Articles | Volume 36, issue 2
https://doi.org/10.5194/ejm-36-267-2024
https://doi.org/10.5194/ejm-36-267-2024
Research article
 | 
13 Mar 2024
Research article |  | 13 Mar 2024

Macraeite, [(H2O)K]Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10  ⋅  4H2O, a new monoclinic paulkerrite-group mineral, from the Cubos–Mesquitela–Mangualde pegmatite, Portugal

Ian E. Grey, Christian Rewitzer, Rupert Hochleitner, Anthony R. Kampf, Stephanie Boer, William G. Mumme, and Nicholas C. Wilson

Related authors

Fluor-rewitzerite, [(H2O)K]Mn2(Al2Ti)(PO4)4(OF)(H2O)10 ⋅ 4H2O, a new paulkerrite-group mineral, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany
Rupert Hochleitner, Ian E. Grey, Anthony R. Kampf, Stephanie Boer, Colin M. MacRae, William G. Mumme, and Nicholas C. Wilson
Eur. J. Mineral., 36, 541–554, https://doi.org/10.5194/ejm-36-541-2024,https://doi.org/10.5194/ejm-36-541-2024, 2024
Short summary
Crystal chemistry of type paulkerrite and establishment of the paulkerrite group nomenclature
Ian E. Grey, Stephanie Boer, Colin M. MacRae, Nicholas C. Wilson, William G. Mumme, and Ferdinando Bosi
Eur. J. Mineral., 35, 909–919, https://doi.org/10.5194/ejm-35-909-2023,https://doi.org/10.5194/ejm-35-909-2023, 2023
Short summary
Regerite, KFe6(PO4)4(OH)7(H2O)6  ⋅  4H2O, the first new mineral species from the Kreuzberg pegmatite, Pleystein, Oberpfalz, Bavaria, Germany
Christian Rewitzer, Rupert Hochleitner, Ian E. Grey, Anthony R. Kampf, Stephanie Boer, and Colin M. MacRae
Eur. J. Mineral., 35, 805–812, https://doi.org/10.5194/ejm-35-805-2023,https://doi.org/10.5194/ejm-35-805-2023, 2023
Short summary
Hochleitnerite, [K(H2O)]Mn2(Ti2Fe)(PO4)4O2(H2O)10  ⋅  4H2O, a new paulkerrite-group mineral, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany
Ian E. Grey, Erich Keck, Anthony R. Kampf, Colin M. MacRae, Robert W. Gable, William G. Mumme, Nicholas C. Wilson, Alexander M. Glenn, and Cameron Davidson
Eur. J. Mineral., 35, 635–643, https://doi.org/10.5194/ejm-35-635-2023,https://doi.org/10.5194/ejm-35-635-2023, 2023
Short summary
Manganrockbridgeite, Mn2+2Fe3+3(PO4)3(OH)4(H2O), a new member of the rockbridgeite group, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria
Ian E. Grey, Rupert Hochleitner, Anthony R. Kampf, Stephanie Boer, Colin M. MacRae, John D. Cashion, Christian Rewitzer, and William G. Mumme
Eur. J. Mineral., 35, 295–304, https://doi.org/10.5194/ejm-35-295-2023,https://doi.org/10.5194/ejm-35-295-2023, 2023
Short summary

Related subject area

New minerals and systematic mineralogy
Zvěstovite-(Fe), Ag6(Ag4Fe2)As4S13, a new member of the tetrahedrite group from the Ulatayskoe Ag–Cu–Co occurrence, eastern Siberia, Russia
Cristian Biagioni, Anatoly V. Kasatkin, Fabrizio Nestola, Radek Škoda, Vladislav V. Gurzhiy, Atali A. Agakhanov, and Natalia N. Koshlyakova
Eur. J. Mineral., 36, 529–540, https://doi.org/10.5194/ejm-36-529-2024,https://doi.org/10.5194/ejm-36-529-2024, 2024
Short summary
Fluor-rewitzerite, [(H2O)K]Mn2(Al2Ti)(PO4)4(OF)(H2O)10 ⋅ 4H2O, a new paulkerrite-group mineral, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany
Rupert Hochleitner, Ian E. Grey, Anthony R. Kampf, Stephanie Boer, Colin M. MacRae, William G. Mumme, and Nicholas C. Wilson
Eur. J. Mineral., 36, 541–554, https://doi.org/10.5194/ejm-36-541-2024,https://doi.org/10.5194/ejm-36-541-2024, 2024
Short summary
Kenoargentotetrahedrite-(Zn), [Ag6]4+(Cu4Zn2)Sb4S12□, a new member of the tetrahedrite group from the Yindongpo Au deposit, China
Kai Qu, Xianzhang Sima, Xiangping Gu, Weizhi Sun, Guang Fan, Zeqiang Yang, and Yanjuan Wang
Eur. J. Mineral., 36, 397–409, https://doi.org/10.5194/ejm-36-397-2024,https://doi.org/10.5194/ejm-36-397-2024, 2024
Short summary
Igelströmite, Fe3+(Sb3+Pb2+)O4, and manganoschafarzikite, Mn2+Sb3+2O4, two new members of the newly established minium group, from the Långban Mn–Fe deposit, Värmland, Sweden
Dan Holtstam, Jörgen Langhof, Henrik Friis, Andreas Karlsson, and Muriel Erambert
Eur. J. Mineral., 36, 311–322, https://doi.org/10.5194/ejm-36-311-2024,https://doi.org/10.5194/ejm-36-311-2024, 2024
Short summary
Mckelveyite group minerals – Part 4: Alicewilsonite-(YLa), Na2Sr2YLa(CO3)6  ⋅  3H2O, a new lanthanum-dominant species from the Paratoo mine, Australia
Inna Lykova, Ralph Rowe, Glenn Poirier, Henrik Friis, and Kate Helwig
Eur. J. Mineral., 36, 301–310, https://doi.org/10.5194/ejm-36-301-2024,https://doi.org/10.5194/ejm-36-301-2024, 2024
Short summary

Cited articles

Aragao, D., Aishima, J., Cherukuvada, H., Clarken, R., Clift, M., Cowieson, N. P., Ericsson, D. J., Gee, C. L., Macedo, S., Mudie, N., Panjikar, S., Price, J. R., Riboldi-Tunnicliffe, A., Rostan, R., Williamson, R., and Caradoc-Davies, T. T.: MX2: a high-flux undulator microfocus beamline serving both the chemical and macromolecular crystallography communities at the Australian Synchrotron, J. Synch. Radiat., 25, 885–891, 2018. 
Bamberger, C. E., Begun, G. M., and MacDougall, C. S.: Raman spectroscopy of potassium titanates: Their synthesis, hydrolytic reactions and thermal stability, Appl. Spectrosc., 44, 31–37, 1990. 
Bosi, F., Hatert, F., Halenius, U., Pasero, M., Ritsuro, M., and Mills, S. J.: On the application of the IMA-CNMNC dominant-valency rule to complex mineral compositions, Mineral. Mag., 83, 627–632, 2019a. 
Bosi, F., Biagioni, C., and Oberti, R.: On the chemical identification and classification of minerals, Minerals, 9, 591, https://doi.org/10.3390/min9100591, 2019b. 
Demartin, F., Pilati, T., Gay, H. D., and Gramaccioli, C. M.: The crystal structure of a mineral related to paulkerrite, Z. Kristallogr., 208, 57–71, 1993. 
Download
Short summary
Macraeite is the fourth type mineral to be described from the Mangualde pegmatite, Portugal, and is the first paulkerrite-group mineral to be characterised from the locality. Its crystal structure has been refined using synchrotron diffraction data, and its chemical analysis, Raman spectrum, and optical properties are reported.