Articles | Volume 36, issue 3
https://doi.org/10.5194/ejm-36-397-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-36-397-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Kenoargentotetrahedrite-(Zn), [Ag6]4+(Cu4Zn2)Sb4S12□, a new member of the tetrahedrite group from the Yindongpo Au deposit, China
Tianjin Center, China Geological Survey, Tianjin, 300171, China
School of Earth Sciences and Engineering, Nanjing University, Nanjing, 210023, China
Xianzhang Sima
Tianjin Center, China Geological Survey, Tianjin, 300171, China
Xiangping Gu
School of Geosciences and Info-Physics, Central South University, Changsha, 410083, China
Weizhi Sun
No. 3 Institute of Geological and Mineral Resources Survey of Henan Geological Bureau, Xinyang, 464000, China
Guang Fan
Institute of Science and Technology Information, Beijing Research Institute of Uranium Geology, Beijing, 100029, China
Zeqiang Yang
No. 3 Institute of Geological and Mineral Resources Survey of Henan Geological Bureau, Xinyang, 464000, China
Yanjuan Wang
CORRESPONDING AUTHOR
School of Earth Sciences and Resources, China University of Geosciences, Beijing, 100083, China
Department of Geosciences, University of Padua, Padua, 35131, Italy
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Cited articles
Andreasen, J. W., Makovicky, E., Lebech, B., and Møller, S. K.: The role of iron in tetrahedrite and tennantite determined by Rietveld refinement of neutron powder diffraction data, Phys. Chem. Miner., 35, 447–454, 2008.
Balitskaya, O. V., Mozgova, N. N., Borodaev, Y. S., Efimova, A. V., and Tsepin, A. I.: Evolution of the unit-cell parameter of fahlores with their silver content, Izv. Akad. Nauk Kaz. SSR, Ser. Geol., 9, 112–120, 1989 (in Russian).
Biagioni, C., George, L. L., Cook, N. J., Makovicky, E., Moëlo, Y., Pasero, M., Sejkora, J., Stanley, C. J., Welch, M. D., and Bosi, F.: The tetrahedrite group: Nomenclature and classification, Am. Min., 105, 109–122, 2020a.
Biagioni, C., Sejkora, J., Moëlo, Y., Makovicky, E., Pasero, M., and Dolníček, Z.: Kenoargentotennantite-(Fe), IMA 2020-062, in: CNMNC Newsletter 58, Eur. J. Mineral., 32, 645–651, 2020b.
Biagioni, C., Sejkora, J., Musetti, S., Velebil, D., and Pasero, M.: Tetrahedrite-(Hg), a new “old” member of the tetrahedrite group, Mineral. Mag., 84, 584–592, 2020c.
Biagioni, C., Sejkora, J., Raber, T., Roth, P., Moëlo, Y., Dolníček, Z., and Pasero, M.: Tennantite-(Hg), Cu6(Cu4Hg2)As4S13, a new tetrahedrite-group mineral from the Lengenbach quarry, Binn, Switzerland, Mineral. Mag., 85, 744–751, 2021.
Biagioni, C., Sejkora, J., Moëlo, Y., Marcoux, E., Mauro, D., and Dolníček, Z.: Tennantite-(Cu), Cu12As4S13, from Layo, Arequipa Department, Peru: a new addition to the tetrahedrite-group minerals, Mineral. Mag., 86, 331–339, 2022a.
Biagioni, C., Kasatkin, A., Sejkora, J., Nestola, F., and Škoda, R.: Tennantite-(Cd), Cu6(Cu4Cd2)As4S13, from the Berenguela mining district, Bolivia: The first Cd-member of the tetrahedrite group, Mineral. Mag., 86, 834–840, 2022b.
Brese, N. E. and O'Keeffe, M.: Bond-valence parameters for solids, Acta Crystallogr., B47, 192–197, 1991.
Brown, I. D.: Predicting bond lengths in inorganic crystals, Acta Crystallogr., B33, 1305–1310, 1977.
Charlat, M. and Lévy, C.: Influence des principales substitutions sur le paramètre cristallin dans la série tennantite-tétraédrite, Bull. Soc. Fr. Mineral. Cristallogr., 98, 152–158, 1975.
Charnock, J. M., Garner, C. D., Pattrick, R. A. D., and Vaughan, D. J.: Investigation into the nature of copper and silver sites in argentian tetrahedrites using EXAFS spectroscopy, Phys. Chem. Miner., 15, 296–299, 1988.
Dolomanov, O. V., Bourhis, L. J., Gildea, R. J, Howard, J. A. K., and Puschmann, H.: OLEX2: A complete structure solution, refinement and analysis program, J. Appl. Crystallogr., 42, 339–341, 2009.
Flack H. D.: On enantiomorph-polarity estimation, Acta Crystallogr., Sect. A: Found. Crystallogr., 39, 876–881, 1983.
Johnson, M. L. and Burnham, C. W.: Crystal structure refinement of an arsenic-bearing argentian tetrahedrite, Am. Min., 70, 165–170, 1985.
Johnson, N. E., Craig, J. R., and Rimstidt, J. D.: Crystal chemistry of tetrahedrite, Am. Min., 73, 389–397, 1988.
Kalbskopf, R.: Strukturverfeinerung des Freibergits, Tschermaks Mineral. Petrogr. Mitt., 18, 147–155, 1972.
Kenngott, A.: Das Mohs'sche Mineralsystem, dem gegenwärtigen Standpuncte der Wissenschaft gemäss bearbeitet, Gerol & Sohn, Wien, 164 pp., 1853.
Kharbish, S., Libowitzky, E., and Beran., A.: The effect of As-Sb substitution in the Raman spectra of tetrahedrite-tennantite and pyrargyrite-proustite solid solutions, Eur. J. Mineral., 19, 567–574, 2007.
Laugier, J., and Bochu, B.: CHECKCELL: a Software Performing Automatic Cell/Space Group Determination, Collaborative Computational Project, Number 14 (CCP14), Laboratory of Materials and Phyisical Engineering, School of Physics, University of Grenoble, France, 2000.
Li, X. L. and Wang, G. X.: Studies of the tetrahedrite-group minerals from Dachang ore field, Guangxi, China, Acta Min. Sin., 10, 119–126, 1990 (in Chinese with English abstract).
Makovicky, E., Karanovicì, L., Poleti, D., Balić-Žunić, T., and Paar, W. H.: Crystal structure of copper-rich unsubstituted tennantite, Cu12.5As4S13, Can. Mineral., 43, 679–688, 2005.
Mikuš, T., Vlasáč, J., Majzlan, J., Sejkora, J., Steciuk, G., Plášil, J., Rößler, C., and Matthes, C.: Argentotetrahedrite-(Cd), Ag6(Cu4Cd2)Sb4S13, a new member of the tetrahedrite group from Rudno nad Hronom, Slovakia, Mineral. Mag., 87, 262–270, 2023.
Moëlo, Y., Makovicky, E., Mozgova, N. N., Jambor, J. L., Cook, N., Pring, A., Paar, W. H., Nickel, E. H., Graeser, S., Karup-Møller, S., Žunic, T. B., Mumme, W. G., Vurro, F., Topa, D., Bindi, L., Bente, K., and Shimizu, M.: Sulfosalt systematics: a review. Report of the sulfosalt sub-committee of the IMA Commission on Ore Mineralogy, Eur. J. Mineral., 20, 7–46, 2008.
Nuss, J., Wedig, U., Xie, W., Yordanov, P., Bruin, J., Hübner, R., Weidenkaff, A., and Takagi, H.: Phosphide–tetrahedrite Ag6Ge10P12: thermoelectric performance of a long-forgotten silver-cluster compound, Chem. Mater., 29, 6956–6965, 2017.
Pattrick, R. A. D. and Hall, A. J.: Silver substitution into synthetic zinc, cadmium, and iron tetrahedrites, Mineral. Mag., 47, 441–451, 1983.
Peterson, R. C. and Miller, I.: Crystal structure and cation distribution in freibergite and tetrahedrite, Mineral. Mag., 50, 717–721, 1986.
Petruk, W. and staff.: Characteristics of the sulphides, Can. Mineral., 11, 196–231, 1971.
Qu, K., Sun, W., Nestola, F., Gu, X., Yang, Z., Sima, X., Tang, C., Fan, G., and Wang, Y.: Kenorozhdestvenskayaite-(Fe), Ag6(Ag4Fe2)Sb4S12□: A new tetrahedrite group mineral containing a natural [Ag6]4+ cluster and its relationship to the synthetic ternary phosphide (Ag6M4P12)M , Am. Min., 1–28, https://doi.org/10.2138/am-2023-9074, 2023.
Rigaku Oxford Diffraction: CrysAlisPro Software system, version 1.171.41.96a, Rigaku Corporation, 2021.
Riley, J. F.: The tetrahedrite–freibergite series, with reference to the Mount Isa Pb–Zn–Ag orebody, Miner. Deposita, 9, 117–124, 1974.
Rozhdestvenskaya, I. V., Zayakina, N. V., and Samusikov, V. P.: Crystal structure features of minerals from a series of tetrahedrite-freibergite, Mineralogiceskij Zhurnal., 15, 9–17, 1993 (in Russian).
Sack, R. O., Lyubimtseva, N. G., Bortnikov, N. S., Anikina, E. Y., and Borisovsky, S. E.: Sulfur vacancies in fahlores from the Ag-Pb–Zn Mangazeyskoye ore deposit (Sakha, Russia), Contrib. Mineral. Petrol., 177, 82, 2022.
Samusikov, V. P., Zayakina, N. V., and Leskova, N. V.: Relation between unit cell of fahlores and Ag-concentration, Doklady Akademii Nauk USSR, 299, 468–471, 1988 (in Russian).
Samusikov, V. P. and Gamyanin, G. N.: Nomenclature of mineral species of Cu-Ag isomorphous tetrahedrite, 16th IMA General Meeting, Pisa, Italy, 4–9 September 1994, 363–364, 1994.
Sejkora, J., Biagioni, C., Vrtiška, L., and Moëlo, Y.: Zvěstovite-(Zn), Ag6(Ag4Zn2)As4S13, a new tetrahedrite-group mineral from Zvěstov, Czech Republic, Mineral. Mag., 85, 716–724, 2021.
Sejkora, J., Biagioni, C., Števko, M., Raber, T., Roth, P., and Vrtiška, L.: Argentotetrahedrite-(Zn), Ag6(Cu4Zn2)Sb4S13, a new member of the tetrahedrite group. Mineral. Mag., 86, 319–330, 2022.
Sejkora, J., Biagioni, C., Škácha, P., Musetti, S., Kasatkin, A. V., and Nestola, F.: Tetrahedrite-(Cd), Cu6(Cu4Cd2)Sb4S13, from Radětice near Příbram, Czech Republic: the new Cd member of the tetrahedrite group, Eur. J. Mineral., 35, 897–907, 2023.
Sheldrick, G. M.: Crystal structure refinement with SHELXL, Acta Crystallogr., C71, 3–8, 2015.
Shimada, N. and Hirowatari, F.: Argentian tetrahedrites from the Taishu-Shigekuma mine, Tsushima Island, Japan, Mineral. J., 1, 77–87, 1972.
Shu, Z., Shen, C., Lu, A., and Gu, X.: Chemical Composition and Crystal Structure of Kenoargentotetrahedrite-(Fe), Ag6Cu4Fe2Sb4S12, from the Bajiazi Pb-Zn Deposit, Liaoning, China, Crystals, 12, 467, https://doi.org/10.3390/cryst12040467, 2022.
von Schnering, H. G. and Hoenle, W.: New compounds containing Ag6(4+) cluster units, Solid Compound of Transition Elements, Int. Conference Stuttgart, 12–16 June, 101–102, 1979.
von Weissenbach, C. G. A.: Ueber die Gehalte der beym sächsischen Bergbau vorkommenden Silbererze. Kalender für den Sächsischen Berg-und Hüttenmann auf das Jahr, 223–248, 1831.
Wang, Y., Chen, R., Gu, X., Nestola, F., Hou, Z., Yang, Z., Dong., G., Guo, H., and Qu, K.: Tetrahedrite-(Ni), Cu6(Cu4Ni2)Sb4S13, the first nickel member of tetrahedrite group mineral from Luobusa chromite deposits, Tibet, China, Am. Min., 108, 1984–1992, 2023a.
Wang, Y., Chen, R., Gu, X., Hou, Z., Nestola, F., Yang, Z., Fan, G., Dong, G., and Qu, K.: Tennantite-(Ni), Cu6(Cu4Ni2)As4S13, from Luobusa ophiolite, Tibet, China: a new Ni member of the tetrahedrite group, Mineral. Mag., 87, 591–598, 2023b.
Warr L. N.: IMA–CNMNC approved mineral symbols, Mineral. Mag., 85, 291–320, 2021.
Welch, M. D., Stanley, C. J., Spratt, J., and Mills, S. J.: Rozhdestvenskayaite Ag10Zn2Sb4S13 and argentotetrahedrite Ag6Cu4(Fe2+, Zn)2Sb4S13: two Ag dominant members of the tetrahedrite group, Eur. J. Mineral., 30, 1163–1172, 2018.
Wilson, A. J. C.: International Tables for Crystallography, Vol. C, Kluwer, Dordrecht, the Netherlands, eBook ISBN: 978-1-4020-5408-2, https://doi.org/10.1107/97809553602060000103, 1992.
Wu, P., Yang, H., Qu, K., Wang, Y., and Gu, X.: Argentotetrahedrite-(Hg) Ag6(Cu4Hg2)Sb4S13: a new tetrahedrite group mineral from Dongping Hg-Ag deposit, Acta Geol. Sin., 96, 418–425, 2022 (in Chinese with English abstract).
Wuensch, B. J.: The crystal structure of tetrahedrite, Cu12Sb4S13, Z. Kristallogr. Cryst. Mater., 119, 437–453, 1964.
Zhang, J., Chen, Y., Yang, Y., and Deng, J.: Lead isotope systematics of the Weishancheng Au-Ag belt, Tongbai Mountains, central China: implication for ore genesis, Int. Geol. Rev., 53, 656–676, 2011.
Zhang, J., Chen, Y. J., Pirajno, F., Deng, J., Chen, H. Y., and Wang, C. M.: Geology, C–H–O–S–Pb isotope systematics and geochronology of the Yindongpo gold deposit, Tongbai Mountains, central China: Implication for ore genesis, Ore Geol. Rev., 53, 343–356, 2013.
Zhdanov, Y. Y., Amuzinskiy, V. A., and Andrianov, N. G.: A natural variety of high-silver fahlerz with a large unit-cell parameter, Dokl. Akad., Earth Sci. Sect., 327, 134–138, 1992.
Short summary
In this paper, the full description of the extremely rare [Ag6]4+-cluster-containing new tetrahedrite-group mineral kenoargentotetrahedrite-(Zn) is reported. The structure refinement result confirms the coupling between the site occupancy factor of subvalent hexasilver clusters at the M(2) site and that of the vacancy at the S(2) site. This relationship further substantiates the charge balance substitution mechanism of S-deficiency tetrahedrites: 6M(2)Ag+ + S(2)S2– = M(2)[Ag6]4+ + S(2)□.
In this paper, the full description of the extremely rare [Ag6]4+-cluster-containing new...