Articles | Volume 36, issue 1
https://doi.org/10.5194/ejm-36-195-2024
https://doi.org/10.5194/ejm-36-195-2024
Research article
 | 
12 Feb 2024
Research article |  | 12 Feb 2024

Confocal μ-XANES as a tool to analyze Fe oxidation state in heterogeneous samples: the case of melt inclusions in olivine from the Hekla volcano

Roman Botcharnikov, Max Wilke, Jan Garrevoet, Maxim Portnyagin, Kevin Klimm, Stephan Buhre, Stepan Krasheninnikov, Renat Almeev, Severine Moune, and Gerald Falkenberg

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Cited articles

Berry, A. J., O'Neill, H. S. C., Jayasutiya, K. D., Campbell, S. J., and Foran, G. J.: XANES calibrations for the oxidation state of iron in a silicate glass, Am. Mineral., 88, 967–977, 2003. 
Berry, A. J., Stewart, G. A., O'Neill, H. S. C., Mallmann, G., and Mosselmans, J. F. W.: A re-assessment of the oxidation state of iron in MORB glasses, Earth Planet. Sc. Lett., 483, 114–123, 2018. 
Bezos, A. and Humler, E.: The Fe3+/ΣFe ratios of MORB glasses and their implications for mantle melting, Geochim. Cosmochim. Ac. 69, 711–725, 2005. 
Borisov, A., Behrens, H. and Holtz, F.: ferric / ferrous ratio in silicate melts: a new model for 1 atm data with special emphasis on the effects of melt composition, Contrib. Mineral. Petrol., 173, 98, https://doi.org/10.1007/s00410-018-1524-8, 2018. 
Botcharnikov, R. E., Koepke, J., Holtz, F., McCammon, C., and Wilke, M.: The effect of water activity on the oxidation and structural state of Fe in a ferrobasaltic melt, Geochim. Cosmochim. Ac., 69, 5071–5085, 2005. 
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Short summary
The new spectroscopic method, based on the syncrotron radiation, allows for determination of Fe oxidation state in tiny objects or in heterogeneous samples. This technique is expected to be an important tool in geosciences unraveling redox conditions in rocks and magmas as well as in material sciences providing constraints on material properties.