Articles | Volume 36, issue 3
https://doi.org/10.5194/ejm-36-397-2024
https://doi.org/10.5194/ejm-36-397-2024
New minerals, nomenclature, and classification
 | 
03 May 2024
New minerals, nomenclature, and classification |  | 03 May 2024

Kenoargentotetrahedrite-(Zn), [Ag6]4+(Cu4Zn2)Sb4S12□, a new member of the tetrahedrite group from the Yindongpo Au deposit, China

Kai Qu, Xianzhang Sima, Xiangping Gu, Weizhi Sun, Guang Fan, Zeqiang Yang, and Yanjuan Wang

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Cited articles

Andreasen, J. W., Makovicky, E., Lebech, B., and Møller, S. K.: The role of iron in tetrahedrite and tennantite determined by Rietveld refinement of neutron powder diffraction data, Phys. Chem. Miner., 35, 447–454, 2008. 
Balitskaya, O. V., Mozgova, N. N., Borodaev, Y. S., Efimova, A. V., and Tsepin, A. I.: Evolution of the unit-cell parameter of fahlores with their silver content, Izv. Akad. Nauk Kaz. SSR, Ser. Geol., 9, 112–120, 1989 (in Russian). 
Biagioni, C., George, L. L., Cook, N. J., Makovicky, E., Moëlo, Y., Pasero, M., Sejkora, J., Stanley, C. J., Welch, M. D., and Bosi, F.: The tetrahedrite group: Nomenclature and classification, Am. Min., 105, 109–122, 2020a. 
Biagioni, C., Sejkora, J., Moëlo, Y., Makovicky, E., Pasero, M., and Dolníček, Z.: Kenoargentotennantite-(Fe), IMA 2020-062, in: CNMNC Newsletter 58, Eur. J. Mineral., 32, 645–651, 2020b. 
Biagioni, C., Sejkora, J., Musetti, S., Velebil, D., and Pasero, M.: Tetrahedrite-(Hg), a new “old” member of the tetrahedrite group, Mineral. Mag., 84, 584–592, 2020c. 
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Short summary
In this paper, the full description of the extremely rare [Ag6]4+-cluster-containing new tetrahedrite-group mineral kenoargentotetrahedrite-(Zn) is reported. The structure refinement result confirms the coupling between the site occupancy factor of subvalent hexasilver clusters at the M(2) site and that of the vacancy at the S(2) site. This relationship further substantiates the charge balance substitution mechanism of S-deficiency tetrahedrites: 6M(2)Ag+ + S(2)S2– = M(2)[Ag6]4+ + S(2)□.
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