Articles | Volume 34, issue 5
https://doi.org/10.5194/ejm-34-439-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-34-439-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
New secondary phosphate mineral occurrences and their crystal chemistry, at the Hagendorf Süd pegmatite, Bavaria
Erich Keck
Algunderweg 3, 92694 Etzenricht, Germany
Ian E. Grey
CORRESPONDING AUTHOR
Mineral Resources, CSIRO, Private Bag 10, Clayton South, Victoria 3169,
Australia
Colin M. MacRae
Mineral Resources, CSIRO, Private Bag 10, Clayton South, Victoria 3169,
Australia
Stephanie Boer
Australian Synchrotron, ANSTO, 800 Blackburn Road, Clayton, Victoria
3168, Australia
Rupert Hochleitner
Bavarian State Collection for Mineralogy (SNSB), Theresienstrasse 41, 80333 Munich, Germany
Christian Rewitzer
Stadtplatz 17, 93437 Furth im Wald, Germany
William G. Mumme
Mineral Resources, CSIRO, Private Bag 10, Clayton South, Victoria 3169,
Australia
A. Matt Glenn
Mineral Resources, CSIRO, Private Bag 10, Clayton South, Victoria 3169,
Australia
Cameron Davidson
Mineral Resources, CSIRO, Private Bag 10, Clayton South, Victoria 3169,
Australia
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The paper gives a characterisation of the new mineral species, whiteite-(CaMnFe), which has recently been approved as a new mineral (proposal IMA2022-077). The study included a single-crystal structure refinement that, when combined with electron microprobe analyses, confirmed that the mineral was a new member of the whiteite subgroup of the jahnsite group of minerals. Relationships between the crystal structure and the unit-cell parameters for the whiteite-subgroup minerals are discussed.
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Fluormacraeite is the first type mineral to be described from the Plößberg pegmatite, Upper Palatinate, Bavaria, Germany. The crystal structure of fluormacraeite has been refined using synchrotron data that has resolved a small monoclinic distortion due to ordering of K and H2O. The general crystal–chemical properties of the monoclinic paulkerrite-group minerals are discussed.
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The paper describes the characterisation of fluor-rewitzerite, a new mineral species belonging to the paulkerrite group. The crystal structure of fluor-rewitzerite has been refined using microfocus synchrotron diffraction data, which allowed 25 of the possible 30 H atoms to be located, thus establishing key features of the H bonding. Crystallochemical trends are reviewed for seven recently characterised monoclinic paulkerrite-group minerals.
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Macraeite is the fourth type mineral to be described from the Mangualde pegmatite, Portugal, and is the first paulkerrite-group mineral to be characterised from the locality. Its crystal structure has been refined using synchrotron diffraction data, and its chemical analysis, Raman spectrum, and optical properties are reported.
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Eur. J. Mineral., 35, 805–812, https://doi.org/10.5194/ejm-35-805-2023, https://doi.org/10.5194/ejm-35-805-2023, 2023
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Regerite is the first new mineral species to be described from the Kreuzberg pegmatite, Pleystein, in the Oberpfalz, Bavaria. It has been characterised using electron microprobe analysis, Raman spectroscopy, optical measurements and a synchrotron-based single-crystal structure refinement. The structure type for regerite has not been previously reported.
Ian E. Grey, Erich Keck, Anthony R. Kampf, Colin M. MacRae, Robert W. Gable, William G. Mumme, Nicholas C. Wilson, Alexander M. Glenn, and Cameron Davidson
Eur. J. Mineral., 35, 635–643, https://doi.org/10.5194/ejm-35-635-2023, https://doi.org/10.5194/ejm-35-635-2023, 2023
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Hochleitnerite is a new member of the paulkerrite group of minerals. Its crystal structure, chemical analyses and Raman spectroscopy are reported, and its crystallochemical properties are discussed in relation to other group members.
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Eur. J. Mineral., 35, 295–304, https://doi.org/10.5194/ejm-35-295-2023, https://doi.org/10.5194/ejm-35-295-2023, 2023
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Ian E. Grey, Rupert Hochleitner, Christian Rewitzer, Anthony R. Kampf, Colin M. MacRae, Robert W. Gable, William G. Mumme, Erich Keck, and Cameron Davidson
Eur. J. Mineral., 35, 189–197, https://doi.org/10.5194/ejm-35-189-2023, https://doi.org/10.5194/ejm-35-189-2023, 2023
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Pleysteinite has been approved as a new mineral species, and we describe here the characterisation of the mineral and its relationship to related minerals benyacarite, paulkerrite and mantienneite. The characterisation includes the determination and refinement of the crystal structure, electron microprobe analyses, optical properties and interpretation of its Raman spectrum.
Rupert Hochleitner, Christian Rewitzer, Ian E. Grey, William G. Mumme, Colin M. MacRae, Anthony R. Kampf, Erich Keck, Robert W. Gable, and Alexander M. Glenn
Eur. J. Mineral., 35, 95–103, https://doi.org/10.5194/ejm-35-95-2023, https://doi.org/10.5194/ejm-35-95-2023, 2023
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The paper gives a characterisation of the new mineral species, whiteite-(CaMnFe), which has recently been approved as a new mineral (proposal IMA2022-077). The study included a single-crystal structure refinement that, when combined with electron microprobe analyses, confirmed that the mineral was a new member of the whiteite subgroup of the jahnsite group of minerals. Relationships between the crystal structure and the unit-cell parameters for the whiteite-subgroup minerals are discussed.
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This paper describes the characterisation of a new mineral from a South Australian phosphate quarry. The characterisation included chemical analyses, infrared spectroscopy, and a determination and refinement of the crystal structure. The results showed that the mineral has a unique crystal chemistry, but it is closely related to the well-known phosphate mineral crandallite.
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Eur. J. Mineral., 34, 215–221, https://doi.org/10.5194/ejm-34-215-2022, https://doi.org/10.5194/ejm-34-215-2022, 2022
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A reinvestigation of angastonite from the type locality has shown that it is a mixture of crystalline phases and an amorphous phase, with the published formula corresponding to the amorphous phase. A redefinition proposal for angastonite as an amorphous mineral was approved by the IMA CNMNC. Our study showed how the amorphous phase formed and how it progressively recrystallises as new crandallite-related minerals.
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Short summary
First occurrences of the secondary phosphate minerals kenngottite, Mn32+Fe43+(PO4)4(OH)6(H2O)2; allanpringite, Fe33+(PO4)2(OH)3·5H2O; iangreyite, Ca2Al7(PO4)2(PO3OH)2(OH,F)15·8H2O; and nizamoffite, MnZn2(PO4)2(H2O)4, from the Hagendorf Süd pegmatite are reported, with characterisation of their crystal chemistry and phase associations.
First occurrences of the secondary phosphate minerals kenngottite, Mn32+Fe43+(PO4)4(OH)6(H2O)2;...