Articles | Volume 35, issue 5
https://doi.org/10.5194/ejm-35-703-2023
https://doi.org/10.5194/ejm-35-703-2023
Research article
 | 
31 Aug 2023
Research article |  | 31 Aug 2023

Batoniite, [Al8(OH)14(H2O)18](SO4)5  ⋅  5H2O, a new mineral with the [Al8(OH)14(H2O)18]10+ polyoxocation from the Cetine di Cotorniano Mine, Tuscany, Italy

Daniela Mauro, Cristian Biagioni, Jiří Sejkora, Zdeněk Dolníček, and Radek Škoda

Related authors

Dacostaite, K(Mg2Al)[Mg(H2O)6]2(AsO4)2F6  ⋅  2H2O, a new fluoride–arsenate mineral from the Cetine di Cotorniano Mine (Tuscany, Italy)
Cristian Biagioni, Daniela Mauro, Jiří Sejkora, Zdeněk Dolníček, Andrea Dini, and Radek Škoda
Eur. J. Mineral., 37, 39–52, https://doi.org/10.5194/ejm-37-39-2025,https://doi.org/10.5194/ejm-37-39-2025, 2025
Short summary
Nannoniite, Al2(OH)5F, a new mineral from the Cetine di Cotorniano mine (Tuscany, Italy)
Cristian Biagioni, Enrico Mugnaioli, Sofia Lorenzon, Daniela Mauro, Silvia Musetti, Jiří Sejkora, Donato Belmonte, Nicola Demitri, and Zdeněk Dolníček
Eur. J. Mineral., 36, 1011–1022, https://doi.org/10.5194/ejm-36-1011-2024,https://doi.org/10.5194/ejm-36-1011-2024, 2024
Short summary
Structural and compositional data for childrenite from the Homolka granite, Czech Republic
Jonas Toupal, Daniela Mauro, Cristian Biagioni, Federica Zaccarini, and Reto Gieré
Eur. J. Mineral., 36, 1–10, https://doi.org/10.5194/ejm-36-1-2024,https://doi.org/10.5194/ejm-36-1-2024, 2024
Short summary
Dutrowite, Na(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3O, a new mineral from the Apuan Alps (Tuscany, Italy): the first member of the tourmaline supergroup with Ti as a species-forming chemical constituent
Cristian Biagioni, Ferdinando Bosi, Daniela Mauro, Henrik Skogby, Andrea Dini, and Federica Zaccarini
Eur. J. Mineral., 35, 81–94, https://doi.org/10.5194/ejm-35-81-2023,https://doi.org/10.5194/ejm-35-81-2023, 2023
Short summary
Graulichite-(La), LaFe3+3(AsO4)2(OH)6, a new addition to the alunite supergroup from the Patte d'Oie mine, Bou Skour mining district, Morocco
Cristian Biagioni, Marco E. Ciriotti, Georges Favreau, Daniela Mauro, and Federica Zaccarini
Eur. J. Mineral., 34, 365–374, https://doi.org/10.5194/ejm-34-365-2022,https://doi.org/10.5194/ejm-34-365-2022, 2022
Short summary

Related subject area

New minerals and systematic mineralogy
Heimaeyite, Na3Al(SO4)3, a new mineral from the fumaroles on Eldfell volcano, Iceland
Tonči Balić-Žunić, Anna Garavelli, Donatella Mitolo, Fabrizio Nestola, Martha Giovanna Pamato, Maja Bar Rasmussen, and Morten Bjerkvig Jølnæs
Eur. J. Mineral., 37, 79–89, https://doi.org/10.5194/ejm-37-79-2025,https://doi.org/10.5194/ejm-37-79-2025, 2025
Short summary
Andreybulakhite, Ni(C2O4)  ⋅  2H2O, the first natural nickel oxalate
Oleg S. Vereshchagin, Sergey N. Britvin, Dmitrii V. Pankin, Marina S. Zelenskaya, Maria G. Krzhizhanovskaya, Maria A. Kuz'mina, Natalia S. Vlasenko, and Olga V. Frank-Kamenetskaya
Eur. J. Mineral., 37, 63–74, https://doi.org/10.5194/ejm-37-63-2025,https://doi.org/10.5194/ejm-37-63-2025, 2025
Short summary
Dacostaite, K(Mg2Al)[Mg(H2O)6]2(AsO4)2F6  ⋅  2H2O, a new fluoride–arsenate mineral from the Cetine di Cotorniano Mine (Tuscany, Italy)
Cristian Biagioni, Daniela Mauro, Jiří Sejkora, Zdeněk Dolníček, Andrea Dini, and Radek Škoda
Eur. J. Mineral., 37, 39–52, https://doi.org/10.5194/ejm-37-39-2025,https://doi.org/10.5194/ejm-37-39-2025, 2025
Short summary
Nannoniite, Al2(OH)5F, a new mineral from the Cetine di Cotorniano mine (Tuscany, Italy)
Cristian Biagioni, Enrico Mugnaioli, Sofia Lorenzon, Daniela Mauro, Silvia Musetti, Jiří Sejkora, Donato Belmonte, Nicola Demitri, and Zdeněk Dolníček
Eur. J. Mineral., 36, 1011–1022, https://doi.org/10.5194/ejm-36-1011-2024,https://doi.org/10.5194/ejm-36-1011-2024, 2024
Short summary
Karlseifertite, Pb(Ga2Ge)(AsO4)2(OH)6, a new dussertite-group mineral, from Tsumeb, Namibia
Anthony R. Kampf, Joy Désor, and Chi Ma
Eur. J. Mineral., 36, 873–878, https://doi.org/10.5194/ejm-36-873-2024,https://doi.org/10.5194/ejm-36-873-2024, 2024
Short summary

Cited articles

Basset, H. and Goodwin, T. H.: The basic aluminum sulphates, J. Chem. Soc., 1949, 2239–2279, 1949. 
Bayliss, P., Kolitsch, U., Nickel, E. H., and Pring, A.: Alunite supergroup: recommended nomenclature, Mineral. Mag., 74, 919–927, 2010. 
Belluomini, G., Fornaseri, M., and Nicoletti, M.: Onoratoite, a new antimony oxychloride from Cetine di Cotorniano, Rosia (Siena, Italy), Mineral. Mag., 36, 1037–1044, 1968. 
Beukes, G. J., Schoch, A. E., de Bruiyn, H., van der Westhuizen, W. A., and Bok, L. D. C.: A new occurrence of the hydrated aluminium sulphate zaherite, from Pofadder, South Africa, Mineral. Mag., 48, 131–135, 1984. 
Biagioni, C., Pasero, M., and Zaccarini, F.: Tiberiobardiite, Cu9Al(SiO3OH)(OH)12(H2O)6(SO4)1.5 10H2O, a new mineral related to chalcophyllite from the Cretaio Cu prospect, Massa Marittima, Grosseto (Tuscany, Italy): Occurrence and crystal structure, Minerals, 8, 152, https://doi.org/10.3390/min8040152, 2018. 
Download
Short summary
Batoniite is a new mineral species belonging to the Al2O3–SO3–H2O ternary system, first found in the Cetine di Cotorniano Mine (Tuscany, Italy). This hydrated Al sulfate shows a novel crystal structure, characterized by Al octamers, so far reported in only synthetic compounds.
Share