Articles | Volume 33, issue 3
Eur. J. Mineral., 33, 305–314, 2021
https://doi.org/10.5194/ejm-33-305-2021
Eur. J. Mineral., 33, 305–314, 2021
https://doi.org/10.5194/ejm-33-305-2021

Research article 02 Jun 2021

Research article | 02 Jun 2021

Quantification of major and trace elements in fluid inclusions and gas bubbles by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) with no internal standard: a new method

Anastassia Y. Borisova et al.

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Cited articles

Borisova, A. Y., Pichavant, M., Polvé, M., Wiedenbeck, M., Freydier, R., and Candaudap, F.: Trace element geochemistry of the 1991 Mt. Pinatubo silicic melts, Philippines: Implications for ore-forming potential of adakitic magmatism, Geochim. Cosmochim. Ac., 70, 3702–3716, https://doi.org/10.1016/j.gca.2006.04.030, 2006. 
Borisova, A. Y., Freydier, R., Polvé, M., Salvi, S., Candaudap, F., and Aigouy, T.: In situ multi-elemental analysis of the Mount Pinatubo quartz-hosted melt inclusions by NIR femtosecond laser ablation – inductively coupled plasma – mass spectrometry, Geostand. Geoanal. Res., 32, 209–229, https://doi.org/10.1111/j.1751-908X.2008.00882.x, 2008. 
Borisova, A. Y., Thomas, R., Salvi, S., Candaudap, F., Lanzanova, A., and Chmeleff, J.: Tin and associated metal and metaloid geochemistry by femtosecond LA-ICP-MS microanalysis in pegmatite-leucogranite melt and fluid inclusions: New evidence for melt-melt-fluid immiscibility, Mineral. Mag., 76, 91–113, https://doi.org/10.1180/minmag.2012.076.1.91, 2012. 
Borisova, A. Y., Toutain, J. P., Dubessy, J. Pallister J., Zwick, A., and Salvi, S.: H2O–CO2–S fluid triggering the 1991 Mount Pinatubo climactic eruption (Philippines), Bull. Volcanol., 76, 800, https://doi.org/10.1007/s00445-014-0800-3, 2014. 
Cauzid, J., Philippot, P., Somogyi, A., Ménez, B., Simionovici, A., and Bleuet, P.: Standardless quantification of single fluid inclusions using synchrotron radiation induced X-ray fluorescence, Chem. Geol., 227, 165–183, https://doi.org/10.1016/j.chemgeo.2005.09.012, 2006. 
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Short summary
We developed a new method for quantifying elemental concentrations in natural and synthetic fluid inclusions and gas bubbles using a laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) method with no internal standard. The method may be applied to estimate trace (metal and metalloid) elemental concentrations in hydrous carbonic (C–O–H) fluid inclusions and bubbles with uncertainty below 25 %.