Articles | Volume 33, issue 6
https://doi.org/10.5194/ejm-33-675-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-33-675-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
New insights in the mechanisms of the reaction 3.65 Å phase = clinoenstatite + water down to nanoscales
Section 3.6, Chemistry and Physics of Earth Materials, Deutsches GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam,
Germany
Oona Appelt
Section 3.6, Chemistry and Physics of Earth Materials, Deutsches GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam,
Germany
Bernd Wunder
Section 3.6, Chemistry and Physics of Earth Materials, Deutsches GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam,
Germany
Richard Wirth
Section 3.5, Interface Geochemistry, Deutsches GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam,
Germany
Related authors
Dirk Spengler, Monika Koch-Müller, Adam Włodek, Simon J. Cuthbert, and Jarosław Majka
EGUsphere, https://doi.org/10.5194/egusphere-2024-2734, https://doi.org/10.5194/egusphere-2024-2734, 2024
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West Norwegian 'diamond facies' eclogite contains tiny mineral inclusions of quartz and amphibole lamellae that are not stable in the diamond field. Low trace amounts of water in the lamellae-bearing host minerals suggest that the inclusion microstructure was not formed by fluid infiltration but by dehydration during early exhumation of these rocks. Some samples with higher water content argue that a late fluid overprint was spatially restricted and obliterated evidence of extreme metamorphism.
Christian Lathe, Monika Koch-Müller, Bernd Wunder, Oona Appelt, Melanie Sieber, Shrikant Bhat, and Robert Farla
Eur. J. Mineral., 35, 1149–1157, https://doi.org/10.5194/ejm-35-1149-2023, https://doi.org/10.5194/ejm-35-1149-2023, 2023
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We examined the reaction phase A plus high-P clinoenstatite to forsterite plus water (Reaction 1) by means of in situ X-ray diffraction measurements with the large volume press at the synchrotron PETRA III, Hamburg. Contrary to other studies, in which all experiments on Reaction (1) were performed at a water activity of 1, the reversed experiments presented in this study were performed at reduced water activity with mole fractions of about XH2O = XCO2 = 0.5.
Melanie J. Sieber, Max Wilke, Oona Appelt, Marcus Oelze, and Monika Koch-Müller
Eur. J. Mineral., 34, 411–424, https://doi.org/10.5194/ejm-34-411-2022, https://doi.org/10.5194/ejm-34-411-2022, 2022
Short summary
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Carbonates reduce the melting point of the mantle, and carbonate melts produced in low-degree melting of a carbonated mantle are considered the precursor of CO2-rich magmas. We established experimentally the melting relations of carbonates up to 9 GPa, showing that Mg-carbonates melt incongruently to periclase and carbonate melt. The trace element signature of carbonate melts parental to kimberlites is approached by melting of Mg-rich carbonates.
Christian Lathe, Monika Koch-Müller, Bernd Wunder, Oona Appelt, Shrikant Bhat, and Robert Farla
Eur. J. Mineral., 34, 201–213, https://doi.org/10.5194/ejm-34-201-2022, https://doi.org/10.5194/ejm-34-201-2022, 2022
Short summary
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The equilibrium phase of A + HP clinoenstatite = forsterite + water was experimentally investigated at aH2O = 1 in situ. In cold subducting slabs, it is of relevance to transport water to large depths, initiating the formation of dense hydrous magnesium silicate (DHMS). At normal gradients, the huge water amount from this reaction induces important processes within the overlying mantle wedge. We additionally discuss the relevance of this reaction for intermediate-depth earthquake formation.
Nada Abdel-Hak, Bernd Wunder, Ilias Efthimiopoulos, and Monika Koch-Müller
Eur. J. Mineral., 32, 469–482, https://doi.org/10.5194/ejm-32-469-2020, https://doi.org/10.5194/ejm-32-469-2020, 2020
Short summary
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The structural response of the NH4+ molecule to temperature and pressure changes is studied in ammonium phengite. The symmetry of the molecule is lowered by increasing P or decreasing T; the type and mechanism of this lowered symmetry is different in both cases. Devolatilisation (NH4+ and OH loss) of ammonium phengite is studied as well. This study confirms the wide stability range of phengite and its volatiles and thus has important implications for N and H recycling into the deep Earth.
Dirk Spengler, Monika Koch-Müller, Adam Włodek, Simon J. Cuthbert, and Jarosław Majka
EGUsphere, https://doi.org/10.5194/egusphere-2024-2734, https://doi.org/10.5194/egusphere-2024-2734, 2024
Short summary
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West Norwegian 'diamond facies' eclogite contains tiny mineral inclusions of quartz and amphibole lamellae that are not stable in the diamond field. Low trace amounts of water in the lamellae-bearing host minerals suggest that the inclusion microstructure was not formed by fluid infiltration but by dehydration during early exhumation of these rocks. Some samples with higher water content argue that a late fluid overprint was spatially restricted and obliterated evidence of extreme metamorphism.
Alessia Borghini, Silvio Ferrero, Patrick J. O'Brien, Bernd Wunder, Peter Tollan, Jarosław Majka, Rico Fuchs, and Kerstin Gresky
Eur. J. Mineral., 36, 279–300, https://doi.org/10.5194/ejm-36-279-2024, https://doi.org/10.5194/ejm-36-279-2024, 2024
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We studied primary granitic and halogen-rich melt inclusions trapped in mantle rocks in the Bohemian Massif (Germany) in order to retrieve important information about the nature of the melt and the source rock. The melt was produced by the partial melting of metasediments during the deepest stages of subduction and interacted with the mantle. This work is an excellent example of transfer of crustal material, volatiles in particular, in the mantle during the subduction of the continental crust.
Christian Lathe, Monika Koch-Müller, Bernd Wunder, Oona Appelt, Melanie Sieber, Shrikant Bhat, and Robert Farla
Eur. J. Mineral., 35, 1149–1157, https://doi.org/10.5194/ejm-35-1149-2023, https://doi.org/10.5194/ejm-35-1149-2023, 2023
Short summary
Short summary
We examined the reaction phase A plus high-P clinoenstatite to forsterite plus water (Reaction 1) by means of in situ X-ray diffraction measurements with the large volume press at the synchrotron PETRA III, Hamburg. Contrary to other studies, in which all experiments on Reaction (1) were performed at a water activity of 1, the reversed experiments presented in this study were performed at reduced water activity with mole fractions of about XH2O = XCO2 = 0.5.
Silvio Ferrero, Alessia Borghini, Laurent Remusat, Gautier Nicoli, Bernd Wunder, and Roberto Braga
Eur. J. Mineral., 35, 1031–1049, https://doi.org/10.5194/ejm-35-1031-2023, https://doi.org/10.5194/ejm-35-1031-2023, 2023
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Garnet often entraps small droplets of deep melts generated during mountain building processes. Using high-resolution techniques, we studied these droplets in order to provide hard numbers for the quantification of volatile budgets during crustal evolution, show how even melts formed at >1000°C contain water, and clarify how water behaves during metamorphism and melting at the microscale. Moreover, we provide the very first data on chlorine in natural melts from crustal reworking.
Melanie J. Sieber, Max Wilke, Oona Appelt, Marcus Oelze, and Monika Koch-Müller
Eur. J. Mineral., 34, 411–424, https://doi.org/10.5194/ejm-34-411-2022, https://doi.org/10.5194/ejm-34-411-2022, 2022
Short summary
Short summary
Carbonates reduce the melting point of the mantle, and carbonate melts produced in low-degree melting of a carbonated mantle are considered the precursor of CO2-rich magmas. We established experimentally the melting relations of carbonates up to 9 GPa, showing that Mg-carbonates melt incongruently to periclase and carbonate melt. The trace element signature of carbonate melts parental to kimberlites is approached by melting of Mg-rich carbonates.
Christian Lathe, Monika Koch-Müller, Bernd Wunder, Oona Appelt, Shrikant Bhat, and Robert Farla
Eur. J. Mineral., 34, 201–213, https://doi.org/10.5194/ejm-34-201-2022, https://doi.org/10.5194/ejm-34-201-2022, 2022
Short summary
Short summary
The equilibrium phase of A + HP clinoenstatite = forsterite + water was experimentally investigated at aH2O = 1 in situ. In cold subducting slabs, it is of relevance to transport water to large depths, initiating the formation of dense hydrous magnesium silicate (DHMS). At normal gradients, the huge water amount from this reaction induces important processes within the overlying mantle wedge. We additionally discuss the relevance of this reaction for intermediate-depth earthquake formation.
Martina Kirilova, Virginia Toy, Katrina Sauer, François Renard, Klaus Gessner, Richard Wirth, Xianghui Xiao, and Risa Matsumura
Solid Earth, 11, 2425–2438, https://doi.org/10.5194/se-11-2425-2020, https://doi.org/10.5194/se-11-2425-2020, 2020
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Processes associated with open pores can change the physical properties of rocks and cause earthquakes. In borehole samples from the Alpine Fault zone, we show that many pores in these rocks were filled by weak materials that can slide easily. The amount of open spaces was thus reduced, and fluids circulating within them built up high pressures. Both weak materials and high pressures within pores reduce the rock strength; thus the state of pores here can trigger the next Alpine Fault earthquake.
Fahui Xiong, Xiangzhen Xu, Enrico Mugnaioli, Mauro Gemmi, Richard Wirth, Edward S. Grew, Paul T. Robinson, and Jingsui Yang
Eur. J. Mineral., 32, 557–574, https://doi.org/10.5194/ejm-32-557-2020, https://doi.org/10.5194/ejm-32-557-2020, 2020
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Two new nanominerals: titanium monophosphide and titanium disilicide, formed at pressures of Earth’s upper mantle by the action of methane and hydrogen from the mantle on basaltic melts in the Luobusa ophiolite (Tibet). The minerals were characterized by 3D electron diffraction, which can solve the crystal structures of phases less than a micrometer in size. The results contribute to our understanding of deeply subducted crustal rocks and their exhumation back to the Earth's surface.
Nada Abdel-Hak, Bernd Wunder, Ilias Efthimiopoulos, and Monika Koch-Müller
Eur. J. Mineral., 32, 469–482, https://doi.org/10.5194/ejm-32-469-2020, https://doi.org/10.5194/ejm-32-469-2020, 2020
Short summary
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The structural response of the NH4+ molecule to temperature and pressure changes is studied in ammonium phengite. The symmetry of the molecule is lowered by increasing P or decreasing T; the type and mechanism of this lowered symmetry is different in both cases. Devolatilisation (NH4+ and OH loss) of ammonium phengite is studied as well. This study confirms the wide stability range of phengite and its volatiles and thus has important implications for N and H recycling into the deep Earth.
Related subject area
High-pressure study of minerals
The use of MgO–ZnO ceramics to record pressure and temperature conditions in the piston–cylinder apparatus
The miscibility gap between the rock salt and wurtzite phases in the MgO–ZnO binary system to 3.5 GPa
High-pressure and high-temperature structure and equation of state of Na3Ca2La(CO3)5 burbankite
In situ reinvestigation of reaction phase A plus high-pressure clinoenstatite to forsterite plus water in the system MgO-SiO2-H2O (MSH)
Melt–rock interactions in a veined mantle: pyroxenite–peridotite reaction experiments at 2 GPa
Deformation of NaCoF3 perovskite and post-perovskite up to 30 GPa and 1013 K: implications for plastic deformation and transformation mechanism
Equation of state and high-pressure phase behaviour of SrCO3
Nicholas Farmer and Hugh St. C. O'Neill
Eur. J. Mineral., 36, 473–489, https://doi.org/10.5194/ejm-36-473-2024, https://doi.org/10.5194/ejm-36-473-2024, 2024
Short summary
Short summary
The piston–cylinder apparatus is widely used to investigate rock properties at the conditions of the interior of the Earth, but uncertainty in its calibration of pressure persists, with substantial differences between laboratories. We use a ceramic of magnesium and zinc oxides to measure the conditions experienced by a sample. Routine use of such ceramics provides an archive of experimental conditions, enables interlaboratory comparisons, and resolves long-standing controversies in calibration.
Nicholas Farmer and Hugh St. C. O'Neill
Eur. J. Mineral., 35, 1051–1071, https://doi.org/10.5194/ejm-35-1051-2023, https://doi.org/10.5194/ejm-35-1051-2023, 2023
Short summary
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The chemical compositions of the synthetic minerals periclase and zincite in the MgO–ZnO binary system change smoothly and systematically with pressure when they exist together in equilibrium. We have studied these changes experimentally over a wide range of conditions and fitted the results to a thermodynamic model. The model may be used to predict the compositions of the coexisting phases accurately at high pressures and temperatures corresponding to the Earth’s crust and uppermost mantle.
Sula Milani, Deborah Spartà, Patrizia Fumagalli, Boby Joseph, Roberto Borghes, Valentina Chenda, Juliette Maurice, Giorgio Bais, and Marco Merlini
Eur. J. Mineral., 34, 351–358, https://doi.org/10.5194/ejm-34-351-2022, https://doi.org/10.5194/ejm-34-351-2022, 2022
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This work presents new thermoelastic parameters and the structural evolution of burbankite at high pressure and high temperature, obtained by in situ synchrotron radiation single-crystal diffraction measurements. Burbankite is a carbonate that may potentially play a key role as an upper-mantle reservoir of light REE3+. We observed that the density of burbankite is greater with respect to carbonatitic magmas, indicating a possible fractionation of this phase in upper-mantle conditions.
Christian Lathe, Monika Koch-Müller, Bernd Wunder, Oona Appelt, Shrikant Bhat, and Robert Farla
Eur. J. Mineral., 34, 201–213, https://doi.org/10.5194/ejm-34-201-2022, https://doi.org/10.5194/ejm-34-201-2022, 2022
Short summary
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The equilibrium phase of A + HP clinoenstatite = forsterite + water was experimentally investigated at aH2O = 1 in situ. In cold subducting slabs, it is of relevance to transport water to large depths, initiating the formation of dense hydrous magnesium silicate (DHMS). At normal gradients, the huge water amount from this reaction induces important processes within the overlying mantle wedge. We additionally discuss the relevance of this reaction for intermediate-depth earthquake formation.
Giulio Borghini, Patrizia Fumagalli, and Elisabetta Rampone
Eur. J. Mineral., 34, 109–129, https://doi.org/10.5194/ejm-34-109-2022, https://doi.org/10.5194/ejm-34-109-2022, 2022
Short summary
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The mineralogical and chemical heterogeneity of the mantle is poorly known because it is not able to be directly investigated. Melt–peridotite interaction processes play a fundamental role in controlling the mantle composition. The results of our reaction experiments help us to evaluate the role of temperature and melt composition in the modification of the mantle through the interaction with pyroxenite-derived melts with implications for the evolution of a veined mantle.
Jeffrey P. Gay, Lowell Miyagi, Samantha Couper, Christopher Langrand, David P. Dobson, Hanns-Peter Liermann, and Sébastien Merkel
Eur. J. Mineral., 33, 591–603, https://doi.org/10.5194/ejm-33-591-2021, https://doi.org/10.5194/ejm-33-591-2021, 2021
Short summary
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We examined the experimental deformation and phase transition of a bridgmanite analogue, NaCoF3, using a resistive-heated diamond anvil cell and a synchrotron radiation source. We wanted to observe the behavior of NaCoF3 under uniaxial compression and its plastic properties, as well as to determine if it is a suitable analogue for natural samples. We observe 100 and 001 compression textures and link those to the dominant deformation mechanism in the perovskite structure.
Nicole Biedermann, Elena Bykova, Wolfgang Morgenroth, Ilias Efthimiopoulos, Jan Mueller, Georg Spiekermann, Konstantin Glazyrin, Anna Pakhomova, Karen Appel, and Max Wilke
Eur. J. Mineral., 32, 575–586, https://doi.org/10.5194/ejm-32-575-2020, https://doi.org/10.5194/ejm-32-575-2020, 2020
Short summary
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Carbonates play a key role in the chemistry and dynamics of our planet. The role of SrCO3 in the deep mantle has received little attention due to its low abundance. However, knowing the high-pressure phase behaviour of natural carbonates across its full compositional range is essential to evaluate effects of chemical substitution in the system of deep-Earth carbonates. We performed powder and single-crystal X-ray diffraction up to 49 GPa and observed a phase transition in SrCO3 at around 26 GPa.
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Short summary
Dense hydrous magnesium silicates, like the 3.65 Å phase, are thought to cause deep earthquakes. We investigated the dehydration of the 3.65 Å phase at P and T. In both directions of the investigated simple reaction, additional metastable water-rich phases occur. The observed extreme reduction in grain size in the dehydration experiments might cause mechanical instabilities in the Earth’s mantle and, finally, induce earthquakes.
Dense hydrous magnesium silicates, like the 3.65 Å phase, are thought to cause deep...