Articles | Volume 33, issue 4
https://doi.org/10.5194/ejm-33-401-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-33-401-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Jul 2021
Research article |
| 21 Jul 2021
| 21 Jul 2021
Geochemistry and paleogeographic implications of Permo-Triassic metasedimentary cover from the Tauern Window (Eastern Alps)
Gerhard Franz
CORRESPONDING AUTHOR
Technische Universität Berlin, Chair of Applied Geochemistry, 10587 Berlin, Germany
Martin Kutzschbach
Technische Universität Berlin, Chair of Applied Geochemistry, 10587 Berlin, Germany
Eleanor J. Berryman
CanmetMINING, Natural Resources Canada, Ottawa, K1A 0G1, Ontario,
Canada
Anette Meixner
Faculty of Geosciences & MARUM – Center for Marine Environmental
Sciences, University of Bremen, 28359 Bremen, Germany
Anselm Loges
Technische Universität Berlin, Chair of Applied Geochemistry, 10587 Berlin, Germany
Freie Universität Berlin, Chair of Mineralogy, 12249 Berlin, Germany
Dina Schultze
Technische Universität Berlin, Chair of Applied Geochemistry, 10587 Berlin, Germany
Freie Universität Berlin, Chair of Mineralogy, 12249 Berlin, Germany
Related authors
Gerhard Franz, Vladimir Khomenko, Peter Lyckberg, Vsevolod Chornousenko, and Ulrich Struck
EGUsphere, https://doi.org/10.5194/egusphere-2024-217, https://doi.org/10.5194/egusphere-2024-217, 2024
Short summary
Short summary
The Volyn biota (Ukraine), previously assumed to be an extreme case of natural, abiotic synthesis of organic matter, is more likely a diverse assemblage of fossils from the deep biosphere. Although contamination by modern organisms cannot completely be ruled out, it is unlikely, considering all aspects, i. e. their mode of occurrence in the deep biosphere, their fossilization and mature state of organic matter, their isotope signature, and their large morphological diversity.
Gerhard Franz, Vladimir Khomenko, Peter Lyckberg, Vsevolod Chournousenko, Ulrich Struck, Ulrich Gernert, and Jörg Nissen
Biogeosciences, 20, 1901–1924, https://doi.org/10.5194/bg-20-1901-2023, https://doi.org/10.5194/bg-20-1901-2023, 2023
Short summary
Short summary
This research describes the occurrence of Precambrian fossils, with exceptionally well preserved morphology in 3D. These microfossils reach a size of millimeters (possibly up to centimeters) and thus indicate the presence of multicellular eukaryotes. Many of them are filamentous, but other types were also found. These fossils lived in a depth of several hundred meters and thus provide good evidence of a continental the deep biosphere, from a time generally considered as the
boring billion.
Gerhard Franz, Peter Lyckberg, Vladimir Khomenko, Vsevolod Chournousenko, Hans-Martin Schulz, Nicolaj Mahlstedt, Richard Wirth, Johannes Glodny, Ulrich Gernert, and Jörg Nissen
Biogeosciences, 19, 1795–1811, https://doi.org/10.5194/bg-19-1795-2022, https://doi.org/10.5194/bg-19-1795-2022, 2022
Short summary
Short summary
In pegmatites from Ukraine Precambrian fossils between 1.5 Ga and 1.76 Ga were preserved in cavities connected to the surface in a geyser system. The fossilization process is silicification of the outermost rim of the fossils, stabilizing the remaining part of the organisms. The variety of organisms points to an ecosystem of several microorganisms which was active in the continental environment, and igneous rocks such as the pegmatites seem to be an ideal habitat for the deep biosphere.
Gerhard Franz, Masafumi Sudo, and Vladimir Khomenko
Eur. J. Mineral., 34, 7–18, https://doi.org/10.5194/ejm-34-7-2022, https://doi.org/10.5194/ejm-34-7-2022, 2022
Short summary
Short summary
The age of formation of buddingtonite, ammonium-bearing feldspar, can be dated with the Ar–Ar method; however, it may often give only minimum ages due to strong resetting. In the studied example it gives a Precambrian minimum age of fossils, associated with this occurrence, and the age of the accompanying mineral muscovite indicates an age near 1.5 Ga. We encourage more dating attempts of buddingtonite, which will give valuable information of diagenetic or hydrothermal events.
Leonid Shumlyanskyy, Gerhard Franz, Sarah Glynn, Oleksandr Mytrokhyn, Dmytro Voznyak, and Olena Bilan
Eur. J. Mineral., 33, 703–716, https://doi.org/10.5194/ejm-33-703-2021, https://doi.org/10.5194/ejm-33-703-2021, 2021
Short summary
Short summary
In the paper we discuss the origin of large chamber pegmatite bodies which contain giant gem-quality crystals of black quartz (morion), beryl, and topaz. We conclude that these pegmatites develop under the influence of later intrusions of mafic rocks that cause reheating of the partly crystallized granite massifs and that they supply a large amount of fluids that facilitate the
inflationof pegmatite chambers and crystallization of giant crystals of various minerals.
Gerhard Franz, Vladimir Khomenko, Peter Lyckberg, Vsevolod Chornousenko, and Ulrich Struck
EGUsphere, https://doi.org/10.5194/egusphere-2024-217, https://doi.org/10.5194/egusphere-2024-217, 2024
Short summary
Short summary
The Volyn biota (Ukraine), previously assumed to be an extreme case of natural, abiotic synthesis of organic matter, is more likely a diverse assemblage of fossils from the deep biosphere. Although contamination by modern organisms cannot completely be ruled out, it is unlikely, considering all aspects, i. e. their mode of occurrence in the deep biosphere, their fossilization and mature state of organic matter, their isotope signature, and their large morphological diversity.
Dirk Spengler, Adam Włodek, Xin Zhong, Anselm Loges, and Simon J. Cuthbert
Eur. J. Mineral., 35, 1125–1147, https://doi.org/10.5194/ejm-35-1125-2023, https://doi.org/10.5194/ejm-35-1125-2023, 2023
Short summary
Short summary
Rock lenses from the diamond stability field (>120 km depth) within ordinary gneiss are enigmatic. Even more when these lenses form an alternating exposure pattern with ordinary lenses. We studied 10 lenses from W Norway and found that many of them have a hidden history. Tiny needles of quartz enclosed in old pyroxene cores are evidence for a rock origin at great depth. These needles survived the rocks' passage to the surface that variably obscured the mineral chemistry – the rocks' memory.
Gerhard Franz, Vladimir Khomenko, Peter Lyckberg, Vsevolod Chournousenko, Ulrich Struck, Ulrich Gernert, and Jörg Nissen
Biogeosciences, 20, 1901–1924, https://doi.org/10.5194/bg-20-1901-2023, https://doi.org/10.5194/bg-20-1901-2023, 2023
Short summary
Short summary
This research describes the occurrence of Precambrian fossils, with exceptionally well preserved morphology in 3D. These microfossils reach a size of millimeters (possibly up to centimeters) and thus indicate the presence of multicellular eukaryotes. Many of them are filamentous, but other types were also found. These fossils lived in a depth of several hundred meters and thus provide good evidence of a continental the deep biosphere, from a time generally considered as the
boring billion.
Anselm Loges, Gudrun Scholz, Nader de Sousa Amadeu, Jingjing Shao, Dina Schultze, Jeremy Fuller, Beate Paulus, Franziska Emmerling, Thomas Braun, and Timm John
Eur. J. Mineral., 34, 507–521, https://doi.org/10.5194/ejm-34-507-2022, https://doi.org/10.5194/ejm-34-507-2022, 2022
Short summary
Short summary
We investigated the effect that fluoride and protons have on each other as structural neighbors in the mineral topaz. This was done using spectroscopic methods, which measure the interaction of electromagnetic radiation with matter. The forces between atoms distort the spectroscopic signals, and this distortion can thus be used to understand the corresponding forces and their effect on the physical properties of the mineral.
Gerhard Franz, Peter Lyckberg, Vladimir Khomenko, Vsevolod Chournousenko, Hans-Martin Schulz, Nicolaj Mahlstedt, Richard Wirth, Johannes Glodny, Ulrich Gernert, and Jörg Nissen
Biogeosciences, 19, 1795–1811, https://doi.org/10.5194/bg-19-1795-2022, https://doi.org/10.5194/bg-19-1795-2022, 2022
Short summary
Short summary
In pegmatites from Ukraine Precambrian fossils between 1.5 Ga and 1.76 Ga were preserved in cavities connected to the surface in a geyser system. The fossilization process is silicification of the outermost rim of the fossils, stabilizing the remaining part of the organisms. The variety of organisms points to an ecosystem of several microorganisms which was active in the continental environment, and igneous rocks such as the pegmatites seem to be an ideal habitat for the deep biosphere.
Gerhard Franz, Masafumi Sudo, and Vladimir Khomenko
Eur. J. Mineral., 34, 7–18, https://doi.org/10.5194/ejm-34-7-2022, https://doi.org/10.5194/ejm-34-7-2022, 2022
Short summary
Short summary
The age of formation of buddingtonite, ammonium-bearing feldspar, can be dated with the Ar–Ar method; however, it may often give only minimum ages due to strong resetting. In the studied example it gives a Precambrian minimum age of fossils, associated with this occurrence, and the age of the accompanying mineral muscovite indicates an age near 1.5 Ga. We encourage more dating attempts of buddingtonite, which will give valuable information of diagenetic or hydrothermal events.
Leonid Shumlyanskyy, Gerhard Franz, Sarah Glynn, Oleksandr Mytrokhyn, Dmytro Voznyak, and Olena Bilan
Eur. J. Mineral., 33, 703–716, https://doi.org/10.5194/ejm-33-703-2021, https://doi.org/10.5194/ejm-33-703-2021, 2021
Short summary
Short summary
In the paper we discuss the origin of large chamber pegmatite bodies which contain giant gem-quality crystals of black quartz (morion), beryl, and topaz. We conclude that these pegmatites develop under the influence of later intrusions of mafic rocks that cause reheating of the partly crystallized granite massifs and that they supply a large amount of fluids that facilitate the
inflationof pegmatite chambers and crystallization of giant crystals of various minerals.
Related subject area
Metamorphic petrology
Sedimentary protolith and high-P metamorphism of oxidized manganiferous quartzite from the Lanterman Range, northern Victoria Land, Antarctica
Metamorphic evolution of sillimanite gneiss in the high-pressure terrane of the Western Gneiss Region (Norway)
Halogen-bearing metasomatizing melt preserved in high-pressure (HP) eclogites of Pfaffenberg, Bohemian Massif
Île Dumet (Armorican Massif, France) and its glaucophane eclogites: the little sister of Île de Groix
Retrogression of ultrahigh-pressure eclogite, Western Gneiss Region, Norway
Electron backscatter diffraction analysis combined with NanoSIMS U–Pb isotope data reveal intra-grain plastic deformation in zircon and its effects on U–Pb age: examples from Himalayan eclogites, Pakistan
H2O and Cl in deep crustal melts: the message of melt inclusions in metamorphic rocks
Very-low-grade phyllosilicates in the Aravis massif (Haute-Savoie, France) and the di-trioctahedral substitution in chlorite
Partial melting of amphibole–clinozoisite eclogite at the pressure maximum (eclogite type locality, Eastern Alps, Austria)
Petrological study of an eclogite-facies metagranite from the Champtoceaux Complex (La Picherais, Armorican Massif, France)
Corundum-bearing and spinel-bearing symplectites in ultrahigh-pressure eclogites record high-temperature overprint and partial melting during slab exhumation
Some thoughts about eclogites and related rocks
Metamorphic P–T paths of Archean granulite facies metasedimentary lithologies from the eastern Beartooth Mountains of the northern Wyoming Province, Montana, USA: constraints from quartz-in-garnet (QuiG) Raman elastic barometry, geothermobarometry, and thermodynamic modeling
Detrital garnet petrology challenges Paleoproterozoic ultrahigh-pressure metamorphism in western Greenland
Equilibrium and kinetic approaches to understand the occurrence of the uncommon chloritoid + biotite assemblage
Reaction progress of clay minerals and carbonaceous matter in a contact metamorphic aureole (Torres del Paine intrusion, Chile)
Partial melting of zoisite eclogite from the Sanddal area, North-East Greenland Caledonides
Taehwan Kim, Yoonsup Kim, Simone Tumiati, Daeyeong Kim, Keewook Yi, and Mi Jung Lee
Eur. J. Mineral., 36, 323–343, https://doi.org/10.5194/ejm-36-323-2024, https://doi.org/10.5194/ejm-36-323-2024, 2024
Short summary
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The manganese-rich siliceous metasediment in the Antarctic Ross orogen most likely originated from Mn-nodule-bearing chert deposited not earlier than ca. 546 Ma. Subduction-related metamorphism resulted in the production of highly oxidized assemblages involving Mn3+ and rare-earth-element-zoned epidote-group mineral and Mn2+-rich garnet. A reduced environment was responsible for the Mn olivine-bearing assemblages from silica-deficient composition.
Ane K. Engvik and Johannes Jakob
Eur. J. Mineral., 36, 345–360, https://doi.org/10.5194/ejm-36-345-2024, https://doi.org/10.5194/ejm-36-345-2024, 2024
Short summary
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The paper documents sillimanite gneiss in the Western Gneiss Region (WGR) and its presence, composition, formation and metamorphic evolution. Peak metamorphism is modelled to T = 750 °C and P around 0.6 GPa. Subsequent retrogression consumes garnet and shows mineral replacement and melt crystallization involving sillimanite, white mica, K-feldspar and quartz. The petrological evolution is in accordance with the investigated eclogites and HP granulites in the northwestern part of WGR.
Alessia Borghini, Silvio Ferrero, Patrick J. O'Brien, Bernd Wunder, Peter Tollan, Jarosław Majka, Rico Fuchs, and Kerstin Gresky
Eur. J. Mineral., 36, 279–300, https://doi.org/10.5194/ejm-36-279-2024, https://doi.org/10.5194/ejm-36-279-2024, 2024
Short summary
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We studied primary granitic and halogen-rich melt inclusions trapped in mantle rocks in the Bohemian Massif (Germany) in order to retrieve important information about the nature of the melt and the source rock. The melt was produced by the partial melting of metasediments during the deepest stages of subduction and interacted with the mantle. This work is an excellent example of transfer of crustal material, volatiles in particular, in the mantle during the subduction of the continental crust.
Gaston Godard, David C. Smith, Damien Jaujard, and Sidali Doukkari
Eur. J. Mineral., 36, 99–122, https://doi.org/10.5194/ejm-36-99-2024, https://doi.org/10.5194/ejm-36-99-2024, 2024
Short summary
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Petrological and mineralogical studies of mica schists, orthogneisses and glaucophane eclogites from Dumet Island (Armorican Massif, NW France) indicate that this occurrence, which has undergone high-pressure metamorphism up to 16 kbar and 620 °C, is similar to that of Groix Island. There are about 10 similar occurrences within the Ibero-Armorican Arc, forming a discontinuous high-pressure belt, but most of them have remained unnoticed due to a high degree of retrogression.
Dirk Spengler, Adam Włodek, Xin Zhong, Anselm Loges, and Simon J. Cuthbert
Eur. J. Mineral., 35, 1125–1147, https://doi.org/10.5194/ejm-35-1125-2023, https://doi.org/10.5194/ejm-35-1125-2023, 2023
Short summary
Short summary
Rock lenses from the diamond stability field (>120 km depth) within ordinary gneiss are enigmatic. Even more when these lenses form an alternating exposure pattern with ordinary lenses. We studied 10 lenses from W Norway and found that many of them have a hidden history. Tiny needles of quartz enclosed in old pyroxene cores are evidence for a rock origin at great depth. These needles survived the rocks' passage to the surface that variably obscured the mineral chemistry – the rocks' memory.
Hafiz U. Rehman, Takanori Kagoshima, Naoto Takahata, Yuji Sano, Fabrice Barou, David Mainprice, and Hiroshi Yamamoto
Eur. J. Mineral., 35, 1079–1090, https://doi.org/10.5194/ejm-35-1079-2023, https://doi.org/10.5194/ejm-35-1079-2023, 2023
Short summary
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Zircon preserves geologic rock history. Electron backscatter diffraction (EBSD) analysis is useful to visualize deformed domains in zircons. Zircons from the Himalayan high-pressure eclogites were analzyed for EBSD to identify intra-grain plastic deformation. The U–Pb isotope age dating, using Nano-SIMS, showed that plastic deformation likely affects the geochronological records. For geologically meaningful results, it is necessary to identify undisturbed domains in zircon via EBSD.
Silvio Ferrero, Alessia Borghini, Laurent Remusat, Gautier Nicoli, Bernd Wunder, and Roberto Braga
Eur. J. Mineral., 35, 1031–1049, https://doi.org/10.5194/ejm-35-1031-2023, https://doi.org/10.5194/ejm-35-1031-2023, 2023
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Garnet often entraps small droplets of deep melts generated during mountain building processes. Using high-resolution techniques, we studied these droplets in order to provide hard numbers for the quantification of volatile budgets during crustal evolution, show how even melts formed at >1000°C contain water, and clarify how water behaves during metamorphism and melting at the microscale. Moreover, we provide the very first data on chlorine in natural melts from crustal reworking.
Benoît Dubacq, Guillaume Bonnet, Manon Warembourg, and Benoît Baptiste
Eur. J. Mineral., 35, 831–844, https://doi.org/10.5194/ejm-35-831-2023, https://doi.org/10.5194/ejm-35-831-2023, 2023
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Minerals in a vein network from the Aravis limestone (Haute-Savoie, France) include carbonates, quartz, fluorite and phyllosilicates, crystallized at around 7 km depth and 190 °C. The mineralogy has been studied with emphasis on the chlorite types: chamosite (iron-rich), cookeite (lithium-rich) and sudoite. The presence of the three chlorite types sheds light on their phase diagrams, and observed cationic substitutions confirm the need for more systematic measurement of lithium in chlorite.
Simon Schorn, Anna Rogowitz, and Christoph A. Hauzenberger
Eur. J. Mineral., 35, 715–735, https://doi.org/10.5194/ejm-35-715-2023, https://doi.org/10.5194/ejm-35-715-2023, 2023
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We investigate rocks called eclogite, which are related to subduction and the collision of continents. Our samples show evidence of limited melting at high pressure corresponding to about 70 km depth, which may play an important role in the exhumation of these rocks and the differentiation of the crust. However, due to their composition and metamorphic evolution, melt production is limited, suggesting that similar rocks are unlikely to contribute strongly to subduction-related magmatism.
Thomas Gyomlai, Philippe Yamato, and Gaston Godard
Eur. J. Mineral., 35, 589–611, https://doi.org/10.5194/ejm-35-589-2023, https://doi.org/10.5194/ejm-35-589-2023, 2023
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The La Picherais metagranite is a key example of undeformed high-pressure quartzofeldspathic rock from the Armorican Massif. Through petrological observations and thermodynamic modelling, this study determines that the metagranite was pressured above 1.7 GPa and the associated mafic lenses at ~ 2.1 GPa. This metagranite provides an opportunity to study the degree of transformation of quartzofeldspathic rocks at high pressure, which may have a significant impact on the dynamics of subduction.
Pan Tang and Shun Guo
Eur. J. Mineral., 35, 569–588, https://doi.org/10.5194/ejm-35-569-2023, https://doi.org/10.5194/ejm-35-569-2023, 2023
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In this study, unusual corundum- and spinel-bearing symplectites after muscovite were found in ultrahigh-pressure eclogites from the Dabie terrane, China. The results indicate that these symplectites formed by the low-pressure partial melting of muscovite during slab exhumation. We stress that the occurrence of corundum- and spinel-bearing symplectites after muscovite in eclogites provides important implications for fluid and melt actions in exhumed slabs.
Michael Brown
Eur. J. Mineral., 35, 523–547, https://doi.org/10.5194/ejm-35-523-2023, https://doi.org/10.5194/ejm-35-523-2023, 2023
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The past 40 years have been a golden age for eclogite studies, supported by an ever wider range of instrumentation and enhanced computational capabilities, linked with ongoing developments in the determination of the temperatures and pressures of metamorphism and the age of these rocks. These data have been used to investigate the spatiotemporal distribution of metamorphism and secular change but not without controversy in relation to the emergence of plate tectonics on Earth.
Larry Tuttle and Darrell J. Henry
Eur. J. Mineral., 35, 499–522, https://doi.org/10.5194/ejm-35-499-2023, https://doi.org/10.5194/ejm-35-499-2023, 2023
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Quartz inclusions in garnet are used to constrain the metamorphic pressure–temperature history of multiple ~2.8 Ga metasedimentary rocks from Montana, USA. Inclusion studies along with mineral and whole rock chemistry suggests that the rocks of interest experienced a clockwise metamorphic P–T history that included isobaric heating to peak metamorphic temperatures once inclusions were entrapped. These findings place fundamental constraints on the P–T evolution of this important geologic setting.
Jan Schönig, Carsten Benner, Guido Meinhold, Hilmar von Eynatten, and N. Keno Lünsdorf
Eur. J. Mineral., 35, 479–498, https://doi.org/10.5194/ejm-35-479-2023, https://doi.org/10.5194/ejm-35-479-2023, 2023
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When and how modern-style plate tectonics initiated is a matter of debate. Although the earliest unequivocal evidence for ultrahigh-pressure metamorphism is Neoproterozoic, similar processes have been proposed for Paleoproterozoic rocks of western Greenland. We intensely screened the area by studying detrital heavy minerals, garnet chemistry, and mineral inclusion assemblages in garnet. Our results raise considerable doubts on the existence of Paleoproterozoic ultrahigh-pressure rocks.
Sara Nerone, Chiara Groppo, and Franco Rolfo
Eur. J. Mineral., 35, 305–320, https://doi.org/10.5194/ejm-35-305-2023, https://doi.org/10.5194/ejm-35-305-2023, 2023
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The coexistence of chloritoid and biotite in medium-pressure Barrovian terranes is uncommon, with chloritoid usually occurring at lower temperatures than biotite. A petrologic approach using equilibrium thermodynamic modelling points out how metapelites can attain H2O-undersaturated conditions even at medium pressure and amphibolite-facies conditions and consequently can be affected by kinetic barriers, which need to be taken into account.
Annette Süssenberger, Susanne Theodora Schmidt, Florian H. Schmidt, and Manuel F. G. Weinkauf
Eur. J. Mineral., 32, 653–671, https://doi.org/10.5194/ejm-32-653-2020, https://doi.org/10.5194/ejm-32-653-2020, 2020
Wentao Cao, Jane A. Gilotti, and Hans-Joachim Massonne
Eur. J. Mineral., 32, 405–425, https://doi.org/10.5194/ejm-32-405-2020, https://doi.org/10.5194/ejm-32-405-2020, 2020
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Zoisite eclogites from the Sanddal area, North-East Greenland, contain numerous textures, such as cusps and neoblasts, which are interpreted as melt-related textures. Mineral chemistry and thermodynamic modeling demonstrate that they were partially melted through the breakdown of hydrous minerals, phengite, paragonite and zoisite. Pressure–temperature phase diagrams show that the eclogites reached a maximum depth of ∼70 km and were partially melted near that depth and during exhumation.
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Short summary
Metamorphic rocks contain information about their original rocks and thus provide insight into the earlier stages of a region of interest. Here, we used the whole-rock chemical composition and stable boron isotopes of a suite of rocks from the Alps (Italy–Austria), which were deposited in a restricted intramontane basin before the Alpine orogeny. It is possible to reconstruct the depositional conditions for these sediments, which are now common metamorphic rocks such as schists and gneisses.
Metamorphic rocks contain information about their original rocks and thus provide insight into...
