Articles | Volume 33, issue 6
https://doi.org/10.5194/ejm-33-675-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-33-675-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
New insights in the mechanisms of the reaction 3.65 Å phase = clinoenstatite + water down to nanoscales
Section 3.6, Chemistry and Physics of Earth Materials, Deutsches GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam,
Germany
Oona Appelt
Section 3.6, Chemistry and Physics of Earth Materials, Deutsches GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam,
Germany
Bernd Wunder
Section 3.6, Chemistry and Physics of Earth Materials, Deutsches GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam,
Germany
Richard Wirth
Section 3.5, Interface Geochemistry, Deutsches GeoForschungsZentrum Potsdam, Telegrafenberg, 14473 Potsdam,
Germany
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Western Norwegian “diamond facies” eclogite contains tiny mineral inclusions of quartz and amphibole lamellae that are not stable in the diamond field. Low trace amounts of water in the lamellae-bearing host minerals suggest that the inclusion microstructure was not formed by fluid infiltration but by dehydration during early exhumation of these rocks. Some samples with higher water content argue that a late fluid overprint was spatially restricted and erased evidence of extreme metamorphism.
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We examined the reaction phase A plus high-P clinoenstatite to forsterite plus water (Reaction 1) by means of in situ X-ray diffraction measurements with the large volume press at the synchrotron PETRA III, Hamburg. Contrary to other studies, in which all experiments on Reaction (1) were performed at a water activity of 1, the reversed experiments presented in this study were performed at reduced water activity with mole fractions of about XH2O = XCO2 = 0.5.
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Carbonates reduce the melting point of the mantle, and carbonate melts produced in low-degree melting of a carbonated mantle are considered the precursor of CO2-rich magmas. We established experimentally the melting relations of carbonates up to 9 GPa, showing that Mg-carbonates melt incongruently to periclase and carbonate melt. The trace element signature of carbonate melts parental to kimberlites is approached by melting of Mg-rich carbonates.
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The equilibrium phase of A + HP clinoenstatite = forsterite + water was experimentally investigated at aH2O = 1 in situ. In cold subducting slabs, it is of relevance to transport water to large depths, initiating the formation of dense hydrous magnesium silicate (DHMS). At normal gradients, the huge water amount from this reaction induces important processes within the overlying mantle wedge. We additionally discuss the relevance of this reaction for intermediate-depth earthquake formation.
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We examined the reaction phase A plus high-P clinoenstatite to forsterite plus water (Reaction 1) by means of in situ X-ray diffraction measurements with the large volume press at the synchrotron PETRA III, Hamburg. Contrary to other studies, in which all experiments on Reaction (1) were performed at a water activity of 1, the reversed experiments presented in this study were performed at reduced water activity with mole fractions of about XH2O = XCO2 = 0.5.
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Garnet often entraps small droplets of deep melts generated during mountain building processes. Using high-resolution techniques, we studied these droplets in order to provide hard numbers for the quantification of volatile budgets during crustal evolution, show how even melts formed at >1000°C contain water, and clarify how water behaves during metamorphism and melting at the microscale. Moreover, we provide the very first data on chlorine in natural melts from crustal reworking.
Melanie J. Sieber, Max Wilke, Oona Appelt, Marcus Oelze, and Monika Koch-Müller
Eur. J. Mineral., 34, 411–424, https://doi.org/10.5194/ejm-34-411-2022, https://doi.org/10.5194/ejm-34-411-2022, 2022
Short summary
Short summary
Carbonates reduce the melting point of the mantle, and carbonate melts produced in low-degree melting of a carbonated mantle are considered the precursor of CO2-rich magmas. We established experimentally the melting relations of carbonates up to 9 GPa, showing that Mg-carbonates melt incongruently to periclase and carbonate melt. The trace element signature of carbonate melts parental to kimberlites is approached by melting of Mg-rich carbonates.
Christian Lathe, Monika Koch-Müller, Bernd Wunder, Oona Appelt, Shrikant Bhat, and Robert Farla
Eur. J. Mineral., 34, 201–213, https://doi.org/10.5194/ejm-34-201-2022, https://doi.org/10.5194/ejm-34-201-2022, 2022
Short summary
Short summary
The equilibrium phase of A + HP clinoenstatite = forsterite + water was experimentally investigated at aH2O = 1 in situ. In cold subducting slabs, it is of relevance to transport water to large depths, initiating the formation of dense hydrous magnesium silicate (DHMS). At normal gradients, the huge water amount from this reaction induces important processes within the overlying mantle wedge. We additionally discuss the relevance of this reaction for intermediate-depth earthquake formation.
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Short summary
Dense hydrous magnesium silicates, like the 3.65 Å phase, are thought to cause deep earthquakes. We investigated the dehydration of the 3.65 Å phase at P and T. In both directions of the investigated simple reaction, additional metastable water-rich phases occur. The observed extreme reduction in grain size in the dehydration experiments might cause mechanical instabilities in the Earth’s mantle and, finally, induce earthquakes.
Dense hydrous magnesium silicates, like the 3.65 Å phase, are thought to cause deep...