Articles | Volume 36, issue 4
https://doi.org/10.5194/ejm-36-615-2024
https://doi.org/10.5194/ejm-36-615-2024
Research article
 | 
22 Aug 2024
Research article |  | 22 Aug 2024

Evidence of the existence of the As4S6 molecule produced by light exposure of alacranite, As8S9

Luca Bindi, Paola Bonazzi, Laura Chelazzi, Matteo M. N. Franceschini, Giovanni O. Lepore, Marta Morana, Giovanni Pratesi, Alice Taddei, Matteo Zoppi, and Silvio Menchetti

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Cited articles

Bindi, L.: CCDC 2366909: Experimental Crystal Structure Determination, The Cambridge Crystallographic Data Centre [data set], https://doi.org/10.5517/ccdc.csd.cc2kfyxw, 2024. 
Bindi, L. and Bonazzi, P.: Light-induced alteration of arsenic sulfides: A new product with an orthorhombic crystal structure, Am. Mineral., 92, 617–620, 2007. 
Bindi, L., Popova, V. I., and Bonazzi, P.: Uzonite, As4S5, from the type-locality: X-ray single crystal study and lighting experiments, Can. Mineral., 41, 1463–1468, 2003. 
Bindi, L., Pratesi, G., Muniz-Miranda, M., Zoppi, M., Chelazzi, L., Lepore, G. O., and Menchetti, S.: From ancient pigments to modern optoelectronic applications of arsenic sulfides: bonazziite, the natural analogue of β-As4S4 from Khaidarkan deposit, Kyrgyzstan, Mineral. Mag., 79, 121–131, 2015. 
Bindi, L., Nespolo, M., Krivovichev, S. V., Chapuis, G., and Biagioni, C.: Producing highly complicated materials. Nature does it better, Rep. Prog. Phys., 83, 106501–106540, 2020. 
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Short summary
The As4S6 molecule was missing in the reported structures of crystalline As chalcogenides. Here we report the first occurrence of the As4S6 molecule together with the other known As4Sn (n = 3, 4, 5) molecules randomly replacing each other in the crystalline structure of a new monoclinic product obtained by the light-induced alteration of the mineral alacranite, As8S9.
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