,
Italy
Keith C. Gordon
Department of Chemistry, University of Otago, Dunedin, New Zealand
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Matthew S. Tarling, Steven A. F. Smith, James M. Scott, Jeremy S. Rooney, Cecilia Viti, and Keith C. Gordon
Solid Earth, 10, 1025–1047, https://doi.org/10.5194/se-10-1025-2019, https://doi.org/10.5194/se-10-1025-2019, 2019
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Shear zones dominated by hydrated mantle rocks (serpentinites) occur in many tectonic settings around the world. To better understand the internal structure, composition and possible mechanical behaviour of these shear zones, we performed a detailed field, petrological and microanalytical study of the Livingstone Fault in New Zealand. We propose a conceptual model to account for the main physical and chemical processes that control deformation in large serpentinite shear zones.
Matteo Demurtas, Steven A.F. Smith, Elena Spagnuolo, and Giulio Di Toro
Solid Earth, 12, 595–612, https://doi.org/10.5194/se-12-595-2021, https://doi.org/10.5194/se-12-595-2021, 2021
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We performed shear experiments on calcite–dolomite gouge mixtures to better understand the behaviour of carbonates during sub-seismic to seismic deformation in the shallow crust. The development of a foliation in the gouge was only restricted to coseismic sliding, whereas fluidisation occurred over a wide range of slip velocities (sub-seismic to coseismic) in the presence of water. These observations will contribute to a better interpretation of the rock record.
Morgan E. Monz, Peter J. Hudleston, David J. Prior, Zachary Michels, Sheng Fan, Marianne Negrini, Pat J. Langhorne, and Chao Qi
The Cryosphere, 15, 303–324, https://doi.org/10.5194/tc-15-303-2021, https://doi.org/10.5194/tc-15-303-2021, 2021
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We present full crystallographic orientations of warm, coarse-grained ice deformed in a shear setting, enabling better characterization of how crystals in glacial ice preferentially align as ice flows. A commonly noted c-axis pattern, with several favored orientations, may result from bias due to overcounting large crystals with complex 3D shapes. A new sample preparation method effectively increases the sample size and reduces bias, resulting in a simpler pattern consistent with the ice flow.
Sheng Fan, Travis F. Hager, David J. Prior, Andrew J. Cross, David L. Goldsby, Chao Qi, Marianne Negrini, and John Wheeler
The Cryosphere, 14, 3875–3905, https://doi.org/10.5194/tc-14-3875-2020, https://doi.org/10.5194/tc-14-3875-2020, 2020
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We performed uniaxial compression experiments on synthetic ice samples. We report ice microstructural evolution at –20 and –30 °C that has never been reported before. Microstructural data show the opening angle of c-axis cones decreases with increasing strain or with decreasing temperature, suggesting a more active grain rotation. CPO intensity weakens with temperature because CPO of small grains is weaker, and it can be explained by grain boundary sliding or nucleation with random orientations.
Matthew S. Tarling, Steven A. F. Smith, James M. Scott, Jeremy S. Rooney, Cecilia Viti, and Keith C. Gordon
Solid Earth, 10, 1025–1047, https://doi.org/10.5194/se-10-1025-2019, https://doi.org/10.5194/se-10-1025-2019, 2019
Short summary
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Shear zones dominated by hydrated mantle rocks (serpentinites) occur in many tectonic settings around the world. To better understand the internal structure, composition and possible mechanical behaviour of these shear zones, we performed a detailed field, petrological and microanalytical study of the Livingstone Fault in New Zealand. We propose a conceptual model to account for the main physical and chemical processes that control deformation in large serpentinite shear zones.
Chao Qi, David J. Prior, Lisa Craw, Sheng Fan, Maria-Gema Llorens, Albert Griera, Marianne Negrini, Paul D. Bons, and David L. Goldsby
The Cryosphere, 13, 351–371, https://doi.org/10.5194/tc-13-351-2019, https://doi.org/10.5194/tc-13-351-2019, 2019
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Ice deformed in nature develops crystallographic preferred orientations, CPOs, which induce an anisotropy in ice viscosity. Shear experiments of ice revealed a transition in CPO with changing temperature/strain, which is due to the change of dominant CPO-formation mechanism: strain-induced grain boundary migration dominates at higher temperatures and lower strains, while lattice rotation dominates at other conditions. Understanding these mechanisms aids the interpretation of CPOs in natural ice.
Jack N. Williams, Virginia G. Toy, Cécile Massiot, David D. McNamara, Steven A. F. Smith, and Steven Mills
Solid Earth, 9, 469–489, https://doi.org/10.5194/se-9-469-2018, https://doi.org/10.5194/se-9-469-2018, 2018
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We present new data on the orientation of fractures, their fill, and their density around the Alpine Fault, a plate boundary fault on the South Island of New Zealand. Fractures < 160 m of the fault are filled and show a range of orientations, whilst fractures at greater distances (< 500 m) are open and parallel to the rock's mechanical weakness. We interpret the latter fracture set to reflect near-surface processes, whilst the latter are potentially linked to deep-seated Alpine Fault seismicity.
Martina Kirilova, Virginia Toy, Jeremy S. Rooney, Carolina Giorgetti, Keith C. Gordon, Cristiano Collettini, and Toru Takeshita
Solid Earth, 9, 223–231, https://doi.org/10.5194/se-9-223-2018, https://doi.org/10.5194/se-9-223-2018, 2018
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Graphite crystallinity “irreversibly” increases with temperature and it has been calibrated as a thermometer recording peak temperatures experienced by a rock. To examine the possibility of mechanical modifications of graphite structure and the impacts on graphite thermometry we performed deformation experiments. Raman spectroscopy demonstrates a reduction in crystallinity due to mechanical reworking in the brittle field. This finding clearly compromises the validity of the graphite thermometry.
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Common energy dispersive methods cannot accurately analyze low concentrations of cobalt in pyrite due to the overlapping of cobalt and iron peaks. The Raman method, on the other hand, has been shown to be very sensitive to a trace amount of cobalt. In addition, it can be applied on a rough surface, does not require a vacuum chamber, and operates with a laser instead of X-rays. Thus, Raman has the potential to be used as an assaying tool for Co-bearing pyrite.
Yves Fuchs, Chloé Fourdrin, and Etienne Balan
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Information about the local structure of tourmaline-group minerals can be obtained from the characteristic OH stretching bands in their vibrational spectra. However, their assignment to specific atomic-scale environments is debated. We address this question theoretically by investigating a series of dravite models. Our results support a local role of cationic occupancies in determining the OH stretching frequencies and bring constraints for the interpretation of the vibrational spectra.
Etienne Balan, Emmanuel Fritsch, Guillaume Radtke, Lorenzo Paulatto, Farid Juillot, Fabien Baron, and Sabine Petit
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Interpretation of vibrational spectra of serpentines is complexified by the common occurrence of divalent and trivalent cationic impurities at tetrahedral and octahedral sites. We theoretically investigate the effect of Fe and Al on the vibrational properties of lizardite, focusing on the OH stretching modes. The results allow us to disentangle the specific effects related to the valence and coordination states of the impurities, supporting a detailed interpretation of the experimental spectra.
Emmanuel Fritsch, Etienne Balan, Sabine Petit, and Farid Juillot
Eur. J. Mineral., 33, 447–462, https://doi.org/10.5194/ejm-33-447-2021, https://doi.org/10.5194/ejm-33-447-2021, 2021
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The study provides new insights into the OH stretching vibrations of serpentine species (lizardite, chrysotile, antigorite) encountered in veins of peridotite. A combination of infrared spectroscopy in the mid-infrared and near-infrared ranges and Raman spectroscopy enabled us to interpret most of the observed bands in the fundamental and first overtone regions of the spectra and to propose consistent spectral decomposition and assignment of the OH stretching bands for the serpentine species.
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Unusually large lizardite (Lz) crystals from Monte Fico serpentinites, Elba (Mellini and Viti, 1994), have allowed several subsequent studies. During a µ-Raman study of serpentine minerals (Compagnoni et al., 2021), the careful microscopic examination of this Lz showed
spongymicrostructure. TEM observations confirmed that the Lz hosts voids, filled with chrysotile and polygonal serpentine; their mutual relationships indicate that Lz grew up with a skeletal habit and fibres epitactically.
Etienne Balan, Emmanuel Fritsch, Guillaume Radtke, Lorenzo Paulatto, Farid Juillot, and Sabine Petit
Eur. J. Mineral., 33, 389–400, https://doi.org/10.5194/ejm-33-389-2021, https://doi.org/10.5194/ejm-33-389-2021, 2021
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The infrared absorption spectrum of an antigorite sample, an important serpentine-group mineral, is compared to its theoretical counterpart computed at the density functional level. The model reproduces most of the observed bands, supporting their assignment to specific vibrational modes. The results provide robust interpretations of the significant differences observed between the antigorite spectrum and that of lizardite, the more symmetric serpentine variety.
Evgeniy Nikolaevich Kozlov, Ekaterina Nikolaevna Fomina, Vladimir Nikolaevich Bocharov, Mikhail Yurievich Sidorov, Natalia Sergeevna Vlasenko, and Vladimir Vladimirovich Shilovskikh
Eur. J. Mineral., 33, 283–297, https://doi.org/10.5194/ejm-33-283-2021, https://doi.org/10.5194/ejm-33-283-2021, 2021
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Carbonophosphates (sidorenkite, bonshtedtite, and bradleyite) with the general formula Na3MCO3PO4 (M is Mn, Fe, and Mg) are often found in inclusions of carbonatite and kimberlite minerals. This article presents the results of Raman spectroscopic study and a simple algorithm for diagnosing mineral phases of the carbonophosphate group. This work may be of interest both to researchers of carbonatites and/or kimberlites and to a wide range of specialists in the field of Raman spectroscopy.
Etienne Balan, Emmanuel Fritsch, Farid Juillot, Thierry Allard, and Sabine Petit
Eur. J. Mineral., 33, 209–220, https://doi.org/10.5194/ejm-33-209-2021, https://doi.org/10.5194/ejm-33-209-2021, 2021
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The OH overtone bands of kaolinite- and serpentine-group minerals observed in their near-infrared (NIR) spectra are widely used but their relation to stretching modes involving coupled OH groups is uncertain. Here, we map a molecular model of harmonically coupled anharmonic oscillators on the spectroscopic properties of 1:1 phyllosilicates. This makes it possible to interpret most of the observed bands and support the assignment of some of them to cationic substitutions in serpentines.
Etienne Balan, Lorenzo Paulatto, Jia Liu, and Jannick Ingrin
Eur. J. Mineral., 32, 505–520, https://doi.org/10.5194/ejm-32-505-2020, https://doi.org/10.5194/ejm-32-505-2020, 2020
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The atomic-scale geometry of hydrous defects in diopside is still imperfectly known despite their contribution to the Earth's water cycle. Their OH-stretching vibrations lead to a variety of infrared absorption bands. Low-temperature infrared spectroscopy makes it possible to resolve additional bands in the spectra of gem-quality natural samples. Theoretical results obtained at the density functional theory level support the assignment of the observed bands to specific atomic-scale models.
Nada Abdel-Hak, Bernd Wunder, Ilias Efthimiopoulos, and Monika Koch-Müller
Eur. J. Mineral., 32, 469–482, https://doi.org/10.5194/ejm-32-469-2020, https://doi.org/10.5194/ejm-32-469-2020, 2020
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The structural response of the NH4+ molecule to temperature and pressure changes is studied in ammonium phengite. The symmetry of the molecule is lowered by increasing P or decreasing T; the type and mechanism of this lowered symmetry is different in both cases. Devolatilisation (NH4+ and OH loss) of ammonium phengite is studied as well. This study confirms the wide stability range of phengite and its volatiles and thus has important implications for N and H recycling into the deep Earth.
Etienne Balan
Eur. J. Mineral., 32, 457–467, https://doi.org/10.5194/ejm-32-457-2020, https://doi.org/10.5194/ejm-32-457-2020, 2020
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Corundum is an important oxide mineral which can contain low amounts of hydrogen-bearing structural defects. These defects are observed by infrared spectroscopy, but their atomic-scale geometry is still uncertain. Here, a theoretical approach makes it possible to relate most of the observed infrared bands to specific atomic configurations, highlighting the key role of other chemical impurities and defect clustering in the high-temperature incorporation of hydrogen in corundum.
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Short summary
Rocks containing the serpentine mineral lizardite occur in many tectonic settings. Knowing the crystal orientation of lizardite in these rocks tells us how they deform and gives insights into their physical properties. The crystal orientation of lizardite is challenging to obtain using standard techniques. To overcome this challenge, we developed a method using Raman spectroscopy to map the crystal orientation of lizardite with minimal preparation on standard thin sections.
Rocks containing the serpentine mineral lizardite occur in many tectonic settings. Knowing the...
