Articles | Volume 35, issue 2
https://doi.org/10.5194/ejm-35-157-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-35-157-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Thermodynamic and structural variations along the olivenite–libethenite solid solution
Institute of Geosciences, Friedrich Schiller University Jena, Burgweg
11, 07749 Jena, Germany
Alexandra Plumhoff
Institute of Geosciences, Friedrich Schiller University Jena, Burgweg
11, 07749 Jena, Germany
Martin Števko
Earth Science
Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 840
05 Bratislava, Slovakia
Department of Mineralogy and Petrology, National Museum,
Cirkusová 1740, 193 00 Prague 9 – Horní Počernice,
Czech Republic
Gwladys Steciuk
Institute of
Physics, Czech Academy of Sciences, Na Slovance 1999/2, 18221 Prague 8, Czech Republic
Jakub Plášil
Institute of
Physics, Czech Academy of Sciences, Na Slovance 1999/2, 18221 Prague 8, Czech Republic
Edgar Dachs
Department of Chemistry and Physics of Materials, University of
Salzburg, Jakob-Haringer-Strasse 2a, 5020 Salzburg, Austria
Artur Benisek
Department of Chemistry and Physics of Materials, University of
Salzburg, Jakob-Haringer-Strasse 2a, 5020 Salzburg, Austria
Related authors
Juraj Majzlan, Anna Reichstein, Patrick Haase, Martin Števko, Jiří Sejkora, and Edgar Dachs
Eur. J. Mineral., 36, 31–54, https://doi.org/10.5194/ejm-36-31-2024, https://doi.org/10.5194/ejm-36-31-2024, 2024
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Minerals formed by weathering of toxic materials, of either natural or human origin, act as storage containers for toxic elements. In this work, we investigated properties of common minerals which store and release arsenic in the environment. The data presented here will allow for improved modeling of the polluted sites and for better remediation strategies that could be applied to minimize the impact of the pollution on the environment.
Khulan Berkh, Juraj Majzlan, Jeannet A. Meima, Jakub Plášil, and Dieter Rammlmair
Eur. J. Mineral., 35, 737–754, https://doi.org/10.5194/ejm-35-737-2023, https://doi.org/10.5194/ejm-35-737-2023, 2023
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Since As is detrimental to the environment, the As content of ores should be reduced before it is released into the atmosphere through a smelting process. Thus, Raman spectra of typical As minerals were investigated, and these can be used in the industrial removal of As-rich ores prior to the ore beneficiation. An additional objective of our study was an investigation of the secondary products of enargite weathering. They play a decisive role in the release or retainment of As in the waste form.
Patrick Haase, Stefan Kiefer, Kilian Pollok, Petr Drahota, and Juraj Majzlan
Eur. J. Mineral., 34, 493–506, https://doi.org/10.5194/ejm-34-493-2022, https://doi.org/10.5194/ejm-34-493-2022, 2022
Short summary
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Stannite decomposition leads to the precipitation of an amorphous and metastable Sn–Fe–As-rich phase. With ageing, goethite and cassiterite crystallize from the precursor and mark the end of the weathering cycle. Other elements are lost in the initial stage of weathering (e.g. Zn, S) or after full oxidation of the sulfidic material (e.g. Cu, Ag). Electron microprobe (EMP) and transmission electron microscopy (TEM) analyses were performed to witness the mobility of the released elements.
Juraj Majzlan, Stefan Kiefer, Kristina Lilova, Tamilarasan Subramani, Alexandra Navrotsky, Edgar Dachs, and Artur Benisek
Eur. J. Mineral., 33, 357–371, https://doi.org/10.5194/ejm-33-357-2021, https://doi.org/10.5194/ejm-33-357-2021, 2021
Short summary
Short summary
Chapmanite is a seemingly rare mineral, a silicate of the elements iron and antimony. In this work, we evaluated how stable and how soluble this mineral is. The goal was to determine if this mineral can store the toxic element antimony. Our results show that it is possible, but its formation in nature is hindered and slow. Yet, in some special environments, it could store and keep antimony over longer time.
Alexandra M. Plumhoff, Jakub Plášil, Edgar Dachs, Artur Benisek, Jiří Sejkora, Martin Števko, Mike S. Rumsey, and Juraj Majzlan
Eur. J. Mineral., 32, 285–304, https://doi.org/10.5194/ejm-32-285-2020, https://doi.org/10.5194/ejm-32-285-2020, 2020
Aileen Meier, Anne Kastner, Dennis Harries, Maria Wierzbicka-Wieczorek, Juraj Majzlan, Georg Büchel, and Erika Kothe
Biogeosciences, 14, 4867–4878, https://doi.org/10.5194/bg-14-4867-2017, https://doi.org/10.5194/bg-14-4867-2017, 2017
Short summary
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Biomineralization of (magnesium) calcite and vaterite by bacterial isolates was observed using isolates from limestone associated groundwater, rock and soil. More than 92 % of isolates could form carbonates with different crystal macromorphologies. Using different conditions like varying temperature, pH or media components but also cocultivation to test for collaborative effects of sympatric bacteria, mechanisms of calcium carbonate formation were studied.
E. Schütze, A. Weist, M. Klose, T. Wach, M. Schumann, S. Nietzsche, D. Merten, J. Baumert, J. Majzlan, and E. Kothe
Biogeosciences, 10, 3605–3614, https://doi.org/10.5194/bg-10-3605-2013, https://doi.org/10.5194/bg-10-3605-2013, 2013
Richard Pažout, Michal Dušek, Jiří Sejkora, Jakub Plášil, Gheorghe Ilinca, and Zdeněk Dolníček
Eur. J. Mineral., 36, 641–656, https://doi.org/10.5194/ejm-36-641-2024, https://doi.org/10.5194/ejm-36-641-2024, 2024
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A new sulfosalt mineral species, lazerckerite, Ag3.7Pb4.6(Sb7.9Bi3.8)Σ11.7S24, has been found, identified, structurally solved, and approved by the IMA. The mineral belongs to the Sb–Bi mixed members of the andorite branch of the lillianite homologous series. The description and characterization of the mineral are presented, and the ways of distinguishing the mineral from other similar members of the group on the basis of chemical results are explained.
Juraj Majzlan, Anna Reichstein, Patrick Haase, Martin Števko, Jiří Sejkora, and Edgar Dachs
Eur. J. Mineral., 36, 31–54, https://doi.org/10.5194/ejm-36-31-2024, https://doi.org/10.5194/ejm-36-31-2024, 2024
Short summary
Short summary
Minerals formed by weathering of toxic materials, of either natural or human origin, act as storage containers for toxic elements. In this work, we investigated properties of common minerals which store and release arsenic in the environment. The data presented here will allow for improved modeling of the polluted sites and for better remediation strategies that could be applied to minimize the impact of the pollution on the environment.
Khulan Berkh, Juraj Majzlan, Jeannet A. Meima, Jakub Plášil, and Dieter Rammlmair
Eur. J. Mineral., 35, 737–754, https://doi.org/10.5194/ejm-35-737-2023, https://doi.org/10.5194/ejm-35-737-2023, 2023
Short summary
Short summary
Since As is detrimental to the environment, the As content of ores should be reduced before it is released into the atmosphere through a smelting process. Thus, Raman spectra of typical As minerals were investigated, and these can be used in the industrial removal of As-rich ores prior to the ore beneficiation. An additional objective of our study was an investigation of the secondary products of enargite weathering. They play a decisive role in the release or retainment of As in the waste form.
Patrick Haase, Stefan Kiefer, Kilian Pollok, Petr Drahota, and Juraj Majzlan
Eur. J. Mineral., 34, 493–506, https://doi.org/10.5194/ejm-34-493-2022, https://doi.org/10.5194/ejm-34-493-2022, 2022
Short summary
Short summary
Stannite decomposition leads to the precipitation of an amorphous and metastable Sn–Fe–As-rich phase. With ageing, goethite and cassiterite crystallize from the precursor and mark the end of the weathering cycle. Other elements are lost in the initial stage of weathering (e.g. Zn, S) or after full oxidation of the sulfidic material (e.g. Cu, Ag). Electron microprobe (EMP) and transmission electron microscopy (TEM) analyses were performed to witness the mobility of the released elements.
Luboš Vrtiška, Jaromír Tvrdý, Jakub Plášil, Jiří Sejkora, Radek Škoda, Nikita V. Chukanov, Andreas Massanek, Jan Filip, Zdeněk Dolníček, and František Veselovský
Eur. J. Mineral., 34, 223–238, https://doi.org/10.5194/ejm-34-223-2022, https://doi.org/10.5194/ejm-34-223-2022, 2022
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The study of the original material of beraunite from the type locality Hrbek, Czech Rep., from collections of the TU Bergakademie Freiberg (Germany) and National Museum Prague (Czech Republic) proved the identity of the minerals beraunite and eleonorite. Because the name beraunite has priority, we consider the name eleonorite to be redundant and proposed to abolish it. The proposal 21-D approved by the IMA discredited eleonorite and accepted the formula of beraunite Fe3+6(PO4)4O(OH)4·6H2O.
Juraj Majzlan, Stefan Kiefer, Kristina Lilova, Tamilarasan Subramani, Alexandra Navrotsky, Edgar Dachs, and Artur Benisek
Eur. J. Mineral., 33, 357–371, https://doi.org/10.5194/ejm-33-357-2021, https://doi.org/10.5194/ejm-33-357-2021, 2021
Short summary
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Chapmanite is a seemingly rare mineral, a silicate of the elements iron and antimony. In this work, we evaluated how stable and how soluble this mineral is. The goal was to determine if this mineral can store the toxic element antimony. Our results show that it is possible, but its formation in nature is hindered and slow. Yet, in some special environments, it could store and keep antimony over longer time.
Pavel Škácha, Jiří Sejkora, Jakub Plášil, Zdeněk Dolníček, and Jana Ulmanová
Eur. J. Mineral., 33, 175–187, https://doi.org/10.5194/ejm-33-175-2021, https://doi.org/10.5194/ejm-33-175-2021, 2021
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Grimmite, sulfide of cobalt and nickel, is the new mineral for the mineralogical system.
Alexandra M. Plumhoff, Jakub Plášil, Edgar Dachs, Artur Benisek, Jiří Sejkora, Martin Števko, Mike S. Rumsey, and Juraj Majzlan
Eur. J. Mineral., 32, 285–304, https://doi.org/10.5194/ejm-32-285-2020, https://doi.org/10.5194/ejm-32-285-2020, 2020
Aileen Meier, Anne Kastner, Dennis Harries, Maria Wierzbicka-Wieczorek, Juraj Majzlan, Georg Büchel, and Erika Kothe
Biogeosciences, 14, 4867–4878, https://doi.org/10.5194/bg-14-4867-2017, https://doi.org/10.5194/bg-14-4867-2017, 2017
Short summary
Short summary
Biomineralization of (magnesium) calcite and vaterite by bacterial isolates was observed using isolates from limestone associated groundwater, rock and soil. More than 92 % of isolates could form carbonates with different crystal macromorphologies. Using different conditions like varying temperature, pH or media components but also cocultivation to test for collaborative effects of sympatric bacteria, mechanisms of calcium carbonate formation were studied.
E. Schütze, A. Weist, M. Klose, T. Wach, M. Schumann, S. Nietzsche, D. Merten, J. Baumert, J. Majzlan, and E. Kothe
Biogeosciences, 10, 3605–3614, https://doi.org/10.5194/bg-10-3605-2013, https://doi.org/10.5194/bg-10-3605-2013, 2013
Related subject area
Environmental and bio-mineralogy
When detection and quantification of mineral fibres in natural raw materials are at their limit – the case of a clay from the Gomsiqe–Puka mining area (Albania)
Sedimentary pyrite as a trap of organic matter: preliminary results from large-framboid observation
Chapmanite [Fe2Sb(Si2O5)O3(OH)]: thermodynamic properties and formation in low-temperature environments
Alessandro F. Gualtieri, Simona Marchetti Dori, Daniele Malferrari, Tommaso Giovanardi, Riccardo Fantini, Francesco Colombo, Mattia Sisti, Rossella Arletti, Maria Cristina Gamberini, Eleonora Braschi, Andrea Orlando, and Enrico Mugnaioli
Eur. J. Mineral., 36, 749–765, https://doi.org/10.5194/ejm-36-749-2024, https://doi.org/10.5194/ejm-36-749-2024, 2024
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This work deals with a challenging case of a commercial clay from Gomsiqe–Puka (Albania) contaminated by mineral fibres. Detection and quantification of asbestos in this material push the boundaries of current experimental methods. Using TEM, micro-Raman spectroscopy, and EPMA, we identified the presence of asbestos tremolite, along with a rare fibrous variety of diopside. The impact of milling on the detection and quantification of mineral fibres was also evaluated.
Nicolas Tribovillard, Viviane Bout-Roumazeilles, Marion Delattre, Sandra Ventalon, and Abderrahmane Bensadok
Eur. J. Mineral., 34, 77–83, https://doi.org/10.5194/ejm-34-77-2022, https://doi.org/10.5194/ejm-34-77-2022, 2022
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The studied succession of limestone and marls is enriched in pyrite framboids. The question is, could sulfate-reducing bacteria have been trapped in pyrite sarcophagi induced by their own metabolism? Our analysis reveals the presence of abundant organic matter. The typical morphology of framboids suggests the early fossilization of bacterial colonies by pyrite. If pyrite is a trap for organic molecules, then pyrite could be an underevaluated component of the C cycle.
Juraj Majzlan, Stefan Kiefer, Kristina Lilova, Tamilarasan Subramani, Alexandra Navrotsky, Edgar Dachs, and Artur Benisek
Eur. J. Mineral., 33, 357–371, https://doi.org/10.5194/ejm-33-357-2021, https://doi.org/10.5194/ejm-33-357-2021, 2021
Short summary
Short summary
Chapmanite is a seemingly rare mineral, a silicate of the elements iron and antimony. In this work, we evaluated how stable and how soluble this mineral is. The goal was to determine if this mineral can store the toxic element antimony. Our results show that it is possible, but its formation in nature is hindered and slow. Yet, in some special environments, it could store and keep antimony over longer time.
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Short summary
This research was done to understand how toxic elements, such as copper or arsenic, move through the environment. The data presented here can be used to model mobility of such elements and to improve remediation strategies at sites contaminated by mining.
This research was done to understand how toxic elements, such as copper or arsenic, move through...