Articles | Volume 35, issue 5
https://doi.org/10.5194/ejm-35-703-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/ejm-35-703-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
31 Aug 2023
Research article |
| 31 Aug 2023
| 31 Aug 2023
Batoniite, [Al8(OH)14(H2O)18](SO4)5 ⋅ 5H2O, a new mineral with the [Al8(OH)14(H2O)18]10+ polyoxocation from the Cetine di Cotorniano Mine, Tuscany, Italy
Dipartimento di Scienze della Terra, Università di Pisa, Via Santa
Maria 53, 56126 Pisa, Italy
Museo di Storia Naturale, Università di Pisa, Via Roma 79, 56011
Calci, Italy
Cristian Biagioni
Dipartimento di Scienze della Terra, Università di Pisa, Via Santa
Maria 53, 56126 Pisa, Italy
Centro per l'Integrazione della Strumentazione scientifica
dell'Università di Pisa (C.I.S.U.P.), Università di Pisa, Pisa,
Italy
Jiří Sejkora
Department of Mineralogy and Petrology, National Museum, Cirkusová
1740, 193 00 Prague 9, Czech Republic
Zdeněk Dolníček
Department of Mineralogy and Petrology, National Museum, Cirkusová
1740, 193 00 Prague 9, Czech Republic
Radek Škoda
Department of Geological Sciences, Faculty of Science, Masaryk
University, Kotlářská 2, 611 37 Brno, Czech Republic
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Jonas Toupal, Daniela Mauro, Cristian Biagioni, Federica Zaccarini, and Reto Gieré
Eur. J. Mineral., 36, 1–10, https://doi.org/10.5194/ejm-36-1-2024, https://doi.org/10.5194/ejm-36-1-2024, 2024
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In this work, we refine the crystal structure of childrenite. Additionally, we provide compositional data to substantially extend the published solid-solution series between childrenite and eosphorite, the Fe and Mn endmembers, respectively. We analyze the valence state of iron to avoid erroneous classification of ernstite or potential discovery of "oxychildrenite", a mineral species not yet confirmed to be stable in nature.
Cristian Biagioni, Ferdinando Bosi, Daniela Mauro, Henrik Skogby, Andrea Dini, and Federica Zaccarini
Eur. J. Mineral., 35, 81–94, https://doi.org/10.5194/ejm-35-81-2023, https://doi.org/10.5194/ejm-35-81-2023, 2023
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Dutrowite is the first tourmaline supergroup minerals having Ti as a species-defining chemical constituent. Its finding improves our knowledge on the crystal chemistry of this important mineral group and allows us to achieve a better picture of the mechanisms favouring the incorporation of Ti.
Cristian Biagioni, Marco E. Ciriotti, Georges Favreau, Daniela Mauro, and Federica Zaccarini
Eur. J. Mineral., 34, 365–374, https://doi.org/10.5194/ejm-34-365-2022, https://doi.org/10.5194/ejm-34-365-2022, 2022
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The paper reports the type description of the new mineral species graulichite-(La). This is a new addition to the dussertite group within the alunite supergroup, and its discovery improves our knowledge on the crystal chemistry of this important supergroup of minerals, having both technological and environmental applications.
Daniela Mauro, Cristian Biagioni, and Federica Zaccarini
Eur. J. Mineral., 33, 717–726, https://doi.org/10.5194/ejm-33-717-2021, https://doi.org/10.5194/ejm-33-717-2021, 2021
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This work reports the full crystal-chemical characterization of gersdorffite from Contrada Zillì (Peloritani Mountains, Sicily, Italy). The structural type shown by gersdorffite (ordered polytype 213) and its chemistry agree with low-temperature crystallization conditions. Moreover, the chemical zoning of the studied crystals recorded changes in the crystallization physicochemical conditions. This zoning may be due to a multistage crystallization, related to the evolution of the ore deposits.
Jonas Toupal, Daniela Mauro, Cristian Biagioni, Federica Zaccarini, and Reto Gieré
Eur. J. Mineral., 36, 1–10, https://doi.org/10.5194/ejm-36-1-2024, https://doi.org/10.5194/ejm-36-1-2024, 2024
Short summary
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In this work, we refine the crystal structure of childrenite. Additionally, we provide compositional data to substantially extend the published solid-solution series between childrenite and eosphorite, the Fe and Mn endmembers, respectively. We analyze the valence state of iron to avoid erroneous classification of ernstite or potential discovery of "oxychildrenite", a mineral species not yet confirmed to be stable in nature.
Jiří Sejkora, Cristian Biagioni, Pavel Škácha, Silvia Musetti, Anatoly V. Kasatkin, and Fabrizio Nestola
Eur. J. Mineral., 35, 897–907, https://doi.org/10.5194/ejm-35-897-2023, https://doi.org/10.5194/ejm-35-897-2023, 2023
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We present the description of new mineral – a Cd-dominant member of the tetrahedrite group, tetrahedrite-(Cd), from the Radětice deposit near Příbram, Czech Republic. All necessary data including crystal structure were successfully determined, and the mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (number 2022-115).
Cristian Biagioni, Ferdinando Bosi, Daniela Mauro, Henrik Skogby, Andrea Dini, and Federica Zaccarini
Eur. J. Mineral., 35, 81–94, https://doi.org/10.5194/ejm-35-81-2023, https://doi.org/10.5194/ejm-35-81-2023, 2023
Short summary
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Dutrowite is the first tourmaline supergroup minerals having Ti as a species-defining chemical constituent. Its finding improves our knowledge on the crystal chemistry of this important mineral group and allows us to achieve a better picture of the mechanisms favouring the incorporation of Ti.
Cristian Biagioni, Marco E. Ciriotti, Georges Favreau, Daniela Mauro, and Federica Zaccarini
Eur. J. Mineral., 34, 365–374, https://doi.org/10.5194/ejm-34-365-2022, https://doi.org/10.5194/ejm-34-365-2022, 2022
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The paper reports the type description of the new mineral species graulichite-(La). This is a new addition to the dussertite group within the alunite supergroup, and its discovery improves our knowledge on the crystal chemistry of this important supergroup of minerals, having both technological and environmental applications.
Luboš Vrtiška, Jaromír Tvrdý, Jakub Plášil, Jiří Sejkora, Radek Škoda, Nikita V. Chukanov, Andreas Massanek, Jan Filip, Zdeněk Dolníček, and František Veselovský
Eur. J. Mineral., 34, 223–238, https://doi.org/10.5194/ejm-34-223-2022, https://doi.org/10.5194/ejm-34-223-2022, 2022
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The study of the original material of beraunite from the type locality Hrbek, Czech Rep., from collections of the TU Bergakademie Freiberg (Germany) and National Museum Prague (Czech Republic) proved the identity of the minerals beraunite and eleonorite. Because the name beraunite has priority, we consider the name eleonorite to be redundant and proposed to abolish it. The proposal 21-D approved by the IMA discredited eleonorite and accepted the formula of beraunite Fe3+6(PO4)4O(OH)4·6H2O.
Daniela Mauro, Cristian Biagioni, and Federica Zaccarini
Eur. J. Mineral., 33, 717–726, https://doi.org/10.5194/ejm-33-717-2021, https://doi.org/10.5194/ejm-33-717-2021, 2021
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This work reports the full crystal-chemical characterization of gersdorffite from Contrada Zillì (Peloritani Mountains, Sicily, Italy). The structural type shown by gersdorffite (ordered polytype 213) and its chemistry agree with low-temperature crystallization conditions. Moreover, the chemical zoning of the studied crystals recorded changes in the crystallization physicochemical conditions. This zoning may be due to a multistage crystallization, related to the evolution of the ore deposits.
Pavel Škácha, Jiří Sejkora, Jakub Plášil, Zdeněk Dolníček, and Jana Ulmanová
Eur. J. Mineral., 33, 175–187, https://doi.org/10.5194/ejm-33-175-2021, https://doi.org/10.5194/ejm-33-175-2021, 2021
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Grimmite, sulfide of cobalt and nickel, is the new mineral for the mineralogical system.
Yves Moëlo and Cristian Biagioni
Eur. J. Mineral., 32, 623–635, https://doi.org/10.5194/ejm-32-623-2020, https://doi.org/10.5194/ejm-32-623-2020, 2020
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The plagionite group is a family of complex sulfides (
lead-antimony sulfosalts) encountered in various Pb-Cu-Zn ore deposits. Analysis of these crystal structures confirms a systematic Pb-versus-Sb substitution in two adjacent cation positions. Such a substitution varies according not only to the Pb / Sb ratio of each member but also, apparently, to the kinetics of crystallization. Re-examination of a Pb-free synthetic derivative permitted its redefinition as a Na-Sb sulfosalt.
Related subject area
New minerals and systematic mineralogy
Mckelveyite group minerals – Part 3: Bainbridgeite-(YCe), Na2Ba2YCe(CO3)6 ⋅ 3H2O, a new species from Mont Saint-Hilaire, Canada
Heimite, PbCu2(AsO4)(OH)3 ⋅ 2H2O, a new mineral from the Grosses Chalttal deposit, Switzerland
OxyEMG: an application for determination of the oxyspinel group end-members based on electron microprobe analyses
Changes to the cerite group nomenclature
Tetrahedrite-(Cd), Cu6(Cu4Cd2)Sb4S13, from Radětice near Příbram, Czech Republic: the new Cd member of the tetrahedrite group
Crystal chemistry of type paulkerrite and establishment of the paulkerrite group nomenclature
Regerite, KFe6(PO4)4(OH)7(H2O)6 ⋅ 4H2O, the first new mineral species from the Kreuzberg pegmatite, Pleystein, Oberpfalz, Bavaria, Germany
Hochleitnerite, [K(H2O)]Mn2(Ti2Fe)(PO4)4O2(H2O)10 ⋅ 4H2O, a new paulkerrite-group mineral, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany
Nomenclature of the triphylite group of minerals
Pseudo-cubic trigonal pyrite from the Madan Pb–Zn ore field (Rhodope Massif, Bulgaria): morphology and twinning
Manganrockbridgeite, Mn2+2Fe3+3(PO4)3(OH)4(H2O), a new member of the rockbridgeite group, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria
Pleysteinite, [(H2O)0.5K0.5]2Mn2Al3(PO4)4F2(H2O)10 ⋅ 4H2O, the Al analogue of benyacarite, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany
Mckelveyite group minerals – Part 1: Nomenclature and new data on donnayite-(Y)
Mckelveyite group minerals – Part 2: Alicewilsonite-(YCe), Na2Sr2YCe(CO3)6 ⋅ 3H2O, a new species
Whiteite-(CaMnFe), a new jahnsite-group mineral from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria
Dutrowite, Na(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3O, a new mineral from the Apuan Alps (Tuscany, Italy): the first member of the tourmaline supergroup with Ti as a species-forming chemical constituent
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Ferri-taramite, a new member of the amphibole supergroup, from the Jakobsberg Mn–Fe deposit, Värmland, Sweden
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Tomsquarryite, NaMgAl3(PO4)2(OH)6 ● 8H2O, a new crandallite-derivative mineral from Tom's phosphate quarry, Kapunda, South Australia
Graulichite-(La), LaFe3+3(AsO4)2(OH)6, a new addition to the alunite supergroup from the Patte d'Oie mine, Bou Skour mining district, Morocco
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Redefinition of beraunite, Fe3+6(PO4)4O(OH)4 ⋅ 6H2O, and discreditation of the name eleonorite: a re-investigation of type material from the Hrbek Mine (Czech Republic)
Redefinition of angastonite, CaMgAl2(PO4)2(OH)4 ⋅ 7H2O, as an amorphous mineral
Liguowuite, WO3, a new member of the A-site vacant perovskite type minerals from the Panzhihua–Xichang region, China
Zinkgruvanite, Ba4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2, a new ericssonite-group mineral from the Zinkgruvan Zn-Pb-Ag-Cu deposit, Askersund, Örebro County, Sweden
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Gobelinite, the Co analogue of ktenasite from Cap Garonne, France, and Eisenzecher Zug, Germany
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Inna Lykova, Ralph Rowe, Glenn Poirier, Henrik Friis, and Kate Helwig
Eur. J. Mineral., 36, 183–194, https://doi.org/10.5194/ejm-36-183-2024, https://doi.org/10.5194/ejm-36-183-2024, 2024
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The new mckelveyite group mineral bainbridgeite-(YCe) was found at Mont Saint-Hilaire, Quebec, Canada.
Thomas Malcherek, Boriana Mihailova, Jochen Schlüter, Philippe Roth, and Nicolas Meisser
Eur. J. Mineral., 36, 153–164, https://doi.org/10.5194/ejm-36-153-2024, https://doi.org/10.5194/ejm-36-153-2024, 2024
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The new mineral heimite was originally discovered on the mine dumps of the Grosses Chalttal deposit, Mürtschenalp district, Glarus, Switzerland. Its relatively simple chemistry is formed by water and ions of lead, copper, arsenic, hydrogen and oxygen. The mineral's crystal structure is related to the well-known duftite, which is also observed to grow on crystals of heimite. While heimite has so far only been found in the central Alps, it is expected to occur in other copper deposits worldwide.
Gabriela R. Ferracutti, Lucía M. Asiain, Antonella S. Antonini, Juan E. Tanzola, and M. Luján Ganuza
Eur. J. Mineral., 36, 87–98, https://doi.org/10.5194/ejm-36-87-2024, https://doi.org/10.5194/ejm-36-87-2024, 2024
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The paper proposes an application called OxyEMG (Oxyspinel group End-Member Generator), which is an improved version of EMG. This tool allows for calculating the portions of 31 end-members of the oxyspinel group from data obtained with an electron microprobe. This is fundamental since this group of minerals is considered to be tectonic tracers; their integral composition should be taken into account and not only those end-members that make up the magnetite or ulvöspinel prisms.
Daniel Atencio, Andrezza A. Azzi, Kai Qu, Ritsuro Miyawaki, Ferdinando Bosi, and Koichi Momma
Eur. J. Mineral., 35, 1027–1030, https://doi.org/10.5194/ejm-35-1027-2023, https://doi.org/10.5194/ejm-35-1027-2023, 2023
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This article introduces a new nomenclature system for the cerite group minerals. This system was necessary to allow the nomenclature of new species of minerals that are currently being described.
Jiří Sejkora, Cristian Biagioni, Pavel Škácha, Silvia Musetti, Anatoly V. Kasatkin, and Fabrizio Nestola
Eur. J. Mineral., 35, 897–907, https://doi.org/10.5194/ejm-35-897-2023, https://doi.org/10.5194/ejm-35-897-2023, 2023
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We present the description of new mineral – a Cd-dominant member of the tetrahedrite group, tetrahedrite-(Cd), from the Radětice deposit near Příbram, Czech Republic. All necessary data including crystal structure were successfully determined, and the mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (number 2022-115).
Ian E. Grey, Stephanie Boer, Colin M. MacRae, Nicholas C. Wilson, William G. Mumme, and Ferdinando Bosi
Eur. J. Mineral., 35, 909–919, https://doi.org/10.5194/ejm-35-909-2023, https://doi.org/10.5194/ejm-35-909-2023, 2023
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The paper describes the formal establishment of the paulkerrite group of minerals and its nomenclature. It includes the application of a site-merging procedure, coupled with a site-total-charge analysis, to obtain unambiguous end-member formulae. Application of the procedure has resulted in the revision of the end-member formulae for several of the group members.
Christian Rewitzer, Rupert Hochleitner, Ian E. Grey, Anthony R. Kampf, Stephanie Boer, and Colin M. MacRae
Eur. J. Mineral., 35, 805–812, https://doi.org/10.5194/ejm-35-805-2023, https://doi.org/10.5194/ejm-35-805-2023, 2023
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Regerite is the first new mineral species to be described from the Kreuzberg pegmatite, Pleystein, in the Oberpfalz, Bavaria. It has been characterised using electron microprobe analysis, Raman spectroscopy, optical measurements and a synchrotron-based single-crystal structure refinement. The structure type for regerite has not been previously reported.
Ian E. Grey, Erich Keck, Anthony R. Kampf, Colin M. MacRae, Robert W. Gable, William G. Mumme, Nicholas C. Wilson, Alexander M. Glenn, and Cameron Davidson
Eur. J. Mineral., 35, 635–643, https://doi.org/10.5194/ejm-35-635-2023, https://doi.org/10.5194/ejm-35-635-2023, 2023
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Hochleitnerite is a new member of the paulkerrite group of minerals. Its crystal structure, chemical analyses and Raman spectroscopy are reported, and its crystallochemical properties are discussed in relation to other group members.
Lyudmila M. Lyalina, Ekaterina A. Selivanova, and Frédéric Hatert
Eur. J. Mineral., 35, 427–437, https://doi.org/10.5194/ejm-35-427-2023, https://doi.org/10.5194/ejm-35-427-2023, 2023
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There are unresolved problems related to the nomenclature and identification of mineral species belonging to the triphylite group of minerals. They can be solved by discarding the traditional views on succession of mineral species during oxidation. In other words, it is necessary to separate the concepts of the origin of the mineral and the boundaries of the species.
Yves Moëlo
Eur. J. Mineral., 35, 333–346, https://doi.org/10.5194/ejm-35-333-2023, https://doi.org/10.5194/ejm-35-333-2023, 2023
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Pyrite crystals with rhombohedral morphology have been known for a long time and were considered up to now as curiosities. The morphological study of well-crystallized, centimeter-sized crystals, often twinned, from the Madan Pb–Zn ore field permitted us to define such a pyrite variety as a pseudo-cubic trigonal derivative of pyrite.
Ian E. Grey, Rupert Hochleitner, Anthony R. Kampf, Stephanie Boer, Colin M. MacRae, John D. Cashion, Christian Rewitzer, and William G. Mumme
Eur. J. Mineral., 35, 295–304, https://doi.org/10.5194/ejm-35-295-2023, https://doi.org/10.5194/ejm-35-295-2023, 2023
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Manganrockbridgeite, Mn2+2Fe3+3(PO4)3(OH)4(H2O), a new member of the rockbridgeite group, has been characterised using electron microprobe analyses, Mössbauer spectroscopy, optical properties and single-crystal X-ray diffraction. Whereas other rockbridgeite-group minerals have orthorhombic symmetry with a statistical distribution of 50%Fe3+/50% vacancies in M3-site octahedra, monoclinic manganrockbridgeite has full ordering of Fe3+ and vacancies in alternate M3 sites along the 5.2 Å axis.
Ian E. Grey, Rupert Hochleitner, Christian Rewitzer, Anthony R. Kampf, Colin M. MacRae, Robert W. Gable, William G. Mumme, Erich Keck, and Cameron Davidson
Eur. J. Mineral., 35, 189–197, https://doi.org/10.5194/ejm-35-189-2023, https://doi.org/10.5194/ejm-35-189-2023, 2023
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Pleysteinite has been approved as a new mineral species, and we describe here the characterisation of the mineral and its relationship to related minerals benyacarite, paulkerrite and mantienneite. The characterisation includes the determination and refinement of the crystal structure, electron microprobe analyses, optical properties and interpretation of its Raman spectrum.
Inna Lykova, Ralph Rowe, Glenn Poirier, Gerald Giester, Kelsie Ojaste, and Henrik Friis
Eur. J. Mineral., 35, 133–142, https://doi.org/10.5194/ejm-35-133-2023, https://doi.org/10.5194/ejm-35-133-2023, 2023
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A new mineral group – the mckelveyite group – consisting of seven carbonate minerals was established. One of the seven members, donnayite-(Y), was re-investigated and its belonging to the mckelveyite group was confirmed.
Inna Lykova, Ralph Rowe, Glenn Poirier, Henrik Friis, and Kate Helwig
Eur. J. Mineral., 35, 143–155, https://doi.org/10.5194/ejm-35-143-2023, https://doi.org/10.5194/ejm-35-143-2023, 2023
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Alicewilsonite-(YCe), a new mckelveyite group, was found at Mont Saint-Hilaire, Quebec, Canada, and subsequently at the Saint-Amable sill, Quebec, Canada, and the Khibiny Massif, Kola Peninsula, Russia.
Rupert Hochleitner, Christian Rewitzer, Ian E. Grey, William G. Mumme, Colin M. MacRae, Anthony R. Kampf, Erich Keck, Robert W. Gable, and Alexander M. Glenn
Eur. J. Mineral., 35, 95–103, https://doi.org/10.5194/ejm-35-95-2023, https://doi.org/10.5194/ejm-35-95-2023, 2023
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The paper gives a characterisation of the new mineral species, whiteite-(CaMnFe), which has recently been approved as a new mineral (proposal IMA2022-077). The study included a single-crystal structure refinement that, when combined with electron microprobe analyses, confirmed that the mineral was a new member of the whiteite subgroup of the jahnsite group of minerals. Relationships between the crystal structure and the unit-cell parameters for the whiteite-subgroup minerals are discussed.
Cristian Biagioni, Ferdinando Bosi, Daniela Mauro, Henrik Skogby, Andrea Dini, and Federica Zaccarini
Eur. J. Mineral., 35, 81–94, https://doi.org/10.5194/ejm-35-81-2023, https://doi.org/10.5194/ejm-35-81-2023, 2023
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Dutrowite is the first tourmaline supergroup minerals having Ti as a species-defining chemical constituent. Its finding improves our knowledge on the crystal chemistry of this important mineral group and allows us to achieve a better picture of the mechanisms favouring the incorporation of Ti.
Chengyang Sun, Taijin Lu, Mingyue He, Zhonghua Song, and Yi Deng
Eur. J. Mineral., 34, 539–547, https://doi.org/10.5194/ejm-34-539-2022, https://doi.org/10.5194/ejm-34-539-2022, 2022
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It was determined that growth bands showing the straight birefringence in octahedral sectors and the enrichment of graphite inclusions in cuboid sectors of Zimbabwean mixed-habit diamonds may both be due to the fluctuation of temperature during crystallization, and they displayed positive anomalies of plastic deformation, residual stress, nitrogen concentration, and VN3H defects. This conclusion clearly revealed the correlation between birefringence and spectroscopic properties of diamonds.
Derek D. V. Leung and Paige E. dePolo
Eur. J. Mineral., 34, 523–538, https://doi.org/10.5194/ejm-34-523-2022, https://doi.org/10.5194/ejm-34-523-2022, 2022
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Minerals have complex crystal structures, but many common minerals are built from the same chemical building blocks. TotBlocks is a novel, open-source tool for investigating these structures. It consists of 3D-printed modules representing the silica tetrahedra and metal–oxygen octahedra that form the shared chemical building blocks of rock-forming minerals. TotBlocks is a low-cost visualization tool that relates mineral properties (habit, cleavage, and symmetry) to crystal structures.
Dan Holtstam, Fernando Cámara, Andreas Karlsson, Henrik Skogby, and Thomas Zack
Eur. J. Mineral., 34, 451–462, https://doi.org/10.5194/ejm-34-451-2022, https://doi.org/10.5194/ejm-34-451-2022, 2022
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A new mineral has been discovered, an amphibole, with the name ferri-taramite, which has now been approved by the International Mineralogical Association. The paper discusses the significance of the discovery in relation to other amphiboles found worldwide. This taramite is unique in that it is from a skarn associated with ore and is not of magmatic origin. For the description we have used many methods, including X-ray diffraction, chemical analyses and several types of spectroscopy.
Mariko Nagashima, Teruyoshi Imaoka, Takashi Kano, Jun-ichi Kimura, Qing Chang, and Takashi Matsumoto
Eur. J. Mineral., 34, 425–438, https://doi.org/10.5194/ejm-34-425-2022, https://doi.org/10.5194/ejm-34-425-2022, 2022
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Ferro-ferri-holmquistite (IMA2022-020), ideal formula ☐Li2(Fe32+Fe23+)Si8O22(OH)2, was found in albitized granite from the Iwagi islet, Ehime, Japan. It is a Fe2+Fe3+ analogue of holmquistite and belongs to the lithium subgroup amphiboles. Ferro-ferri-holmquistite occurs as blue acicular crystals typically replacing the biotite and is the product of metasomatic mineral replacement reactions by dissolution–reprecipitation processes associated with Na- and Li-rich hydrothermal fluids.
Peter Elliott, Ian E. Grey, William G. Mumme, Colin M. MacRae, and Anthony R. Kampf
Eur. J. Mineral., 34, 375–383, https://doi.org/10.5194/ejm-34-375-2022, https://doi.org/10.5194/ejm-34-375-2022, 2022
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This paper describes the characterisation of a new mineral from a South Australian phosphate quarry. The characterisation included chemical analyses, infrared spectroscopy, and a determination and refinement of the crystal structure. The results showed that the mineral has a unique crystal chemistry, but it is closely related to the well-known phosphate mineral crandallite.
Cristian Biagioni, Marco E. Ciriotti, Georges Favreau, Daniela Mauro, and Federica Zaccarini
Eur. J. Mineral., 34, 365–374, https://doi.org/10.5194/ejm-34-365-2022, https://doi.org/10.5194/ejm-34-365-2022, 2022
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The paper reports the type description of the new mineral species graulichite-(La). This is a new addition to the dussertite group within the alunite supergroup, and its discovery improves our knowledge on the crystal chemistry of this important supergroup of minerals, having both technological and environmental applications.
Frank de Wit and Stuart J. Mills
Eur. J. Mineral., 34, 321–324, https://doi.org/10.5194/ejm-34-321-2022, https://doi.org/10.5194/ejm-34-321-2022, 2022
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The name sigismundite has been reinstated for what was previously arrojadite-(BaFe). Sigismundite honours Pietro Sigismund (1874–1962), and this paper outlines his significant contributions to Italian mineralogy.
Luboš Vrtiška, Jaromír Tvrdý, Jakub Plášil, Jiří Sejkora, Radek Škoda, Nikita V. Chukanov, Andreas Massanek, Jan Filip, Zdeněk Dolníček, and František Veselovský
Eur. J. Mineral., 34, 223–238, https://doi.org/10.5194/ejm-34-223-2022, https://doi.org/10.5194/ejm-34-223-2022, 2022
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The study of the original material of beraunite from the type locality Hrbek, Czech Rep., from collections of the TU Bergakademie Freiberg (Germany) and National Museum Prague (Czech Republic) proved the identity of the minerals beraunite and eleonorite. Because the name beraunite has priority, we consider the name eleonorite to be redundant and proposed to abolish it. The proposal 21-D approved by the IMA discredited eleonorite and accepted the formula of beraunite Fe3+6(PO4)4O(OH)4·6H2O.
Ian Edward Grey, Peter Elliott, William Gus Mumme, Colin M. MacRae, Anthony R. Kampf, and Stuart J. Mills
Eur. J. Mineral., 34, 215–221, https://doi.org/10.5194/ejm-34-215-2022, https://doi.org/10.5194/ejm-34-215-2022, 2022
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A reinvestigation of angastonite from the type locality has shown that it is a mixture of crystalline phases and an amorphous phase, with the published formula corresponding to the amorphous phase. A redefinition proposal for angastonite as an amorphous mineral was approved by the IMA CNMNC. Our study showed how the amorphous phase formed and how it progressively recrystallises as new crandallite-related minerals.
Yuan Xue, Ningyue Sun, Hongping He, Aiqing Chen, and Yiping Yang
Eur. J. Mineral., 34, 95–108, https://doi.org/10.5194/ejm-34-95-2022, https://doi.org/10.5194/ejm-34-95-2022, 2022
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Liguowuite, a new member of the non-stoichiometric perovskite group minerals, ideally WO3, has been found in the Panzhihua–Xichang region, China. Liguowuite is monoclinic and is in space group P21 / n, with a = 7.32582(18) Å, b = 7.54767(18) Å, c = 7.71128(18) Å, β = 90.678(3)°, V = 426.348(19) Å3, and Z = 8. According to the hierarchical scheme for perovskite supergroup minerals, liguowuite is the first reported example of A-site vacant single oxide, i.e., a new perovskite subgroup.
Fernando Cámara, Dan Holtstam, Nils Jansson, Erik Jonsson, Andreas Karlsson, Jörgen Langhof, Jaroslaw Majka, and Anders Zetterqvist
Eur. J. Mineral., 33, 659–673, https://doi.org/10.5194/ejm-33-659-2021, https://doi.org/10.5194/ejm-33-659-2021, 2021
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Zinkgruvanite, a barium manganese iron silicate with sulfate, is a new mineral found in drill core samples from the Zinkgruvan zinc, lead and silver mine in Sweden. It is associated with other minerals like baryte, barytocalcite, diopside and sulfide minerals. It occurs as flattened and elongated crystals up to 1 mm. It is almost black. Zinkgruvanite is closely related to the mineral yoshimuraite and based on its crystal structure, grouped with the ericssonite group of minerals.
Biljana Krüger, Evgeny V. Galuskin, Irina O. Galuskina, Hannes Krüger, and Yevgeny Vapnik
Eur. J. Mineral., 33, 341–355, https://doi.org/10.5194/ejm-33-341-2021, https://doi.org/10.5194/ejm-33-341-2021, 2021
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This is the first description of the new mineral kahlenbergite, found in the Hatrurim Basin, Israel, which is a region with unusual pyrometamorphic rocks. Kahlenbergite is chemically and structurally characterized. It is very similar to β-alumina compounds, which are synthetic materials known for their properties as fast ion conductors. Research in the Hatrurim Basin is needed to understand the complex mechanisms that created this mineralogically diverse
hotspotof new minerals.
Antonia Cepedal, Mercedes Fuertes-Fuente, and Agustín Martin-Izard
Eur. J. Mineral., 33, 165–174, https://doi.org/10.5194/ejm-33-165-2021, https://doi.org/10.5194/ejm-33-165-2021, 2021
Pavel Škácha, Jiří Sejkora, Jakub Plášil, Zdeněk Dolníček, and Jana Ulmanová
Eur. J. Mineral., 33, 175–187, https://doi.org/10.5194/ejm-33-175-2021, https://doi.org/10.5194/ejm-33-175-2021, 2021
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Grimmite, sulfide of cobalt and nickel, is the new mineral for the mineralogical system.
Thomas Witzke, Martin Schreyer, Benjamin Brandes, René Csuk, and Herbert Pöllmann
Eur. J. Mineral., 33, 1–8, https://doi.org/10.5194/ejm-33-1-2021, https://doi.org/10.5194/ejm-33-1-2021, 2021
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The new mineral species freitalite, C14H10, corresponding to the aromatic hydrocarbon anthracene, has been discovered on the mine dump of the Königin Carola shaft (Paul Berndt Mine), Freital, near Dresden, Saxony, Germany. Freitalite is a product of pyrolysis of coal and was formed by sublimation from a gas phase. The mineral was identified by several analytical methods.
Stuart J. Mills, Uwe Kolitsch, Georges Favreau, William D. Birch, Valérie Galea-Clolus, and Johannes Markus Henrich
Eur. J. Mineral., 32, 637–644, https://doi.org/10.5194/ejm-32-637-2020, https://doi.org/10.5194/ejm-32-637-2020, 2020
Fahui Xiong, Xiangzhen Xu, Enrico Mugnaioli, Mauro Gemmi, Richard Wirth, Edward S. Grew, Paul T. Robinson, and Jingsui Yang
Eur. J. Mineral., 32, 557–574, https://doi.org/10.5194/ejm-32-557-2020, https://doi.org/10.5194/ejm-32-557-2020, 2020
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Two new nanominerals: titanium monophosphide and titanium disilicide, formed at pressures of Earth’s upper mantle by the action of methane and hydrogen from the mantle on basaltic melts in the Luobusa ophiolite (Tibet). The minerals were characterized by 3D electron diffraction, which can solve the crystal structures of phases less than a micrometer in size. The results contribute to our understanding of deeply subducted crustal rocks and their exhumation back to the Earth's surface.
Yuan Xue, Guowu Li, and Yingmei Xie
Eur. J. Mineral., 32, 483–494, https://doi.org/10.5194/ejm-32-483-2020, https://doi.org/10.5194/ejm-32-483-2020, 2020
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Wumuite, ideally KAl0.33W2.67O9 with a hexagonal tungsten bronze (HTB)-type structure, is another new mineral containing potassium and tungsten found in the Pan–Xi region in China after tewite was discovered. In this study, artificial synthetic experiments have been conducted to explore the formation process of wumuite and tewite. Wumuite was speculated to be formed by a metasomatic reaction between W-rich hydrothermal fluids and the potassium feldspar in the monzonite.
Simon Philippo, Frédéric Hatert, Yannick Bruni, Pietro Vignola, and Jiří Sejkora
Eur. J. Mineral., 32, 449–455, https://doi.org/10.5194/ejm-32-449-2020, https://doi.org/10.5194/ejm-32-449-2020, 2020
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Luxembourgite, ideally AgCuPbBi4Se8, is a new selenide discovered at Bivels, Grand Duchy of Luxembourg. The mineral forms tiny fibres deposited on dolomite crystals. Its crystal structure is similar to those of litochlebite and watkinsonite, and can be described as an alternation of two types of anionic layers: a pseudotetragonal layer four atoms thick and a pseudohexagonal layer one atom thick. The species named for the city of Luxembourg, close to its locality of discovery.
Anthony R. Kampf, Barbara P. Nash, Jakub Plášil, Jason B. Smith, and Mark N. Feinglos
Eur. J. Mineral., 32, 373–385, https://doi.org/10.5194/ejm-32-373-2020, https://doi.org/10.5194/ejm-32-373-2020, 2020
Cristiano Ferraris, Isabella Pignatelli, Fernando Cámara, Giancarlo Parodi, Sylvain Pont, Martin Schreyer, and Fengxia Wei
Eur. J. Mineral., 32, 355–365, https://doi.org/10.5194/ejm-32-355-2020, https://doi.org/10.5194/ejm-32-355-2020, 2020
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Laurentthomasite is a new mineral from Madagascar showing a very strong dichroism going from deep blue to yellow-green colours. The physical and chemical characteristics of this gem quality mineral bring it to the attention of the jewel industry as well as collectors of cut stones.
Elena Bonaccorsi and Paolo Orlandi
Eur. J. Mineral., 32, 347–354, https://doi.org/10.5194/ejm-32-347-2020, https://doi.org/10.5194/ejm-32-347-2020, 2020
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Molybdates are of a great interest due to their ionic conductivity, negative thermal expansion, and immobilization of radionuclides. The new mineral tancaite-(Ce), FeCe(MoO4)3•3H2O, shows a new structure type never observed in natural and synthetic molybdates. Its cubic average structure may be described as a derivative of the perovskite structure, in which Fe-centred octahedra are linked through MoO4 groups. The ordering of Mo and O atoms results in one or more complex superstructures.
Natale Perchiazzi, Ulf Hålenius, Nicola Demitri, and Pietro Vignola
Eur. J. Mineral., 32, 265–273, https://doi.org/10.5194/ejm-32-265-2020, https://doi.org/10.5194/ejm-32-265-2020, 2020
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Type material for heliophyllite, preserved in the Swedish Museum of Natural History in Stockholm, was re-investigated through a combined EPMA (electron probe X-ray microanalysis), Raman, and X-ray powder diffraction (XRPD) and single-crystal study. EPMA chemical data, together with Raman and single-crystal structural studies, point to heliophyllite being identical to ecdemite. XRPD synchrotron data highlight the presence of a minor quantity of finely admixed finnemanite in the analyzed material.
Jan Parafiniuk and Frédéric Hatert
Eur. J. Mineral., 32, 215–217, https://doi.org/10.5194/ejm-32-215-2020, https://doi.org/10.5194/ejm-32-215-2020, 2020
Ekaterina Kaneva, Tatiana Radomskaya, Ludmila Suvorova, Irina Sterkhova, and Mikhail Mitichkin
Eur. J. Mineral., 32, 137–146, https://doi.org/10.5194/ejm-32-137-2020, https://doi.org/10.5194/ejm-32-137-2020, 2020
Tomas Husdal, Ian E. Grey, Henrik Friis, Fabrice Dal Bo, Anthony R. Kampf, Colin M. MacRae, W. Gus Mumme, Ole-Thorstein Ljøstad, and Finlay Shanks
Eur. J. Mineral., 32, 89–98, https://doi.org/10.5194/ejm-32-89-2020, https://doi.org/10.5194/ejm-32-89-2020, 2020
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This paper describes the characterization of a new mineral from the Oumlil mine in the Bou Azzer cobalt mining district in Morocco. This mining district is one of the world's largest producers of the important element cobalt. This study on the new mineral halilsarpite provides useful information on the results of chemical weathering processes on the primary arsenide minerals at the mine.
Cited articles
Basset, H. and Goodwin, T. H.: The basic aluminum sulphates, J. Chem. Soc.,
1949, 2239–2279, 1949.
Bayliss, P., Kolitsch, U., Nickel, E. H., and Pring, A.: Alunite supergroup:
recommended nomenclature, Mineral. Mag., 74, 919–927, 2010.
Belluomini, G., Fornaseri, M., and Nicoletti, M.: Onoratoite, a new antimony
oxychloride from Cetine di Cotorniano, Rosia (Siena, Italy), Mineral. Mag.,
36, 1037–1044, 1968.
Beukes, G. J., Schoch, A. E., de Bruiyn, H., van der Westhuizen, W. A., and Bok,
L. D. C.: A new occurrence of the hydrated aluminium sulphate zaherite, from
Pofadder, South Africa, Mineral. Mag., 48, 131–135, 1984.
Biagioni, C., Pasero, M., and Zaccarini, F.: Tiberiobardiite,
Cu9Al(SiO3OH)(OH)12(H2O)6(SO4)1.5 ⋅ 10H2O, a new mineral related to chalcophyllite from the Cretaio Cu
prospect, Massa Marittima, Grosseto (Tuscany, Italy): Occurrence and crystal
structure, Minerals, 8, 152, https://doi.org/10.3390/min8040152, 2018.
Biagioni, C., Bindi, L., and Kampf, A. R.: Crystal-chemistry of sulfates from
the Apuan Alps (Tuscany, Italy), VII. Magnanelliite,
KFe
Biagioni, C., Bindi, L., Mauro, D., and Hålenius, U.: Crystal chemistry
of sulfates from the Apuan Alps (Tuscany, Italy), V. Scordariite,
K8(Fe
Biagioni, C., Bindi, L., Mauro, D., and Pasero, M.: Crystal-chemistry of
sulfates from the Apuan Alps (Tuscany, Italy), IV. Giacovazzoite,
K5Fe
Biagioni, C., Mauro, D., and Pasero, M.: Sulfates from the pyrite ore
deposits of the Apuan Alps (Tuscany, Italy): A review, Minerals, 10, 1092, https://doi.org/10.3390/min10121092,
2020b.
Bigham, J. and Nordstrom, D. K.: Iron and aluminum hydroxysulfates from acid
sulfate waters, Rev. Mineral. Geochem., 40, 351–403, 2000.
Brese, N. E. and O'Keeffe, M.: Bond-valence parameters for solids, Acta
Crystallogr. B, 47, 192–197, 1991.
Bruker AXS Inc.: APEX4, Bruker Advanced X–ray Solutions, Madison,
Wisconsin, USA, 2022.
Casey, W. H.: Large aqueous aluminum hydroxide molecules, Chem. Rev., 106,
1–16, 2006.
Casey, W. H., Olmstead, M. M., and Phillips, B. L.: A new aluminum hydroxide
octamer, [Al8(OH)14(H2O)18](SO4)5 ⋅ 16H2O, Inorg. Chem., 44, 4888–4890, 2005.
Čech, F.: Rostite, a new name for orthorhombic
Al(SO4)(OH) ⋅ 5H2O, N. Jb. Miner., Mh., 1979, 193–196,
1979.
Čejka, J., Sejkora, J., Plášil, J., Bahfenne, S., Palmer, S. J.,
and Frost, R. L.: A vibrational spectroscopic study of hydrated Fe3+
hydroxyl-sulfates; polymorphic minerals butlerite and parabutlerite,
Spectrochim. Acta A., 79, 1356–1363, 2011.
Chou, I.-M., Seal II, R. R., and Wang, A.: The stability of sulfate and
hydrated sulfate minerals near ambient conditions and their significance in
environmental and planetary sciences, J. Asian Earth Sci., 62, 734–758,
2013.
Chukanov, N. V., Aksenov, S. M., Rastsvetaeva, R. K., Kampf, A. R., Möhn,
G., Belakovskiy, D. I., and Lorenz, J. A.: Riotintoite,
Al(SO4)(OH) ⋅ 3H2O, a new mineral from La Vendida copper
mine, Antofagasta region, Chile, Can. Mineral., 54, 1293–1305, 2016.
Clayton, T.: Hydrobasaluminite and basaluminite from Chickerell, Dorset,
Mineral. Mag., 43, 931–937, 1980.
Dahmen, T. and Gruehn, R.: Beiträge zum thermischen Verhalten von
Sulfaten, IX. Einkristallstrukturverfeinerung der Metall(III)-sulfate
Cr2(SO4)3 und Al2(SO4)3, Z. Kristallogr., 204,
57–65, 1993.
de Bruyin, H., Schoch, A. E., Beukes, G. J., Bok, L. D. C., and van der
Westhuizen, W. A.: Note on cell parameters of zaherite, Mineral. Mag., 49,
145–146, 1985.
Dini, A.: Ore deposits, industrial minerals and geothermal resources, Per.
Mineral., 72, 41–52, 2003.
Fang, J. H. and Robinson, P. D.: Alunogen,
Al2(H2O)12(SO4)3 ⋅ 5H2O: Its atomic
arrangement and water content, Am. Mineral., 61, 311–317, 1976.
Farkas, L. and Pertlik, F.: Crystal structure determinations of
felsőbányaite and basaluminite,
Al4(SO4)(OH)10 ⋅ 4H2O, Acta Mineral. Petrogr.,
38, 5–15, 1997.
Farkas, L. and Werner, P.-E.: Powder diffraction studies on aluminite and
meta-aluminite, Z. Kristallogr., 151, 141–152, 1980.
Ferraris G. and Franchini-Angela, M.: Survey of the geometry and environment
of water molecules in crystalline hydrates studied by neutron diffraction,
Acta Crystallogr. B, 28, 3572–3583, 1972.
Ferraris, G. and Ivaldi, G.: Bond valence vs bond length in O⋯O hydrogen bonds, Acta Crystallogr. B, 44, 341–344,
1988.
Frondel, C.: Meta-aluminite, a new mineral from Temple Mountain, Utah, Am.
Mineral., 53, 717–721, 1968.
Gamyanin, G. M., Zhdanov, Y. Y., Zayakina, N. V., Gamyanina, V. F., and Suknev,
V. S.: Mangazeite, Al2(SO4)(OH)4 ⋅ 3H2O – a new
mineral, Zap. Ross. Mineral. Obsh., 135, 20–24, 2006 (in Russian).
Hawthorne, F. C.: Towards a structural classification of minerals: the
viMivT2Øn minerals, Am. Mineral., 70, 455–473, 1985.
Hawthorne, F. C., Krivovichev, S. V., and Burns, P. C.: The crystal chemistry of
sulfate minerals, Rev. Mineral. Geochem., 40, 1–112, 2000.
Kahlenberg, V., Braun, D. E., Krüger, H., Schmidmair, D., and Orlova, M.:
Temperature- and moisture-dependent studies on alunogen and the crystal
structure of meta-alunogen determined from laboratory powder diffraction
data, Phys. Chem. Mineral., 44, 95–107, 2017.
Kampf, A. R., Cooper, M. A., Hughes, J. M., Nash, B. P., Hawthorne, F. C., and
Marty, J.: Caseyite, a new mineral containing a variant of the
flat-Al13 polyoxometalate cation, Am. Mineral., 105, 123–131, 2020.
Kampf, A. R., Cooper, M. A., Hughes, J. M., Ma, C., Casey, W. H., Hawthorne,
F. C., and Marty, J.: Protocaseyite, a new decavanate mineral containing a
[Al4(OH)6(H2O)12]6+ linear tetramer, a novel
isopolycation, Am. Mineral., 107, 1181–1189, 2022.
Krivovichev, S. V.: Polyoxometalate clusters in minerals: review and
complexity analysis, Acta Crystallogr. B, 76, 618–629, 2020.
Lattanzi, P.: Epithermal precious metal deposits of Italy – an overview,
Miner. Dep., 34, 630–638, 1999.
Lepore, G. O., Bindi, L., Di Benedetto, F., Mugnaioli, E., Viti, C., Zanetti,
A., Ciriotti, M. E., and Bonazzi, P.: A multimethodic approach for the
characterization of manganiceladonite, a new member of the celadonite family
from Cerchiara mine, Eastern Liguria, Italy, Mineral. Mag., 81, 167–173,
2017.
Libowitzky, E.: Correlation of O–H stretching frequencies and
O–H⋯O hydrogen bond lengths in minerals,
Monat. Chem., 130, 1047–1059, 1999.
Manasse, E.: Melanteria e fibroferrite delle Cetine (Siena), Atti Soc. Tosc.
Sci. Nat., Proc. Verb., 17, 51–56, 1908.
Mandarino, J. A.: The Gladstone-Dale relationship, Part III. Some general
applications, Can. Mineral., 17, 71–76, 1979.
Mandarino, J. A.: The Gladstone-Dale relationship, Part IV. The compatibility
concept and some application, Can. Mineral., 19, 441–450, 1981.
Martin, R., Rodgers, K. A., and Browne, P. R. L.: The nature and significance of
sulphate-rich, aluminous efflorescences from the Te Kopia geothermal field,
Taupo Volcanic Zone, New Zealand, Mineral. Mag., 63, 413–419, 1999.
Mauro, D. and Biagioni, C.: New crystal-structure data on bohuslavite,
Fe3+(PO4)3(SO4)(OH)(H2O)10 ⋅ nH2O, Minerals, 13, 286, https://doi.org/10.3390/min13020286, 2023.
Mauro, D., Biagioni, C., Bonaccorsi, E., Hålenius, U., Pasero, M.,
Skogby, H., Zaccarini, F., Sejkora, J., Plášil, J., Kampf, A.R.,
Filip, J., Novotný, P., Škoda, R., and Witzke, T.: Bohuslavite,
Fe3+(PO4)3(SO4)(OH)(H2O)10 ⋅ nH2O, a new hydrated iron phosphate-sulfate, Eur. J. Mineral., 31, 1033–1046, 2019.
Mauro, D., Biagioni, C., Pasero, M., and Zaccarini, F.: Crystal-chemistry of
sulfates from the Apuan Alps, Tuscany, Italy. VIII. New data on khademite,
Al(SO4)F(H2O)5, Mineral. Mag., 84, 540–546, 2020.
Menchetti, S. and Sabelli, C.: Alunogen. Its structure and twinning,
Tschermaks Mineral. Petrogr. Mitt., 21, 164–178, 1974.
Menchetti, S. and Batoni, M.: Le Cetine di Cotorniano, Miniera &
Minerali. Associazione Micro-mineralogica Italiana, Cremona, 353 pp., ISBN 978-88-905541-3-1, 2015.
Myneni, S. C.: X-ray and vibrational spectroscopy of sulfate in earth
materials, Rev. Mineral. Geochem., 40, 113–172, 2020.
Nakamoto, K.: Infrared and Raman spectra of inorganic and coordination
compounds Part A: Theory and application in inorganic chemistry, John Wiley
and Sons, Hoboken New Jersey, 419 pp., https://doi.org/10.1002/9780470405840, 2009.
Olmi, F. and Sabelli, C.: Brizziite, NaSbO3, a new mineral from the
Cetine mine (Tuscany, Italy): description and crystal structure, Eur. J.
Mineral., 6, 667–672, 1994.
Olmi, F., Sabelli, C., and Trosti-Ferroni, R.: Rosenbergite,
AlF[F0.5(H2O)0.5]4 ⋅ H2O, a new mineral
from the Cetine mine (Tuscany, Italy): description and crystal structure,
Eur. J. Mineral., 5, 1167–1174, 1993.
Panichi, U.: Millosevichite, nuovo minerale del Faraglione di Levante
nell'Isola di Vulcano, Rend. Accad. Naz. Lincei Cl. Sci. Fis. Mat. Nat., 22,
303–303, 1913.
Perkins, C. K., Eitrheim, E. S., Fulton, B. L., Fullmer, L. B., Colla, C. A.,
Park, D. H., Oliveri, A. F., Hutchison, J. E., Nyman, M., Casey, W. H., Forbes,
T. Z., Johnson, D. W., and Keszler, D. A.: Synthesis of an aluminum hydroxide
octamer through a simple dissolution method, Ang. Chem., 56, 10161–10164,
2017.
Pouchou, J. L. and Pichoir, F.: “PAP” (φρZ) procedure for
improved quantitative microanalysis, in: Microbeam Analysis, edited by:
Armstrong, J. T., San Francisco Press, San Francisco, 104–106, 1985.
Sabelli, C.: I minerali delle Cetine di Cotorniano (SI): i solfati dimorfi
jurbanite e rostite, Per. Mineral., 53, 53–65, 1984.
Sabelli, C.: Refinement of the crystal structure of jurbanite,
Al(SO4)(OH) ⋅ 5H2O, Z. Kristallogr., 173, 33–39, 1985a.
Sabelli, C.: Uklonskovite, NaMg(SO4)F ⋅ 2H2O: new
mineralogical data and structure refinement, Bull. Minéral., 108,
133–138, 1985b.
Sabelli, C. and Brizzi, G.: Alteration minerals of the Cetine mine, Tuscany,
Italy, Mineral. Rec., 15, 27–36, 1984.
Sabelli, C. and Santucci, A.: Rare sulfates from the Cetine mine, Tuscany,
Italy, N. Jb. Miner., Mt., 1987, 171–182, 1987.
Sabelli, C. and Trosti Ferroni, R.: The crystal structure of aluminite, Acta
Crystallogr. B, 34, 2407–2412, 1978.
Sabelli, C. and Vezzalini, G.: Cetineite, a new antimony oxide-sulfide
mineral from Cetine mine, Tuscany, Italy, N. Jb. Miner. Mh., 1987, 419–425,
1987.
Schindler, M. and Hawthorne, F. C.: A bond-valence approach to the structure,
chemistry and paragenesis of hydroxy-hydrated oxysalt minerals, I. Theory,
Can. Mineral., 39, 1225–1242, 2001.
Schmetzer, K., Ottemann, J., and Bank, H.: Schlossmacherit,
(H3O,Ca)Al3[(OH)6|((S,As)O4)2], ein neues
Mineral der Alunit-Jarosit Reihe, N. Jb. Miner., Mh., 1980, 215–222, 1980.
Seichter, W., Moegel, H. J., Brand, P., and Salah, D.: Crystal structure and
formation of the aluminum hydroxide chloride
[Al13(OH)24(H2O)24]Cl15 × 13H2O, Eur.
J. Inorg. Chem., 1998, 795–797, 1998.
Sheldrick, G. M.: Crystal structure refinement with SHELXL, Acta
Crystallogr. C, 71, 3–8, 2015.
Sillitoe, R. H. and Brogi, A.: Geothermal systems in Northern Apennines,
Italy: modern analogues of Carlin-style gold deposits, Econ. Geol., 116,
1491–1501, 2021.
Smith, D. G. W. and Nickel, E. H.: A system for codification for unnamed
minerals: report of the Subcommittee for Unnamed Minerals of the IMA
Commission on New Minerals, Nomenclature and Classification, Can. Mineral.,
45, 983–1055, 2007.
Wilson, A. J. C. (Ed.): International Tables for Crystallography Volume C:
Mathematical, Physical and Chemical Tables, Kluwer Academic Publishers,
Dordrecht, the Netherlands, 1992.
Wright, F. E.: Computation of the optic axial angle from the three principal
refractive indices, Am. Mineral., 36, 543–556, 1951.
Zimbelman, D. R., Rye, R. O., and Breit, G. N.: Origin of secondary sulfate
minerals on active andesitic stratovolcanoes, Chem. Geol., 215, 37–60,
2005.
Short summary
Batoniite is a new mineral species belonging to the Al2O3–SO3–H2O ternary system, first found in the Cetine di Cotorniano Mine (Tuscany, Italy). This hydrated Al sulfate shows a novel crystal structure, characterized by Al octamers, so far reported in only synthetic compounds.
Batoniite is a new mineral species belonging to the Al2O3–SO3–H2O ternary system, first found in...
