Articles | Volume 37, issue 1
https://doi.org/10.5194/ejm-37-39-2025
https://doi.org/10.5194/ejm-37-39-2025
New minerals, nomenclature, and classification
 | 
20 Jan 2025
New minerals, nomenclature, and classification |  | 20 Jan 2025

Dacostaite, K(Mg2Al)[Mg(H2O)6]2(AsO4)2F6  ⋅  2H2O, a new fluoride–arsenate mineral from the Cetine di Cotorniano Mine (Tuscany, Italy)

Cristian Biagioni, Daniela Mauro, Jiří Sejkora, Zdeněk Dolníček, Andrea Dini, and Radek Škoda

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Cited articles

Ballirano, P., Callegari, A., Caucia, F., Maras, A., Mazzi, F., and Ungaretti, L.: The crystal structure of vicanite-(Ce), a borosilicate showing an unusual (Si3B3O18)15− polyanion, Am. Mineral., 87, 1139–1143, 2002. 
Belluomini, G., Fornaseri, M., and Nicoletti, M.: Onoratoite, a new antimony oxychloride from Cetine di Cotorniano, Rosia (Siena, Italy), Mineral. Mag., 36, 1037–1044, 1968. 
Bermanec, V.: Centro-symmetric tilasite from Nežilovo, Macedonia: A crystal structure refinement, Neues Jb. Miner. Monat., 1994, 289–294, 1994. 
Biagioni, C., Bosi, F., Hålenius, U., and Pasero, M.: The crystal structure of svabite, Ca5(AsO4)3F, an arsenate member of the apatite supergroup, Am. Mineral., 101, 1750–1755, 2016. 
Biagioni, C., Mugnaioli, E., Lorenzon, S., Mauro, D., Musetti, S., Sejkora, J., Belmonte, D., Demitri, N., and Dolníček, Z.: Nannoniite, Al2(OH)5F, a new mineral from the Cetine di Cotorniano mine (Tuscany, Italy), Eur. J. Mineral., 36, 1011–1022, https://doi.org/10.5194/ejm-36-1011-2024, 2024. 
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Short summary
Dacostaite is a new fluoride–arsenate mineral found in the Sb(Au) deposit of the Cetine di Cotorniano Mine (Tuscany, Italy). It shows a novel crystal structure formed by heteropolyhedral layers and isolated Mg(H2O)6 groups connected by H bonds. The heteropolyhedral layers are similar to those occurring in alunite-supergroup minerals, and this is a further example of the ability of nature to use similar modules in forming the large number of currently known structural arrangements. 
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