Articles | Volume 36, issue 3
https://doi.org/10.5194/ejm-36-397-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/ejm-36-397-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
03 May 2024
Research article |
| 03 May 2024
| 03 May 2024
Kenoargentotetrahedrite-(Zn), [Ag6]4+(Cu4Zn2)Sb4S12□, a new member of the tetrahedrite group from the Yindongpo Au deposit, China
Tianjin Center, China Geological Survey, Tianjin, 300171, China
School of Earth Sciences and Engineering, Nanjing University, Nanjing, 210023, China
Xianzhang Sima
Tianjin Center, China Geological Survey, Tianjin, 300171, China
Xiangping Gu
School of Geosciences and Info-Physics, Central South University, Changsha, 410083, China
Weizhi Sun
No. 3 Institute of Geological and Mineral Resources Survey of Henan Geological Bureau, Xinyang, 464000, China
Guang Fan
Institute of Science and Technology Information, Beijing Research Institute of Uranium Geology, Beijing, 100029, China
Zeqiang Yang
No. 3 Institute of Geological and Mineral Resources Survey of Henan Geological Bureau, Xinyang, 464000, China
Yanjuan Wang
CORRESPONDING AUTHOR
School of Earth Sciences and Resources, China University of Geosciences, Beijing, 100083, China
Department of Geosciences, University of Padua, Padua, 35131, Italy
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Daniel Atencio, Andrezza A. Azzi, Kai Qu, Ritsuro Miyawaki, Ferdinando Bosi, and Koichi Momma
Eur. J. Mineral., 35, 1027–1030, https://doi.org/10.5194/ejm-35-1027-2023, https://doi.org/10.5194/ejm-35-1027-2023, 2023
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This article introduces a new nomenclature system for the cerite group minerals. This system was necessary to allow the nomenclature of new species of minerals that are currently being described.
Yanjuan Wang, Fabrizio Nestola, Huaikun Li, Zengqian Hou, Martha G. Pamato, Davide Novella, Alessandra Lorenzetti, Pia Antonietta Antignani, Paolo Cornale, Jacopo Nava, Guochen Dong, and Kai Qu
Eur. J. Mineral., 35, 361–372, https://doi.org/10.5194/ejm-35-361-2023, https://doi.org/10.5194/ejm-35-361-2023, 2023
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In this work we have applied the elastic geobarometry approach to a Chinese diamond in order to determine the depth of formation of an olivine-bearing diamond. Together with the temperature of residence at which the diamond resided in the mantle, we were able to discover that the diamond was formed at about 190 km depth. Beyond the geological meaning of our results, this work could be a reference paper for future works on Chinese diamonds using elastic geobarometry.
Yanjuan Wang, Fabrizio Nestola, Zengqian Hou, Xiangping Gu, Guochen Dong, Zhusen Yang, Guang Fan, Zhibin Xiao, and Kai Qu
Eur. J. Mineral., 35, 65–74, https://doi.org/10.5194/ejm-35-65-2023, https://doi.org/10.5194/ejm-35-65-2023, 2023
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Bobtraillite is an extremely rare cyclosilicate with a unique composition and complex structure. In this paper, we describe the second occurrence of the extremely rare complex zirconium silicate. The results suggest that the ideal formula of bobtraillite could be written as (Na, □)12(□, Na)12Sr12Zr14(Si3O9)10[Si2BO7(OH)2]6·12H2O.
Daniel Atencio, Andrezza A. Azzi, Kai Qu, Ritsuro Miyawaki, Ferdinando Bosi, and Koichi Momma
Eur. J. Mineral., 35, 1027–1030, https://doi.org/10.5194/ejm-35-1027-2023, https://doi.org/10.5194/ejm-35-1027-2023, 2023
Short summary
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This article introduces a new nomenclature system for the cerite group minerals. This system was necessary to allow the nomenclature of new species of minerals that are currently being described.
Yanjuan Wang, Fabrizio Nestola, Huaikun Li, Zengqian Hou, Martha G. Pamato, Davide Novella, Alessandra Lorenzetti, Pia Antonietta Antignani, Paolo Cornale, Jacopo Nava, Guochen Dong, and Kai Qu
Eur. J. Mineral., 35, 361–372, https://doi.org/10.5194/ejm-35-361-2023, https://doi.org/10.5194/ejm-35-361-2023, 2023
Short summary
Short summary
In this work we have applied the elastic geobarometry approach to a Chinese diamond in order to determine the depth of formation of an olivine-bearing diamond. Together with the temperature of residence at which the diamond resided in the mantle, we were able to discover that the diamond was formed at about 190 km depth. Beyond the geological meaning of our results, this work could be a reference paper for future works on Chinese diamonds using elastic geobarometry.
Yanjuan Wang, Fabrizio Nestola, Zengqian Hou, Xiangping Gu, Guochen Dong, Zhusen Yang, Guang Fan, Zhibin Xiao, and Kai Qu
Eur. J. Mineral., 35, 65–74, https://doi.org/10.5194/ejm-35-65-2023, https://doi.org/10.5194/ejm-35-65-2023, 2023
Short summary
Short summary
Bobtraillite is an extremely rare cyclosilicate with a unique composition and complex structure. In this paper, we describe the second occurrence of the extremely rare complex zirconium silicate. The results suggest that the ideal formula of bobtraillite could be written as (Na, □)12(□, Na)12Sr12Zr14(Si3O9)10[Si2BO7(OH)2]6·12H2O.
Related subject area
New minerals and systematic mineralogy
Dacostaite, K(Mg2Al)[Mg(H2O)6]2(AsO4)2F6 ⋅ 2H2O, a new fluoride–arsenate mineral from the Cetine di Cotorniano Mine (Tuscany, Italy)
Nannoniite, Al2(OH)5F, a new mineral from the Cetine di Cotorniano mine (Tuscany, Italy)
Karlseifertite, Pb(Ga2Ge)(AsO4)2(OH)6, a new dussertite-group mineral, from Tsumeb, Namibia
Bonacinaite, Sc(AsO4) ⋅ 2H2O, the first scandium arsenate
Lazerckerite, Ag3.75Pb4.5(Sb7.75Bi4)S24, from Kutná Hora, Czech Republic: a new Sb–Bi member of the andorite branch of the lillianite homologous series
Rotherkopfite, KNa2(Fe2+2.5Ti4+1.5)Fe2+(Si4O12)2, a new neptunite-group mineral without essential lithium, from Rother Kopf, Eifel volcanic fields, Germany
Zvěstovite-(Fe), Ag6(Ag4Fe2)As4S13, a new member of the tetrahedrite group from the Ulatayskoe Ag–Cu–Co occurrence, eastern Siberia, Russia
Fluor-rewitzerite, [(H2O)K]Mn2(Al2Ti)(PO4)4(OF)(H2O)10 ⋅ 4H2O, a new paulkerrite-group mineral, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany
Igelströmite, Fe3+(Sb3+Pb2+)O4, and manganoschafarzikite, Mn2+Sb3+2O4, two new members of the newly established minium group, from the Långban Mn–Fe deposit, Värmland, Sweden
Mckelveyite group minerals – Part 4: Alicewilsonite-(YLa), Na2Sr2YLa(CO3)6 ⋅ 3H2O, a new lanthanum-dominant species from the Paratoo mine, Australia
Macraeite, [(H2O)K]Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 ⋅ 4H2O, a new monoclinic paulkerrite-group mineral, from the Cubos–Mesquitela–Mangualde pegmatite, Portugal
Mckelveyite group minerals – Part 3: Bainbridgeite-(YCe), Na2Ba2YCe(CO3)6 ⋅ 3H2O, a new species from Mont Saint-Hilaire, Canada
Heimite, PbCu2(AsO4)(OH)3 ⋅ 2H2O, a new mineral from the Grosses Chalttal deposit, Switzerland
OxyEMG: an application for determination of the oxyspinel group end-members based on electron microprobe analyses
Changes to the cerite group nomenclature
Tetrahedrite-(Cd), Cu6(Cu4Cd2)Sb4S13, from Radětice near Příbram, Czech Republic: the new Cd member of the tetrahedrite group
Crystal chemistry of type paulkerrite and establishment of the paulkerrite group nomenclature
Regerite, KFe6(PO4)4(OH)7(H2O)6 ⋅ 4H2O, the first new mineral species from the Kreuzberg pegmatite, Pleystein, Oberpfalz, Bavaria, Germany
Batoniite, [Al8(OH)14(H2O)18](SO4)5 ⋅ 5H2O, a new mineral with the [Al8(OH)14(H2O)18]10+ polyoxocation from the Cetine di Cotorniano Mine, Tuscany, Italy
Hochleitnerite, [K(H2O)]Mn2(Ti2Fe)(PO4)4O2(H2O)10 ⋅ 4H2O, a new paulkerrite-group mineral, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany
Nomenclature of the triphylite group of minerals
Pseudo-cubic trigonal pyrite from the Madan Pb–Zn ore field (Rhodope Massif, Bulgaria): morphology and twinning
Manganrockbridgeite, Mn2+2Fe3+3(PO4)3(OH)4(H2O), a new member of the rockbridgeite group, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria
Pleysteinite, [(H2O)0.5K0.5]2Mn2Al3(PO4)4F2(H2O)10 ⋅ 4H2O, the Al analogue of benyacarite, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany
Mckelveyite group minerals – Part 1: Nomenclature and new data on donnayite-(Y)
Mckelveyite group minerals – Part 2: Alicewilsonite-(YCe), Na2Sr2YCe(CO3)6 ⋅ 3H2O, a new species
Whiteite-(CaMnFe), a new jahnsite-group mineral from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria
Dutrowite, Na(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3O, a new mineral from the Apuan Alps (Tuscany, Italy): the first member of the tourmaline supergroup with Ti as a species-forming chemical constituent
Corresponding relationship between characteristic birefringence, strain, and impurities in Zimbabwean mixed-habit diamonds revealed by mapping techniques
TotBlocks: exploring the relationships between modular rock-forming minerals with 3D-printed interlocking brick modules
Ferri-taramite, a new member of the amphibole supergroup, from the Jakobsberg Mn–Fe deposit, Värmland, Sweden
Ferro-ferri-holmquistite, □Li2(Fe2+3Fe3+2)Si8O22(OH)2, Fe2+Fe3+ analogue of holmquistite, from the Iwagi islet, Ehime, Japan
Tomsquarryite, NaMgAl3(PO4)2(OH)6 ● 8H2O, a new crandallite-derivative mineral from Tom's phosphate quarry, Kapunda, South Australia
Graulichite-(La), LaFe3+3(AsO4)2(OH)6, a new addition to the alunite supergroup from the Patte d'Oie mine, Bou Skour mining district, Morocco
Arrojadite-group nomenclature: sigismundite reinstated
Redefinition of beraunite, Fe3+6(PO4)4O(OH)4 ⋅ 6H2O, and discreditation of the name eleonorite: a re-investigation of type material from the Hrbek Mine (Czech Republic)
Redefinition of angastonite, CaMgAl2(PO4)2(OH)4 ⋅ 7H2O, as an amorphous mineral
Liguowuite, WO3, a new member of the A-site vacant perovskite type minerals from the Panzhihua–Xichang region, China
Zinkgruvanite, Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2, a new ericssonite-group mineral from the Zinkgruvan Zn-Pb-Ag-Cu deposit, Askersund, Örebro County, Sweden
Kahlenbergite KAl11O17, a new β-alumina mineral and Fe-rich hibonite from the Hatrurim Basin, the Negev desert, Israel
Occurrence of silesiaite, a new calcium–iron–tin sorosilicate in the calcic skarn of El Valle-Boinás, Asturias, Spain
Grimmite, NiCo2S4, a new thiospinel from Příbram, Czech Republic
Freitalite, C14H10, a new aromatic hydrocarbon mineral from Freital, Saxony, Germany
Gobelinite, the Co analogue of ktenasite from Cap Garonne, France, and Eisenzecher Zug, Germany
Two new minerals, badengzhuite, TiP, and zhiqinite, TiSi2, from the Cr-11 chromitite orebody, Luobusa ophiolite, Tibet, China: is this evidence for super-reduced mantle-derived fluids?
Wumuite (KAl0.33W2.67O9) – a new mineral with an HTB-type structure from the Panzhihua–Xichang region in China
Luxembourgite, AgCuPbBi4Se8, a new mineral species from Bivels, Grand Duchy of Luxembourg
Niasite and johanngeorgenstadtite, Ni2+4.5(AsO4)3 dimorphs from Johanngeorgenstadt, Germany
Laurentthomasite, Mg2K(Be2Al)Si12O30: a new milarite-group-type member from the Ihorombe region, Fianarantsoa Province, Madagascar
Tancaite-(Ce), ideally FeCe(MoO4)3 ● 3H2O: description and average crystal structure
Cristian Biagioni, Daniela Mauro, Jiří Sejkora, Zdeněk Dolníček, Andrea Dini, and Radek Škoda
Eur. J. Mineral., 37, 39–52, https://doi.org/10.5194/ejm-37-39-2025, https://doi.org/10.5194/ejm-37-39-2025, 2025
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Dacostaite is a new fluoride–arsenate mineral found in the Sb(Au) deposit of the Cetine di Cotorniano Mine (Tuscany, Italy). It shows a novel crystal structure formed by heteropolyhedral layers and isolated Mg(H2O)6 groups connected by H bonds. The heteropolyhedral layers are similar to those occurring in alunite-supergroup minerals, and this is a further example of the ability of nature to use similar modules in forming the large number of currently known structural arrangements.
Cristian Biagioni, Enrico Mugnaioli, Sofia Lorenzon, Daniela Mauro, Silvia Musetti, Jiří Sejkora, Donato Belmonte, Nicola Demitri, and Zdeněk Dolníček
Eur. J. Mineral., 36, 1011–1022, https://doi.org/10.5194/ejm-36-1011-2024, https://doi.org/10.5194/ejm-36-1011-2024, 2024
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Nannoniite, Al2(OH)5F, is a new mineral species discovered in the Cetine di Cotorniano mine (Tuscany, Italy). Its description was possible through a multi-technique approach, and its crystal structure was solved through three-dimensional electron diffraction, revealing close relations with gibbsite. The partial replacement of (OH) by F induces subtle by detectable structural changes. This study reveals that Al hydroxides could be a source of F in geological environments.
Anthony R. Kampf, Joy Désor, and Chi Ma
Eur. J. Mineral., 36, 873–878, https://doi.org/10.5194/ejm-36-873-2024, https://doi.org/10.5194/ejm-36-873-2024, 2024
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Karlseifertite is a new member of the dussertite group of the alunite supergroup from Tsumeb, Namibia. It is the first member of the dussertite group to be described based upon valency-imposed double site occupancy in the octahedrally coordinated cation site. It is also the first member of the alunite supergroup containing essential Ge.
Marco E. Ciriotti, Uwe Kolitsch, Fernando Cámara, Pietro Vignola, Frédéric Hatert, Erica Bittarello, Roberto Bracco, and Giorgio Maria Bortolozzi
Eur. J. Mineral., 36, 863–872, https://doi.org/10.5194/ejm-36-863-2024, https://doi.org/10.5194/ejm-36-863-2024, 2024
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The article provides the standard description of bonacinaite, Sc3+(AsO4)·2H2O, the first natural scandium arsenate. The new mineral species was found in a few specimens in the dumps of the old Varenche Mine, Valle d'Aosta, Italy, which is therefore the type locality and the only locality in the world. Bonacinaite forms colourless (with faint to distinct violet tints), pseudohexagonal, thick tabular crystals, up to 0.25 mm in size, or as small, faintly violet lath-shaped crystals.
Richard Pažout, Michal Dušek, Jiří Sejkora, Jakub Plášil, Gheorghe Ilinca, and Zdeněk Dolníček
Eur. J. Mineral., 36, 641–656, https://doi.org/10.5194/ejm-36-641-2024, https://doi.org/10.5194/ejm-36-641-2024, 2024
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A new sulfosalt mineral species, lazerckerite, Ag3.7Pb4.6(Sb7.9Bi3.8)Σ11.7S24, has been found, identified, structurally solved, and approved by the IMA. The mineral belongs to the Sb–Bi mixed members of the andorite branch of the lillianite homologous series. The description and characterization of the mineral are presented, and the ways of distinguishing the mineral from other similar members of the group on the basis of chemical results are explained.
Anthony R. Kampf, Gerhard Möhn, Chi Ma, George R. Rossman, Joy Désor, and Yunbin Guan
Eur. J. Mineral., 36, 605–614, https://doi.org/10.5194/ejm-36-605-2024, https://doi.org/10.5194/ejm-36-605-2024, 2024
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Rotherkopfite is the first member of the neptunite group that does not contain lithium in its chemical formula. It was found at Rother Kopf, Eifel volcanic fields, Germany, where in occurs in cavities in a quartz–sanidine fragment embedded in a volcanic rock. Rotherkopfite occurs as dark brownish-red crystals, up to about 0.2 mm across. The intriguing crystal structure is based on two interwoven three-dimensional frameworks.
Cristian Biagioni, Anatoly V. Kasatkin, Fabrizio Nestola, Radek Škoda, Vladislav V. Gurzhiy, Atali A. Agakhanov, and Natalia N. Koshlyakova
Eur. J. Mineral., 36, 529–540, https://doi.org/10.5194/ejm-36-529-2024, https://doi.org/10.5194/ejm-36-529-2024, 2024
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Zvěstovite-(Fe) is a new, Ag-rich, member of the tetrahedrite group, the most widespread sulfosalts in ore deposits. Its discovery stresses the chemical variability of this mineral group, allowing for a better understanding of the structural plasticity of these compounds, which are able to host a plethora of different elements typical of hydrothermal environments.
Rupert Hochleitner, Ian E. Grey, Anthony R. Kampf, Stephanie Boer, Colin M. MacRae, William G. Mumme, and Nicholas C. Wilson
Eur. J. Mineral., 36, 541–554, https://doi.org/10.5194/ejm-36-541-2024, https://doi.org/10.5194/ejm-36-541-2024, 2024
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The paper describes the characterisation of fluor-rewitzerite, a new mineral species belonging to the paulkerrite group. The crystal structure of fluor-rewitzerite has been refined using microfocus synchrotron diffraction data, which allowed 25 of the possible 30 H atoms to be located, thus establishing key features of the H bonding. Crystallochemical trends are reviewed for seven recently characterised monoclinic paulkerrite-group minerals.
Dan Holtstam, Jörgen Langhof, Henrik Friis, Andreas Karlsson, and Muriel Erambert
Eur. J. Mineral., 36, 311–322, https://doi.org/10.5194/ejm-36-311-2024, https://doi.org/10.5194/ejm-36-311-2024, 2024
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We described two new minerals, igelströmite and manganoschafarzikite, from the Långban manganese–iron deposit in Värmland, Sweden. The chemical formulae are Fe3+(Sb3+Pb2+)O4 and Mn2+Sb3+2O4, respectively. They belong to a new mineral group, where all members have the same crystal structure. It is called the minium group, after the lead-oxide mineral that is the oldest known substance of this kind.
Inna Lykova, Ralph Rowe, Glenn Poirier, Henrik Friis, and Kate Helwig
Eur. J. Mineral., 36, 301–310, https://doi.org/10.5194/ejm-36-301-2024, https://doi.org/10.5194/ejm-36-301-2024, 2024
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The first lanthanum-dominant mckelveyite group mineral, alicewilsonite-(YLa), Na2Sr2YLa(CO3)6∙3H2O, was found at the Paratoo copper mine, South Australia, Australia.
Ian E. Grey, Christian Rewitzer, Rupert Hochleitner, Anthony R. Kampf, Stephanie Boer, William G. Mumme, and Nicholas C. Wilson
Eur. J. Mineral., 36, 267–278, https://doi.org/10.5194/ejm-36-267-2024, https://doi.org/10.5194/ejm-36-267-2024, 2024
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Macraeite is the fourth type mineral to be described from the Mangualde pegmatite, Portugal, and is the first paulkerrite-group mineral to be characterised from the locality. Its crystal structure has been refined using synchrotron diffraction data, and its chemical analysis, Raman spectrum, and optical properties are reported.
Inna Lykova, Ralph Rowe, Glenn Poirier, Henrik Friis, and Kate Helwig
Eur. J. Mineral., 36, 183–194, https://doi.org/10.5194/ejm-36-183-2024, https://doi.org/10.5194/ejm-36-183-2024, 2024
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The new mckelveyite group mineral bainbridgeite-(YCe) was found at Mont Saint-Hilaire, Quebec, Canada.
Thomas Malcherek, Boriana Mihailova, Jochen Schlüter, Philippe Roth, and Nicolas Meisser
Eur. J. Mineral., 36, 153–164, https://doi.org/10.5194/ejm-36-153-2024, https://doi.org/10.5194/ejm-36-153-2024, 2024
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The new mineral heimite was originally discovered on the mine dumps of the Grosses Chalttal deposit, Mürtschenalp district, Glarus, Switzerland. Its relatively simple chemistry is formed by water and ions of lead, copper, arsenic, hydrogen and oxygen. The mineral's crystal structure is related to the well-known duftite, which is also observed to grow on crystals of heimite. While heimite has so far only been found in the central Alps, it is expected to occur in other copper deposits worldwide.
Gabriela R. Ferracutti, Lucía M. Asiain, Antonella S. Antonini, Juan E. Tanzola, and M. Luján Ganuza
Eur. J. Mineral., 36, 87–98, https://doi.org/10.5194/ejm-36-87-2024, https://doi.org/10.5194/ejm-36-87-2024, 2024
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The paper proposes an application called OxyEMG (Oxyspinel group End-Member Generator), which is an improved version of EMG. This tool allows for calculating the portions of 31 end-members of the oxyspinel group from data obtained with an electron microprobe. This is fundamental since this group of minerals is considered to be tectonic tracers; their integral composition should be taken into account and not only those end-members that make up the magnetite or ulvöspinel prisms.
Daniel Atencio, Andrezza A. Azzi, Kai Qu, Ritsuro Miyawaki, Ferdinando Bosi, and Koichi Momma
Eur. J. Mineral., 35, 1027–1030, https://doi.org/10.5194/ejm-35-1027-2023, https://doi.org/10.5194/ejm-35-1027-2023, 2023
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This article introduces a new nomenclature system for the cerite group minerals. This system was necessary to allow the nomenclature of new species of minerals that are currently being described.
Jiří Sejkora, Cristian Biagioni, Pavel Škácha, Silvia Musetti, Anatoly V. Kasatkin, and Fabrizio Nestola
Eur. J. Mineral., 35, 897–907, https://doi.org/10.5194/ejm-35-897-2023, https://doi.org/10.5194/ejm-35-897-2023, 2023
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We present the description of new mineral – a Cd-dominant member of the tetrahedrite group, tetrahedrite-(Cd), from the Radětice deposit near Příbram, Czech Republic. All necessary data including crystal structure were successfully determined, and the mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (number 2022-115).
Ian E. Grey, Stephanie Boer, Colin M. MacRae, Nicholas C. Wilson, William G. Mumme, and Ferdinando Bosi
Eur. J. Mineral., 35, 909–919, https://doi.org/10.5194/ejm-35-909-2023, https://doi.org/10.5194/ejm-35-909-2023, 2023
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The paper describes the formal establishment of the paulkerrite group of minerals and its nomenclature. It includes the application of a site-merging procedure, coupled with a site-total-charge analysis, to obtain unambiguous end-member formulae. Application of the procedure has resulted in the revision of the end-member formulae for several of the group members.
Christian Rewitzer, Rupert Hochleitner, Ian E. Grey, Anthony R. Kampf, Stephanie Boer, and Colin M. MacRae
Eur. J. Mineral., 35, 805–812, https://doi.org/10.5194/ejm-35-805-2023, https://doi.org/10.5194/ejm-35-805-2023, 2023
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Regerite is the first new mineral species to be described from the Kreuzberg pegmatite, Pleystein, in the Oberpfalz, Bavaria. It has been characterised using electron microprobe analysis, Raman spectroscopy, optical measurements and a synchrotron-based single-crystal structure refinement. The structure type for regerite has not been previously reported.
Daniela Mauro, Cristian Biagioni, Jiří Sejkora, Zdeněk Dolníček, and Radek Škoda
Eur. J. Mineral., 35, 703–714, https://doi.org/10.5194/ejm-35-703-2023, https://doi.org/10.5194/ejm-35-703-2023, 2023
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Batoniite is a new mineral species belonging to the Al2O3–SO3–H2O ternary system, first found in the Cetine di Cotorniano Mine (Tuscany, Italy). This hydrated Al sulfate shows a novel crystal structure, characterized by Al octamers, so far reported in only synthetic compounds.
Ian E. Grey, Erich Keck, Anthony R. Kampf, Colin M. MacRae, Robert W. Gable, William G. Mumme, Nicholas C. Wilson, Alexander M. Glenn, and Cameron Davidson
Eur. J. Mineral., 35, 635–643, https://doi.org/10.5194/ejm-35-635-2023, https://doi.org/10.5194/ejm-35-635-2023, 2023
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Hochleitnerite is a new member of the paulkerrite group of minerals. Its crystal structure, chemical analyses and Raman spectroscopy are reported, and its crystallochemical properties are discussed in relation to other group members.
Lyudmila M. Lyalina, Ekaterina A. Selivanova, and Frédéric Hatert
Eur. J. Mineral., 35, 427–437, https://doi.org/10.5194/ejm-35-427-2023, https://doi.org/10.5194/ejm-35-427-2023, 2023
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There are unresolved problems related to the nomenclature and identification of mineral species belonging to the triphylite group of minerals. They can be solved by discarding the traditional views on succession of mineral species during oxidation. In other words, it is necessary to separate the concepts of the origin of the mineral and the boundaries of the species.
Yves Moëlo
Eur. J. Mineral., 35, 333–346, https://doi.org/10.5194/ejm-35-333-2023, https://doi.org/10.5194/ejm-35-333-2023, 2023
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Pyrite crystals with rhombohedral morphology have been known for a long time and were considered up to now as curiosities. The morphological study of well-crystallized, centimeter-sized crystals, often twinned, from the Madan Pb–Zn ore field permitted us to define such a pyrite variety as a pseudo-cubic trigonal derivative of pyrite.
Ian E. Grey, Rupert Hochleitner, Anthony R. Kampf, Stephanie Boer, Colin M. MacRae, John D. Cashion, Christian Rewitzer, and William G. Mumme
Eur. J. Mineral., 35, 295–304, https://doi.org/10.5194/ejm-35-295-2023, https://doi.org/10.5194/ejm-35-295-2023, 2023
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Manganrockbridgeite, Mn2+2Fe3+3(PO4)3(OH)4(H2O), a new member of the rockbridgeite group, has been characterised using electron microprobe analyses, Mössbauer spectroscopy, optical properties and single-crystal X-ray diffraction. Whereas other rockbridgeite-group minerals have orthorhombic symmetry with a statistical distribution of 50%Fe3+/50% vacancies in M3-site octahedra, monoclinic manganrockbridgeite has full ordering of Fe3+ and vacancies in alternate M3 sites along the 5.2 Å axis.
Ian E. Grey, Rupert Hochleitner, Christian Rewitzer, Anthony R. Kampf, Colin M. MacRae, Robert W. Gable, William G. Mumme, Erich Keck, and Cameron Davidson
Eur. J. Mineral., 35, 189–197, https://doi.org/10.5194/ejm-35-189-2023, https://doi.org/10.5194/ejm-35-189-2023, 2023
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Pleysteinite has been approved as a new mineral species, and we describe here the characterisation of the mineral and its relationship to related minerals benyacarite, paulkerrite and mantienneite. The characterisation includes the determination and refinement of the crystal structure, electron microprobe analyses, optical properties and interpretation of its Raman spectrum.
Inna Lykova, Ralph Rowe, Glenn Poirier, Gerald Giester, Kelsie Ojaste, and Henrik Friis
Eur. J. Mineral., 35, 133–142, https://doi.org/10.5194/ejm-35-133-2023, https://doi.org/10.5194/ejm-35-133-2023, 2023
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A new mineral group – the mckelveyite group – consisting of seven carbonate minerals was established. One of the seven members, donnayite-(Y), was re-investigated and its belonging to the mckelveyite group was confirmed.
Inna Lykova, Ralph Rowe, Glenn Poirier, Henrik Friis, and Kate Helwig
Eur. J. Mineral., 35, 143–155, https://doi.org/10.5194/ejm-35-143-2023, https://doi.org/10.5194/ejm-35-143-2023, 2023
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Alicewilsonite-(YCe), a new mckelveyite group, was found at Mont Saint-Hilaire, Quebec, Canada, and subsequently at the Saint-Amable sill, Quebec, Canada, and the Khibiny Massif, Kola Peninsula, Russia.
Rupert Hochleitner, Christian Rewitzer, Ian E. Grey, William G. Mumme, Colin M. MacRae, Anthony R. Kampf, Erich Keck, Robert W. Gable, and Alexander M. Glenn
Eur. J. Mineral., 35, 95–103, https://doi.org/10.5194/ejm-35-95-2023, https://doi.org/10.5194/ejm-35-95-2023, 2023
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The paper gives a characterisation of the new mineral species, whiteite-(CaMnFe), which has recently been approved as a new mineral (proposal IMA2022-077). The study included a single-crystal structure refinement that, when combined with electron microprobe analyses, confirmed that the mineral was a new member of the whiteite subgroup of the jahnsite group of minerals. Relationships between the crystal structure and the unit-cell parameters for the whiteite-subgroup minerals are discussed.
Cristian Biagioni, Ferdinando Bosi, Daniela Mauro, Henrik Skogby, Andrea Dini, and Federica Zaccarini
Eur. J. Mineral., 35, 81–94, https://doi.org/10.5194/ejm-35-81-2023, https://doi.org/10.5194/ejm-35-81-2023, 2023
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Dutrowite is the first tourmaline supergroup minerals having Ti as a species-defining chemical constituent. Its finding improves our knowledge on the crystal chemistry of this important mineral group and allows us to achieve a better picture of the mechanisms favouring the incorporation of Ti.
Chengyang Sun, Taijin Lu, Mingyue He, Zhonghua Song, and Yi Deng
Eur. J. Mineral., 34, 539–547, https://doi.org/10.5194/ejm-34-539-2022, https://doi.org/10.5194/ejm-34-539-2022, 2022
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It was determined that growth bands showing the straight birefringence in octahedral sectors and the enrichment of graphite inclusions in cuboid sectors of Zimbabwean mixed-habit diamonds may both be due to the fluctuation of temperature during crystallization, and they displayed positive anomalies of plastic deformation, residual stress, nitrogen concentration, and VN3H defects. This conclusion clearly revealed the correlation between birefringence and spectroscopic properties of diamonds.
Derek D. V. Leung and Paige E. dePolo
Eur. J. Mineral., 34, 523–538, https://doi.org/10.5194/ejm-34-523-2022, https://doi.org/10.5194/ejm-34-523-2022, 2022
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Minerals have complex crystal structures, but many common minerals are built from the same chemical building blocks. TotBlocks is a novel, open-source tool for investigating these structures. It consists of 3D-printed modules representing the silica tetrahedra and metal–oxygen octahedra that form the shared chemical building blocks of rock-forming minerals. TotBlocks is a low-cost visualization tool that relates mineral properties (habit, cleavage, and symmetry) to crystal structures.
Dan Holtstam, Fernando Cámara, Andreas Karlsson, Henrik Skogby, and Thomas Zack
Eur. J. Mineral., 34, 451–462, https://doi.org/10.5194/ejm-34-451-2022, https://doi.org/10.5194/ejm-34-451-2022, 2022
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A new mineral has been discovered, an amphibole, with the name ferri-taramite, which has now been approved by the International Mineralogical Association. The paper discusses the significance of the discovery in relation to other amphiboles found worldwide. This taramite is unique in that it is from a skarn associated with ore and is not of magmatic origin. For the description we have used many methods, including X-ray diffraction, chemical analyses and several types of spectroscopy.
Mariko Nagashima, Teruyoshi Imaoka, Takashi Kano, Jun-ichi Kimura, Qing Chang, and Takashi Matsumoto
Eur. J. Mineral., 34, 425–438, https://doi.org/10.5194/ejm-34-425-2022, https://doi.org/10.5194/ejm-34-425-2022, 2022
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Ferro-ferri-holmquistite (IMA2022-020), ideal formula ☐Li2(Fe32+Fe23+)Si8O22(OH)2, was found in albitized granite from the Iwagi islet, Ehime, Japan. It is a Fe2+Fe3+ analogue of holmquistite and belongs to the lithium subgroup amphiboles. Ferro-ferri-holmquistite occurs as blue acicular crystals typically replacing the biotite and is the product of metasomatic mineral replacement reactions by dissolution–reprecipitation processes associated with Na- and Li-rich hydrothermal fluids.
Peter Elliott, Ian E. Grey, William G. Mumme, Colin M. MacRae, and Anthony R. Kampf
Eur. J. Mineral., 34, 375–383, https://doi.org/10.5194/ejm-34-375-2022, https://doi.org/10.5194/ejm-34-375-2022, 2022
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This paper describes the characterisation of a new mineral from a South Australian phosphate quarry. The characterisation included chemical analyses, infrared spectroscopy, and a determination and refinement of the crystal structure. The results showed that the mineral has a unique crystal chemistry, but it is closely related to the well-known phosphate mineral crandallite.
Cristian Biagioni, Marco E. Ciriotti, Georges Favreau, Daniela Mauro, and Federica Zaccarini
Eur. J. Mineral., 34, 365–374, https://doi.org/10.5194/ejm-34-365-2022, https://doi.org/10.5194/ejm-34-365-2022, 2022
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The paper reports the type description of the new mineral species graulichite-(La). This is a new addition to the dussertite group within the alunite supergroup, and its discovery improves our knowledge on the crystal chemistry of this important supergroup of minerals, having both technological and environmental applications.
Frank de Wit and Stuart J. Mills
Eur. J. Mineral., 34, 321–324, https://doi.org/10.5194/ejm-34-321-2022, https://doi.org/10.5194/ejm-34-321-2022, 2022
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The name sigismundite has been reinstated for what was previously arrojadite-(BaFe). Sigismundite honours Pietro Sigismund (1874–1962), and this paper outlines his significant contributions to Italian mineralogy.
Luboš Vrtiška, Jaromír Tvrdý, Jakub Plášil, Jiří Sejkora, Radek Škoda, Nikita V. Chukanov, Andreas Massanek, Jan Filip, Zdeněk Dolníček, and František Veselovský
Eur. J. Mineral., 34, 223–238, https://doi.org/10.5194/ejm-34-223-2022, https://doi.org/10.5194/ejm-34-223-2022, 2022
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The study of the original material of beraunite from the type locality Hrbek, Czech Rep., from collections of the TU Bergakademie Freiberg (Germany) and National Museum Prague (Czech Republic) proved the identity of the minerals beraunite and eleonorite. Because the name beraunite has priority, we consider the name eleonorite to be redundant and proposed to abolish it. The proposal 21-D approved by the IMA discredited eleonorite and accepted the formula of beraunite Fe3+6(PO4)4O(OH)4·6H2O.
Ian Edward Grey, Peter Elliott, William Gus Mumme, Colin M. MacRae, Anthony R. Kampf, and Stuart J. Mills
Eur. J. Mineral., 34, 215–221, https://doi.org/10.5194/ejm-34-215-2022, https://doi.org/10.5194/ejm-34-215-2022, 2022
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A reinvestigation of angastonite from the type locality has shown that it is a mixture of crystalline phases and an amorphous phase, with the published formula corresponding to the amorphous phase. A redefinition proposal for angastonite as an amorphous mineral was approved by the IMA CNMNC. Our study showed how the amorphous phase formed and how it progressively recrystallises as new crandallite-related minerals.
Yuan Xue, Ningyue Sun, Hongping He, Aiqing Chen, and Yiping Yang
Eur. J. Mineral., 34, 95–108, https://doi.org/10.5194/ejm-34-95-2022, https://doi.org/10.5194/ejm-34-95-2022, 2022
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Liguowuite, a new member of the non-stoichiometric perovskite group minerals, ideally WO3, has been found in the Panzhihua–Xichang region, China. Liguowuite is monoclinic and is in space group P21 / n, with a = 7.32582(18) Å, b = 7.54767(18) Å, c = 7.71128(18) Å, β = 90.678(3)°, V = 426.348(19) Å3, and Z = 8. According to the hierarchical scheme for perovskite supergroup minerals, liguowuite is the first reported example of A-site vacant single oxide, i.e., a new perovskite subgroup.
Fernando Cámara, Dan Holtstam, Nils Jansson, Erik Jonsson, Andreas Karlsson, Jörgen Langhof, Jaroslaw Majka, and Anders Zetterqvist
Eur. J. Mineral., 33, 659–673, https://doi.org/10.5194/ejm-33-659-2021, https://doi.org/10.5194/ejm-33-659-2021, 2021
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Zinkgruvanite, a barium manganese iron silicate with sulfate, is a new mineral found in drill core samples from the Zinkgruvan zinc, lead and silver mine in Sweden. It is associated with other minerals like baryte, barytocalcite, diopside and sulfide minerals. It occurs as flattened and elongated crystals up to 1 mm. It is almost black. Zinkgruvanite is closely related to the mineral yoshimuraite and based on its crystal structure, grouped with the ericssonite group of minerals.
Biljana Krüger, Evgeny V. Galuskin, Irina O. Galuskina, Hannes Krüger, and Yevgeny Vapnik
Eur. J. Mineral., 33, 341–355, https://doi.org/10.5194/ejm-33-341-2021, https://doi.org/10.5194/ejm-33-341-2021, 2021
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This is the first description of the new mineral kahlenbergite, found in the Hatrurim Basin, Israel, which is a region with unusual pyrometamorphic rocks. Kahlenbergite is chemically and structurally characterized. It is very similar to β-alumina compounds, which are synthetic materials known for their properties as fast ion conductors. Research in the Hatrurim Basin is needed to understand the complex mechanisms that created this mineralogically diverse
hotspotof new minerals.
Antonia Cepedal, Mercedes Fuertes-Fuente, and Agustín Martin-Izard
Eur. J. Mineral., 33, 165–174, https://doi.org/10.5194/ejm-33-165-2021, https://doi.org/10.5194/ejm-33-165-2021, 2021
Pavel Škácha, Jiří Sejkora, Jakub Plášil, Zdeněk Dolníček, and Jana Ulmanová
Eur. J. Mineral., 33, 175–187, https://doi.org/10.5194/ejm-33-175-2021, https://doi.org/10.5194/ejm-33-175-2021, 2021
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Grimmite, sulfide of cobalt and nickel, is the new mineral for the mineralogical system.
Thomas Witzke, Martin Schreyer, Benjamin Brandes, René Csuk, and Herbert Pöllmann
Eur. J. Mineral., 33, 1–8, https://doi.org/10.5194/ejm-33-1-2021, https://doi.org/10.5194/ejm-33-1-2021, 2021
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The new mineral species freitalite, C14H10, corresponding to the aromatic hydrocarbon anthracene, has been discovered on the mine dump of the Königin Carola shaft (Paul Berndt Mine), Freital, near Dresden, Saxony, Germany. Freitalite is a product of pyrolysis of coal and was formed by sublimation from a gas phase. The mineral was identified by several analytical methods.
Stuart J. Mills, Uwe Kolitsch, Georges Favreau, William D. Birch, Valérie Galea-Clolus, and Johannes Markus Henrich
Eur. J. Mineral., 32, 637–644, https://doi.org/10.5194/ejm-32-637-2020, https://doi.org/10.5194/ejm-32-637-2020, 2020
Fahui Xiong, Xiangzhen Xu, Enrico Mugnaioli, Mauro Gemmi, Richard Wirth, Edward S. Grew, Paul T. Robinson, and Jingsui Yang
Eur. J. Mineral., 32, 557–574, https://doi.org/10.5194/ejm-32-557-2020, https://doi.org/10.5194/ejm-32-557-2020, 2020
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Two new nanominerals: titanium monophosphide and titanium disilicide, formed at pressures of Earth’s upper mantle by the action of methane and hydrogen from the mantle on basaltic melts in the Luobusa ophiolite (Tibet). The minerals were characterized by 3D electron diffraction, which can solve the crystal structures of phases less than a micrometer in size. The results contribute to our understanding of deeply subducted crustal rocks and their exhumation back to the Earth's surface.
Yuan Xue, Guowu Li, and Yingmei Xie
Eur. J. Mineral., 32, 483–494, https://doi.org/10.5194/ejm-32-483-2020, https://doi.org/10.5194/ejm-32-483-2020, 2020
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Wumuite, ideally KAl0.33W2.67O9 with a hexagonal tungsten bronze (HTB)-type structure, is another new mineral containing potassium and tungsten found in the Pan–Xi region in China after tewite was discovered. In this study, artificial synthetic experiments have been conducted to explore the formation process of wumuite and tewite. Wumuite was speculated to be formed by a metasomatic reaction between W-rich hydrothermal fluids and the potassium feldspar in the monzonite.
Simon Philippo, Frédéric Hatert, Yannick Bruni, Pietro Vignola, and Jiří Sejkora
Eur. J. Mineral., 32, 449–455, https://doi.org/10.5194/ejm-32-449-2020, https://doi.org/10.5194/ejm-32-449-2020, 2020
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Luxembourgite, ideally AgCuPbBi4Se8, is a new selenide discovered at Bivels, Grand Duchy of Luxembourg. The mineral forms tiny fibres deposited on dolomite crystals. Its crystal structure is similar to those of litochlebite and watkinsonite, and can be described as an alternation of two types of anionic layers: a pseudotetragonal layer four atoms thick and a pseudohexagonal layer one atom thick. The species named for the city of Luxembourg, close to its locality of discovery.
Anthony R. Kampf, Barbara P. Nash, Jakub Plášil, Jason B. Smith, and Mark N. Feinglos
Eur. J. Mineral., 32, 373–385, https://doi.org/10.5194/ejm-32-373-2020, https://doi.org/10.5194/ejm-32-373-2020, 2020
Cristiano Ferraris, Isabella Pignatelli, Fernando Cámara, Giancarlo Parodi, Sylvain Pont, Martin Schreyer, and Fengxia Wei
Eur. J. Mineral., 32, 355–365, https://doi.org/10.5194/ejm-32-355-2020, https://doi.org/10.5194/ejm-32-355-2020, 2020
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Laurentthomasite is a new mineral from Madagascar showing a very strong dichroism going from deep blue to yellow-green colours. The physical and chemical characteristics of this gem quality mineral bring it to the attention of the jewel industry as well as collectors of cut stones.
Elena Bonaccorsi and Paolo Orlandi
Eur. J. Mineral., 32, 347–354, https://doi.org/10.5194/ejm-32-347-2020, https://doi.org/10.5194/ejm-32-347-2020, 2020
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Molybdates are of a great interest due to their ionic conductivity, negative thermal expansion, and immobilization of radionuclides. The new mineral tancaite-(Ce), FeCe(MoO4)3•3H2O, shows a new structure type never observed in natural and synthetic molybdates. Its cubic average structure may be described as a derivative of the perovskite structure, in which Fe-centred octahedra are linked through MoO4 groups. The ordering of Mo and O atoms results in one or more complex superstructures.
Cited articles
Andreasen, J. W., Makovicky, E., Lebech, B., and Møller, S. K.: The role of iron in tetrahedrite and tennantite determined by Rietveld refinement of neutron powder diffraction data, Phys. Chem. Miner., 35, 447–454, 2008.
Balitskaya, O. V., Mozgova, N. N., Borodaev, Y. S., Efimova, A. V., and Tsepin, A. I.: Evolution of the unit-cell parameter of fahlores with their silver content, Izv. Akad. Nauk Kaz. SSR, Ser. Geol., 9, 112–120, 1989 (in Russian).
Biagioni, C., George, L. L., Cook, N. J., Makovicky, E., Moëlo, Y., Pasero, M., Sejkora, J., Stanley, C. J., Welch, M. D., and Bosi, F.: The tetrahedrite group: Nomenclature and classification, Am. Min., 105, 109–122, 2020a.
Biagioni, C., Sejkora, J., Moëlo, Y., Makovicky, E., Pasero, M., and Dolníček, Z.: Kenoargentotennantite-(Fe), IMA 2020-062, in: CNMNC Newsletter 58, Eur. J. Mineral., 32, 645–651, 2020b.
Biagioni, C., Sejkora, J., Musetti, S., Velebil, D., and Pasero, M.: Tetrahedrite-(Hg), a new “old” member of the tetrahedrite group, Mineral. Mag., 84, 584–592, 2020c.
Biagioni, C., Sejkora, J., Raber, T., Roth, P., Moëlo, Y., Dolníček, Z., and Pasero, M.: Tennantite-(Hg), Cu6(Cu4Hg2)As4S13, a new tetrahedrite-group mineral from the Lengenbach quarry, Binn, Switzerland, Mineral. Mag., 85, 744–751, 2021.
Biagioni, C., Sejkora, J., Moëlo, Y., Marcoux, E., Mauro, D., and Dolníček, Z.: Tennantite-(Cu), Cu12As4S13, from Layo, Arequipa Department, Peru: a new addition to the tetrahedrite-group minerals, Mineral. Mag., 86, 331–339, 2022a.
Biagioni, C., Kasatkin, A., Sejkora, J., Nestola, F., and Škoda, R.: Tennantite-(Cd), Cu6(Cu4Cd2)As4S13, from the Berenguela mining district, Bolivia: The first Cd-member of the tetrahedrite group, Mineral. Mag., 86, 834–840, 2022b.
Brese, N. E. and O'Keeffe, M.: Bond-valence parameters for solids, Acta Crystallogr., B47, 192–197, 1991.
Brown, I. D.: Predicting bond lengths in inorganic crystals, Acta Crystallogr., B33, 1305–1310, 1977.
Charlat, M. and Lévy, C.: Influence des principales substitutions sur le paramètre cristallin dans la série tennantite-tétraédrite, Bull. Soc. Fr. Mineral. Cristallogr., 98, 152–158, 1975.
Charnock, J. M., Garner, C. D., Pattrick, R. A. D., and Vaughan, D. J.: Investigation into the nature of copper and silver sites in argentian tetrahedrites using EXAFS spectroscopy, Phys. Chem. Miner., 15, 296–299, 1988.
Dolomanov, O. V., Bourhis, L. J., Gildea, R. J, Howard, J. A. K., and Puschmann, H.: OLEX2: A complete structure solution, refinement and analysis program, J. Appl. Crystallogr., 42, 339–341, 2009.
Flack H. D.: On enantiomorph-polarity estimation, Acta Crystallogr., Sect. A: Found. Crystallogr., 39, 876–881, 1983.
Johnson, M. L. and Burnham, C. W.: Crystal structure refinement of an arsenic-bearing argentian tetrahedrite, Am. Min., 70, 165–170, 1985.
Johnson, N. E., Craig, J. R., and Rimstidt, J. D.: Crystal chemistry of tetrahedrite, Am. Min., 73, 389–397, 1988.
Kalbskopf, R.: Strukturverfeinerung des Freibergits, Tschermaks Mineral. Petrogr. Mitt., 18, 147–155, 1972.
Kenngott, A.: Das Mohs'sche Mineralsystem, dem gegenwärtigen Standpuncte der Wissenschaft gemäss bearbeitet, Gerol & Sohn, Wien, 164 pp., 1853.
Kharbish, S., Libowitzky, E., and Beran., A.: The effect of As-Sb substitution in the Raman spectra of tetrahedrite-tennantite and pyrargyrite-proustite solid solutions, Eur. J. Mineral., 19, 567–574, 2007.
Laugier, J., and Bochu, B.: CHECKCELL: a Software Performing Automatic Cell/Space Group Determination, Collaborative Computational Project, Number 14 (CCP14), Laboratory of Materials and Phyisical Engineering, School of Physics, University of Grenoble, France, 2000.
Li, X. L. and Wang, G. X.: Studies of the tetrahedrite-group minerals from Dachang ore field, Guangxi, China, Acta Min. Sin., 10, 119–126, 1990 (in Chinese with English abstract).
Makovicky, E., Karanovicì, L., Poleti, D., Balić-Žunić, T., and Paar, W. H.: Crystal structure of copper-rich unsubstituted tennantite, Cu12.5As4S13, Can. Mineral., 43, 679–688, 2005.
Mikuš, T., Vlasáč, J., Majzlan, J., Sejkora, J., Steciuk, G., Plášil, J., Rößler, C., and Matthes, C.: Argentotetrahedrite-(Cd), Ag6(Cu4Cd2)Sb4S13, a new member of the tetrahedrite group from Rudno nad Hronom, Slovakia, Mineral. Mag., 87, 262–270, 2023.
Moëlo, Y., Makovicky, E., Mozgova, N. N., Jambor, J. L., Cook, N., Pring, A., Paar, W. H., Nickel, E. H., Graeser, S., Karup-Møller, S., Žunic, T. B., Mumme, W. G., Vurro, F., Topa, D., Bindi, L., Bente, K., and Shimizu, M.: Sulfosalt systematics: a review. Report of the sulfosalt sub-committee of the IMA Commission on Ore Mineralogy, Eur. J. Mineral., 20, 7–46, 2008.
Nuss, J., Wedig, U., Xie, W., Yordanov, P., Bruin, J., Hübner, R., Weidenkaff, A., and Takagi, H.: Phosphide–tetrahedrite Ag6Ge10P12: thermoelectric performance of a long-forgotten silver-cluster compound, Chem. Mater., 29, 6956–6965, 2017.
Pattrick, R. A. D. and Hall, A. J.: Silver substitution into synthetic zinc, cadmium, and iron tetrahedrites, Mineral. Mag., 47, 441–451, 1983.
Peterson, R. C. and Miller, I.: Crystal structure and cation distribution in freibergite and tetrahedrite, Mineral. Mag., 50, 717–721, 1986.
Petruk, W. and staff.: Characteristics of the sulphides, Can. Mineral., 11, 196–231, 1971.
Qu, K., Sun, W., Nestola, F., Gu, X., Yang, Z., Sima, X., Tang, C., Fan, G., and Wang, Y.: Kenorozhdestvenskayaite-(Fe), Ag6(Ag4Fe2)Sb4S12□: A new tetrahedrite group mineral containing a natural [Ag6]4+ cluster and its relationship to the synthetic ternary phosphide (Ag6M4P12)M
Rigaku Oxford Diffraction: CrysAlisPro Software system, version 1.171.41.96a, Rigaku Corporation, 2021.
Riley, J. F.: The tetrahedrite–freibergite series, with reference to the Mount Isa Pb–Zn–Ag orebody, Miner. Deposita, 9, 117–124, 1974.
Rozhdestvenskaya, I. V., Zayakina, N. V., and Samusikov, V. P.: Crystal structure features of minerals from a series of tetrahedrite-freibergite, Mineralogiceskij Zhurnal., 15, 9–17, 1993 (in Russian).
Sack, R. O., Lyubimtseva, N. G., Bortnikov, N. S., Anikina, E. Y., and Borisovsky, S. E.: Sulfur vacancies in fahlores from the Ag-Pb–Zn Mangazeyskoye ore deposit (Sakha, Russia), Contrib. Mineral. Petrol., 177, 82, 2022.
Samusikov, V. P., Zayakina, N. V., and Leskova, N. V.: Relation between unit cell of fahlores and Ag-concentration, Doklady Akademii Nauk USSR, 299, 468–471, 1988 (in Russian).
Samusikov, V. P. and Gamyanin, G. N.: Nomenclature of mineral species of Cu-Ag isomorphous tetrahedrite, 16th IMA General Meeting, Pisa, Italy, 4–9 September 1994, 363–364, 1994.
Sejkora, J., Biagioni, C., Vrtiška, L., and Moëlo, Y.: Zvěstovite-(Zn), Ag6(Ag4Zn2)As4S13, a new tetrahedrite-group mineral from Zvěstov, Czech Republic, Mineral. Mag., 85, 716–724, 2021.
Sejkora, J., Biagioni, C., Števko, M., Raber, T., Roth, P., and Vrtiška, L.: Argentotetrahedrite-(Zn), Ag6(Cu4Zn2)Sb4S13, a new member of the tetrahedrite group. Mineral. Mag., 86, 319–330, 2022.
Sejkora, J., Biagioni, C., Škácha, P., Musetti, S., Kasatkin, A. V., and Nestola, F.: Tetrahedrite-(Cd), Cu6(Cu4Cd2)Sb4S13, from Radětice near Příbram, Czech Republic: the new Cd member of the tetrahedrite group, Eur. J. Mineral., 35, 897–907, 2023.
Sheldrick, G. M.: Crystal structure refinement with SHELXL, Acta Crystallogr., C71, 3–8, 2015.
Shimada, N. and Hirowatari, F.: Argentian tetrahedrites from the Taishu-Shigekuma mine, Tsushima Island, Japan, Mineral. J., 1, 77–87, 1972.
Shu, Z., Shen, C., Lu, A., and Gu, X.: Chemical Composition and Crystal Structure of Kenoargentotetrahedrite-(Fe), Ag6Cu4Fe2Sb4S12, from the Bajiazi Pb-Zn Deposit, Liaoning, China, Crystals, 12, 467, https://doi.org/10.3390/cryst12040467, 2022.
von Schnering, H. G. and Hoenle, W.: New compounds containing Ag6(4+) cluster units, Solid Compound of Transition Elements, Int. Conference Stuttgart, 12–16 June, 101–102, 1979.
von Weissenbach, C. G. A.: Ueber die Gehalte der beym sächsischen Bergbau vorkommenden Silbererze. Kalender für den Sächsischen Berg-und Hüttenmann auf das Jahr, 223–248, 1831.
Wang, Y., Chen, R., Gu, X., Nestola, F., Hou, Z., Yang, Z., Dong., G., Guo, H., and Qu, K.: Tetrahedrite-(Ni), Cu6(Cu4Ni2)Sb4S13, the first nickel member of tetrahedrite group mineral from Luobusa chromite deposits, Tibet, China, Am. Min., 108, 1984–1992, 2023a.
Wang, Y., Chen, R., Gu, X., Hou, Z., Nestola, F., Yang, Z., Fan, G., Dong, G., and Qu, K.: Tennantite-(Ni), Cu6(Cu4Ni2)As4S13, from Luobusa ophiolite, Tibet, China: a new Ni member of the tetrahedrite group, Mineral. Mag., 87, 591–598, 2023b.
Warr L. N.: IMA–CNMNC approved mineral symbols, Mineral. Mag., 85, 291–320, 2021.
Welch, M. D., Stanley, C. J., Spratt, J., and Mills, S. J.: Rozhdestvenskayaite Ag10Zn2Sb4S13 and argentotetrahedrite Ag6Cu4(Fe2+, Zn)2Sb4S13: two Ag dominant members of the tetrahedrite group, Eur. J. Mineral., 30, 1163–1172, 2018.
Wilson, A. J. C.: International Tables for Crystallography, Vol. C, Kluwer, Dordrecht, the Netherlands, eBook ISBN: 978-1-4020-5408-2, https://doi.org/10.1107/97809553602060000103, 1992.
Wu, P., Yang, H., Qu, K., Wang, Y., and Gu, X.: Argentotetrahedrite-(Hg) Ag6(Cu4Hg2)Sb4S13: a new tetrahedrite group mineral from Dongping Hg-Ag deposit, Acta Geol. Sin., 96, 418–425, 2022 (in Chinese with English abstract).
Wuensch, B. J.: The crystal structure of tetrahedrite, Cu12Sb4S13, Z. Kristallogr. Cryst. Mater., 119, 437–453, 1964.
Zhang, J., Chen, Y., Yang, Y., and Deng, J.: Lead isotope systematics of the Weishancheng Au-Ag belt, Tongbai Mountains, central China: implication for ore genesis, Int. Geol. Rev., 53, 656–676, 2011.
Zhang, J., Chen, Y. J., Pirajno, F., Deng, J., Chen, H. Y., and Wang, C. M.: Geology, C–H–O–S–Pb isotope systematics and geochronology of the Yindongpo gold deposit, Tongbai Mountains, central China: Implication for ore genesis, Ore Geol. Rev., 53, 343–356, 2013.
Zhdanov, Y. Y., Amuzinskiy, V. A., and Andrianov, N. G.: A natural variety of high-silver fahlerz with a large unit-cell parameter, Dokl. Akad., Earth Sci. Sect., 327, 134–138, 1992.
Short summary
In this paper, the full description of the extremely rare [Ag6]4+-cluster-containing new tetrahedrite-group mineral kenoargentotetrahedrite-(Zn) is reported. The structure refinement result confirms the coupling between the site occupancy factor of subvalent hexasilver clusters at the M(2) site and that of the vacancy at the S(2) site. This relationship further substantiates the charge balance substitution mechanism of S-deficiency tetrahedrites: 6M(2)Ag+ + S(2)S2– = M(2)[Ag6]4+ + S(2)□.
In this paper, the full description of the extremely rare [Ag6]4+-cluster-containing new...
