Articles | Volume 35, issue 5
https://doi.org/10.5194/ejm-35-831-2023
https://doi.org/10.5194/ejm-35-831-2023
Research article
 | 
04 Oct 2023
Research article |  | 04 Oct 2023

Very-low-grade phyllosilicates in the Aravis massif (Haute-Savoie, France) and the di-trioctahedral substitution in chlorite

Benoît Dubacq, Guillaume Bonnet, Manon Warembourg, and Benoît Baptiste

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Cited articles

Abad, I., Nieto, F., Peacor, D. R., and Velilla, N.: Prograde and retrograde diagenetic and metamorphic evolution in metapelitic rocks of Sierra Espuña (Spain), Clay. Clay Miner., 38, 1–23, https://doi.org/10.1180/0009855033810074, 2003. 
Abad, I., Nieto, F., Gutierrez-Alonso, G., do Campo, M., Lopez-Munguira, A., and Velilla, N.: Illitic substitution in micas of very low-grade metamorphic clastic rocks, Eur. J. Miner., 18, 59–69, https://doi.org/10.1127/0935-1221/2006/0018-0059, 2006. 
Aleksandrova, V. A., Drits, V. A., and Sokolova, G. V.: Crystal structure of ditrioctahedral chlorite, Sov. Phys. Crystallogr., 18, 50–53, 1973. 
Bailey, S. and Lister, J.: Structures, compositions, and X-ray-diffraction identification of dioctahedral chlorites, Clay. Clay Miner., 37, 193–202, https://doi.org/10.1346/CCMN.1989.0370301, 1989. 
Battaglia, S.: Variations in the chemical composition of illite from five geothermal fields: a possible geothermometer, Clay Miner., 39, 501–510, https://doi.org/10.1180/0009855043940150, 2004. 
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Short summary
Minerals in a vein network from the Aravis limestone (Haute-Savoie, France) include carbonates, quartz, fluorite and phyllosilicates, crystallized at around 7 km depth and 190 °C. The mineralogy has been studied with emphasis on the chlorite types: chamosite (iron-rich), cookeite (lithium-rich) and sudoite. The presence of the three chlorite types sheds light on their phase diagrams, and observed cationic substitutions confirm the need for more systematic measurement of lithium in chlorite.
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