Articles | Volume 35, issue 1
https://doi.org/10.5194/ejm-35-81-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-35-81-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Dutrowite, Na(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3O, a new mineral from the Apuan Alps (Tuscany, Italy): the first member of the tourmaline supergroup with Ti as a species-forming chemical constituent
Cristian Biagioni
CORRESPONDING AUTHOR
Dipartimento di Scienze della Terra, Università di Pisa, Via Santa
Maria 53, 56126 Pisa, Italy
Ferdinando Bosi
Dipartimento di Scienze della Terra, Sapienza Università di Roma,
Piazzale Aldo Moro 5, 00185 Rome, Italy
Daniela Mauro
Dipartimento di Scienze della Terra, Università di Pisa, Via Santa
Maria 53, 56126 Pisa, Italy
Museo di Storia Naturale, Università di Pisa, Via Roma 79, 56011
Calci, Italy
Henrik Skogby
Department of Geosciences, Swedish Museum of Natural History, P.O. Box
50007, 10405 Stockholm, Sweden
Andrea Dini
Istituto di Geoscienze e Georisorse, CNR-Pisa, Via Moruzzi 1, 56124
Pisa, Italy
Federica Zaccarini
Department of Applied Geological Sciences and Geophysics, University
of Leoben, Peter Tunner Str. 5, 8700 Leoben, Austria
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Giuseppe Illuminati, Silvia Musetti, Fabio Bellatreccia, Cristian Biagioni, Enrico Caprilli, Ahmad Rabiee, and Marco E. Ciriotti
Eur. J. Mineral., 37, 483–504, https://doi.org/10.5194/ejm-37-483-2025, https://doi.org/10.5194/ejm-37-483-2025, 2025
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In this work, we present the most iron-rich chrysoberyl discovered to date, found in the Sabatini Volcanic Complex (Latium, Italy). We provide a comprehensive overview of its chemical, structural, spectroscopic, and optical properties. The characterization of this chrysoberyl reveals several unique features, offering valuable insights into its genetic model and geochemical constraints, which are consistent with existing literature on the Sabatini complex and with ongoing research.
Cristian Biagioni, Jiří Sejkora, Yves Moëlo, Georges Favreau, Vincent Bourgoin, Jean-Claude Boulliard, Elena Bonaccorsi, Daniela Mauro, Silvia Musetti, Marco Pasero, Natale Perchiazzi, and Jana Ulmanová
Eur. J. Mineral., 37, 319–335, https://doi.org/10.5194/ejm-37-319-2025, https://doi.org/10.5194/ejm-37-319-2025, 2025
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Ginelfite is a new Ag–Fe–Tl–Pb sulfosalt described from the hydrothermal deposit of Jas Roux (France). It belongs to the so-called boxwork sulfosalts, a group of species showing the highest structural complexity among this group of chalcogenides. This very complex structure is probably stabilized by the occurrence of minor chemical constituents (Tl, Fe) occupying specific structural positions.
Cristian Biagioni, Daniela Mauro, Jiří Sejkora, Zdeněk Dolníček, Andrea Dini, and Radek Škoda
Eur. J. Mineral., 37, 39–52, https://doi.org/10.5194/ejm-37-39-2025, https://doi.org/10.5194/ejm-37-39-2025, 2025
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Dacostaite is a new fluoride–arsenate mineral found in the Sb(Au) deposit of the Cetine di Cotorniano Mine (Tuscany, Italy). It shows a novel crystal structure formed by heteropolyhedral layers and isolated Mg(H2O)6 groups connected by H bonds. The heteropolyhedral layers are similar to those occurring in alunite-supergroup minerals, and this is a further example of the ability of nature to use similar modules in forming the large number of currently known structural arrangements.
Cristian Biagioni, Enrico Mugnaioli, Sofia Lorenzon, Daniela Mauro, Silvia Musetti, Jiří Sejkora, Donato Belmonte, Nicola Demitri, and Zdeněk Dolníček
Eur. J. Mineral., 36, 1011–1022, https://doi.org/10.5194/ejm-36-1011-2024, https://doi.org/10.5194/ejm-36-1011-2024, 2024
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Nannoniite, Al2(OH)5F, is a new mineral species discovered in the Cetine di Cotorniano mine (Tuscany, Italy). Its description was possible through a multi-technique approach, and its crystal structure was solved through three-dimensional electron diffraction, revealing close relations with gibbsite. The partial replacement of (OH) by F induces subtle by detectable structural changes. This study reveals that Al hydroxides could be a source of F in geological environments.
Cristian Biagioni, Anatoly V. Kasatkin, Fabrizio Nestola, Radek Škoda, Vladislav V. Gurzhiy, Atali A. Agakhanov, and Natalia N. Koshlyakova
Eur. J. Mineral., 36, 529–540, https://doi.org/10.5194/ejm-36-529-2024, https://doi.org/10.5194/ejm-36-529-2024, 2024
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Zvěstovite-(Fe) is a new, Ag-rich, member of the tetrahedrite group, the most widespread sulfosalts in ore deposits. Its discovery stresses the chemical variability of this mineral group, allowing for a better understanding of the structural plasticity of these compounds, which are able to host a plethora of different elements typical of hydrothermal environments.
Jonas Toupal, Daniela Mauro, Cristian Biagioni, Federica Zaccarini, and Reto Gieré
Eur. J. Mineral., 36, 1–10, https://doi.org/10.5194/ejm-36-1-2024, https://doi.org/10.5194/ejm-36-1-2024, 2024
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In this work, we refine the crystal structure of childrenite. Additionally, we provide compositional data to substantially extend the published solid-solution series between childrenite and eosphorite, the Fe and Mn endmembers, respectively. We analyze the valence state of iron to avoid erroneous classification of ernstite or potential discovery of "oxychildrenite", a mineral species not yet confirmed to be stable in nature.
Jiří Sejkora, Cristian Biagioni, Pavel Škácha, Silvia Musetti, Anatoly V. Kasatkin, and Fabrizio Nestola
Eur. J. Mineral., 35, 897–907, https://doi.org/10.5194/ejm-35-897-2023, https://doi.org/10.5194/ejm-35-897-2023, 2023
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We present the description of new mineral – a Cd-dominant member of the tetrahedrite group, tetrahedrite-(Cd), from the Radětice deposit near Příbram, Czech Republic. All necessary data including crystal structure were successfully determined, and the mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (number 2022-115).
Daniela Mauro, Cristian Biagioni, Jiří Sejkora, Zdeněk Dolníček, and Radek Škoda
Eur. J. Mineral., 35, 703–714, https://doi.org/10.5194/ejm-35-703-2023, https://doi.org/10.5194/ejm-35-703-2023, 2023
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Batoniite is a new mineral species belonging to the Al2O3–SO3–H2O ternary system, first found in the Cetine di Cotorniano Mine (Tuscany, Italy). This hydrated Al sulfate shows a novel crystal structure, characterized by Al octamers, so far reported in only synthetic compounds.
Cristian Biagioni, Marco E. Ciriotti, Georges Favreau, Daniela Mauro, and Federica Zaccarini
Eur. J. Mineral., 34, 365–374, https://doi.org/10.5194/ejm-34-365-2022, https://doi.org/10.5194/ejm-34-365-2022, 2022
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The paper reports the type description of the new mineral species graulichite-(La). This is a new addition to the dussertite group within the alunite supergroup, and its discovery improves our knowledge on the crystal chemistry of this important supergroup of minerals, having both technological and environmental applications.
Daniela Mauro, Cristian Biagioni, and Federica Zaccarini
Eur. J. Mineral., 33, 717–726, https://doi.org/10.5194/ejm-33-717-2021, https://doi.org/10.5194/ejm-33-717-2021, 2021
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This work reports the full crystal-chemical characterization of gersdorffite from Contrada Zillì (Peloritani Mountains, Sicily, Italy). The structural type shown by gersdorffite (ordered polytype 213) and its chemistry agree with low-temperature crystallization conditions. Moreover, the chemical zoning of the studied crystals recorded changes in the crystallization physicochemical conditions. This zoning may be due to a multistage crystallization, related to the evolution of the ore deposits.
Yves Moëlo and Cristian Biagioni
Eur. J. Mineral., 32, 623–635, https://doi.org/10.5194/ejm-32-623-2020, https://doi.org/10.5194/ejm-32-623-2020, 2020
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The plagionite group is a family of complex sulfides (
lead-antimony sulfosalts) encountered in various Pb-Cu-Zn ore deposits. Analysis of these crystal structures confirms a systematic Pb-versus-Sb substitution in two adjacent cation positions. Such a substitution varies according not only to the Pb / Sb ratio of each member but also, apparently, to the kinetics of crystallization. Re-examination of a Pb-free synthetic derivative permitted its redefinition as a Na-Sb sulfosalt.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 37, 549–553, https://doi.org/10.5194/ejm-37-549-2025, https://doi.org/10.5194/ejm-37-549-2025, 2025
Ferdinando Bosi, Federico Pezzotta, Henrik Skobgy, Riccardo Luppi, Paolo Ballirano, Ulf Hålenius, Gioacchino Tempesta, Giovanna Agrosì, and Jiří Sejkora
Eur. J. Mineral., 37, 505–516, https://doi.org/10.5194/ejm-37-505-2025, https://doi.org/10.5194/ejm-37-505-2025, 2025
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This study describes the elbaite neotype, found in crystals from a site on Elba island, Italy. Researchers analyzed these nearly colorless crystals and found that their formation was influenced by earlier changes in the surrounding rock. As different minerals formed first, they set the stage for elbaite to develop later in deeper spaces. This work helps us understand how changes in the local environment affect how and when certain minerals grow.
Giuseppe Illuminati, Silvia Musetti, Fabio Bellatreccia, Cristian Biagioni, Enrico Caprilli, Ahmad Rabiee, and Marco E. Ciriotti
Eur. J. Mineral., 37, 483–504, https://doi.org/10.5194/ejm-37-483-2025, https://doi.org/10.5194/ejm-37-483-2025, 2025
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In this work, we present the most iron-rich chrysoberyl discovered to date, found in the Sabatini Volcanic Complex (Latium, Italy). We provide a comprehensive overview of its chemical, structural, spectroscopic, and optical properties. The characterization of this chrysoberyl reveals several unique features, offering valuable insights into its genetic model and geochemical constraints, which are consistent with existing literature on the Sabatini complex and with ongoing research.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 37, 337–342, https://doi.org/10.5194/ejm-37-337-2025, https://doi.org/10.5194/ejm-37-337-2025, 2025
Cristian Biagioni, Jiří Sejkora, Yves Moëlo, Georges Favreau, Vincent Bourgoin, Jean-Claude Boulliard, Elena Bonaccorsi, Daniela Mauro, Silvia Musetti, Marco Pasero, Natale Perchiazzi, and Jana Ulmanová
Eur. J. Mineral., 37, 319–335, https://doi.org/10.5194/ejm-37-319-2025, https://doi.org/10.5194/ejm-37-319-2025, 2025
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Ginelfite is a new Ag–Fe–Tl–Pb sulfosalt described from the hydrothermal deposit of Jas Roux (France). It belongs to the so-called boxwork sulfosalts, a group of species showing the highest structural complexity among this group of chalcogenides. This very complex structure is probably stabilized by the occurrence of minor chemical constituents (Tl, Fe) occupying specific structural positions.
Erik Jonsson, Ulf Hålenius, Jaroslaw Majka, and Ferdinando Bosi
Eur. J. Mineral., 37, 269–277, https://doi.org/10.5194/ejm-37-269-2025, https://doi.org/10.5194/ejm-37-269-2025, 2025
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Skogbyite, with the chemical formula Zr(Mg2+2Mn3+4)SiO12, is a new species in the braunite group of minerals. It was discovered in a complex mineral assemblage, essentially a very poor manganese ore, from the Långban Fe–Mn oxide deposit, Värmland County, Bergslagen ore province, Sweden. It is named after the Swedish mineralogist Henrik Skogby (b. 1956). It is a new mineral attesting to the localised mobility and reactivity of zirconium under very special geological conditions.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 37, 249–255, https://doi.org/10.5194/ejm-37-249-2025, https://doi.org/10.5194/ejm-37-249-2025, 2025
Dan Holtstam, Fernando Cámara, Henrik Skogby, Andreas Karlsson, and Alessandro De Leo
Eur. J. Mineral., 37, 221–231, https://doi.org/10.5194/ejm-37-221-2025, https://doi.org/10.5194/ejm-37-221-2025, 2025
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The mineral clino-ferro-suenoite, with the chemical formula ◻Mn2Fe2+5Si8O22(OH)2, was historically named “dannemorite” or “manganogrunerite” and is a member of the amphibole supergroup. It is now formally approved by the International Mineralogical Association. It occurs in iron–manganese-bearing rock from the Hilläng mines, Dalarna, Sweden, and is associated with the minerals fayalite, spessartine, ferro-actinolite, calcite, magnetite and pyrite. It formed by replacement of Mn-bearing fayalite.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 37, 75–78, https://doi.org/10.5194/ejm-37-75-2025, https://doi.org/10.5194/ejm-37-75-2025, 2025
Cristian Biagioni, Daniela Mauro, Jiří Sejkora, Zdeněk Dolníček, Andrea Dini, and Radek Škoda
Eur. J. Mineral., 37, 39–52, https://doi.org/10.5194/ejm-37-39-2025, https://doi.org/10.5194/ejm-37-39-2025, 2025
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Dacostaite is a new fluoride–arsenate mineral found in the Sb(Au) deposit of the Cetine di Cotorniano Mine (Tuscany, Italy). It shows a novel crystal structure formed by heteropolyhedral layers and isolated Mg(H2O)6 groups connected by H bonds. The heteropolyhedral layers are similar to those occurring in alunite-supergroup minerals, and this is a further example of the ability of nature to use similar modules in forming the large number of currently known structural arrangements.
Giovanni B. Andreozzi, Claudia Gori, Henrik Skogby, Ulf Hålenius, Alessandra Altieri, and Ferdinando Bosi
Eur. J. Mineral., 37, 1–12, https://doi.org/10.5194/ejm-37-1-2025, https://doi.org/10.5194/ejm-37-1-2025, 2025
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The compositional variation in a multi-coloured, zoned tourmaline from the Cruzeiro pegmatite, Brazil, reflects melt chemical evolution during the entire pegmatite differentiation. In uncontaminated granitic pegmatite systems such as that of Cruzeiro, the compositional evolution of tourmaline progresses from schorl to fluor-elbaite, rather than directly from schorl to elbaite, to reflect co-enrichment in Li and F during fractional crystallization.
Cristian Biagioni, Enrico Mugnaioli, Sofia Lorenzon, Daniela Mauro, Silvia Musetti, Jiří Sejkora, Donato Belmonte, Nicola Demitri, and Zdeněk Dolníček
Eur. J. Mineral., 36, 1011–1022, https://doi.org/10.5194/ejm-36-1011-2024, https://doi.org/10.5194/ejm-36-1011-2024, 2024
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Nannoniite, Al2(OH)5F, is a new mineral species discovered in the Cetine di Cotorniano mine (Tuscany, Italy). Its description was possible through a multi-technique approach, and its crystal structure was solved through three-dimensional electron diffraction, revealing close relations with gibbsite. The partial replacement of (OH) by F induces subtle by detectable structural changes. This study reveals that Al hydroxides could be a source of F in geological environments.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 36, 1005–1010, https://doi.org/10.5194/ejm-36-1005-2024, https://doi.org/10.5194/ejm-36-1005-2024, 2024
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 36, 917–923, https://doi.org/10.5194/ejm-36-917-2024, https://doi.org/10.5194/ejm-36-917-2024, 2024
Beatrice Celata, Ferdinando Bosi, Kira A. Musiyachenko, Andrey V. Korsakov, and Giovanni B. Andreozzi
Eur. J. Mineral., 36, 797–811, https://doi.org/10.5194/ejm-36-797-2024, https://doi.org/10.5194/ejm-36-797-2024, 2024
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The discovery of the K-dominant tourmaline maruyamaite with microdiamond inclusions suggested its ultrahigh-pressure formation. We analyzed the role of K in the tourmaline structure, with a special focus on its stability. High pressure is necessary to squeeze the large cation K+ in the stiff framework of tourmaline, although K is the underdog component if Na+ is present in the mineralizing fluid. K-tourmaline is stable at high pressure, overcoming the stereotype of a mere crustal component.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 36, 599–604, https://doi.org/10.5194/ejm-36-599-2024, https://doi.org/10.5194/ejm-36-599-2024, 2024
Cristian Biagioni, Anatoly V. Kasatkin, Fabrizio Nestola, Radek Škoda, Vladislav V. Gurzhiy, Atali A. Agakhanov, and Natalia N. Koshlyakova
Eur. J. Mineral., 36, 529–540, https://doi.org/10.5194/ejm-36-529-2024, https://doi.org/10.5194/ejm-36-529-2024, 2024
Short summary
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Zvěstovite-(Fe) is a new, Ag-rich, member of the tetrahedrite group, the most widespread sulfosalts in ore deposits. Its discovery stresses the chemical variability of this mineral group, allowing for a better understanding of the structural plasticity of these compounds, which are able to host a plethora of different elements typical of hydrothermal environments.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 36, 525–528, https://doi.org/10.5194/ejm-36-525-2024, https://doi.org/10.5194/ejm-36-525-2024, 2024
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 36, 361–367, https://doi.org/10.5194/ejm-36-361-2024, https://doi.org/10.5194/ejm-36-361-2024, 2024
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 36, 165–172, https://doi.org/10.5194/ejm-36-165-2024, https://doi.org/10.5194/ejm-36-165-2024, 2024
Jonas Toupal, Daniela Mauro, Cristian Biagioni, Federica Zaccarini, and Reto Gieré
Eur. J. Mineral., 36, 1–10, https://doi.org/10.5194/ejm-36-1-2024, https://doi.org/10.5194/ejm-36-1-2024, 2024
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In this work, we refine the crystal structure of childrenite. Additionally, we provide compositional data to substantially extend the published solid-solution series between childrenite and eosphorite, the Fe and Mn endmembers, respectively. We analyze the valence state of iron to avoid erroneous classification of ernstite or potential discovery of "oxychildrenite", a mineral species not yet confirmed to be stable in nature.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 35, 1073–1078, https://doi.org/10.5194/ejm-35-1073-2023, https://doi.org/10.5194/ejm-35-1073-2023, 2023
Daniel Atencio, Andrezza A. Azzi, Kai Qu, Ritsuro Miyawaki, Ferdinando Bosi, and Koichi Momma
Eur. J. Mineral., 35, 1027–1030, https://doi.org/10.5194/ejm-35-1027-2023, https://doi.org/10.5194/ejm-35-1027-2023, 2023
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This article introduces a new nomenclature system for the cerite group minerals. This system was necessary to allow the nomenclature of new species of minerals that are currently being described.
Jiří Sejkora, Cristian Biagioni, Pavel Škácha, Silvia Musetti, Anatoly V. Kasatkin, and Fabrizio Nestola
Eur. J. Mineral., 35, 897–907, https://doi.org/10.5194/ejm-35-897-2023, https://doi.org/10.5194/ejm-35-897-2023, 2023
Short summary
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We present the description of new mineral – a Cd-dominant member of the tetrahedrite group, tetrahedrite-(Cd), from the Radětice deposit near Příbram, Czech Republic. All necessary data including crystal structure were successfully determined, and the mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (number 2022-115).
Ian E. Grey, Stephanie Boer, Colin M. MacRae, Nicholas C. Wilson, William G. Mumme, and Ferdinando Bosi
Eur. J. Mineral., 35, 909–919, https://doi.org/10.5194/ejm-35-909-2023, https://doi.org/10.5194/ejm-35-909-2023, 2023
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The paper describes the formal establishment of the paulkerrite group of minerals and its nomenclature. It includes the application of a site-merging procedure, coupled with a site-total-charge analysis, to obtain unambiguous end-member formulae. Application of the procedure has resulted in the revision of the end-member formulae for several of the group members.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 35, 891–895, https://doi.org/10.5194/ejm-35-891-2023, https://doi.org/10.5194/ejm-35-891-2023, 2023
Alessandra Altieri, Federico Pezzotta, Giovanni B. Andreozzi, Henrik Skogby, and Ferdinando Bosi
Eur. J. Mineral., 35, 755–771, https://doi.org/10.5194/ejm-35-755-2023, https://doi.org/10.5194/ejm-35-755-2023, 2023
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Elba tourmaline crystals commonly display a sharp transition to dark colors at the analogous termination, but the mechanisms leading to the formation of such terminations are unclear. Here we propose a general genetic model in which, as a consequence of a pocket rupture event, chemical alteration of early formed Fe-/Mn-rich minerals in the enclosing pegmatite was responsible for the release of Fe and/or Mn in the geochemical system, allowing the formation of the late-stage dark terminations.
Daniela Mauro, Cristian Biagioni, Jiří Sejkora, Zdeněk Dolníček, and Radek Škoda
Eur. J. Mineral., 35, 703–714, https://doi.org/10.5194/ejm-35-703-2023, https://doi.org/10.5194/ejm-35-703-2023, 2023
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Batoniite is a new mineral species belonging to the Al2O3–SO3–H2O ternary system, first found in the Cetine di Cotorniano Mine (Tuscany, Italy). This hydrated Al sulfate shows a novel crystal structure, characterized by Al octamers, so far reported in only synthetic compounds.
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 35, 659–664, https://doi.org/10.5194/ejm-35-659-2023, https://doi.org/10.5194/ejm-35-659-2023, 2023
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 35, 397–402, https://doi.org/10.5194/ejm-35-397-2023, https://doi.org/10.5194/ejm-35-397-2023, 2023
Ferdinando Bosi, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 35, 285–293, https://doi.org/10.5194/ejm-35-285-2023, https://doi.org/10.5194/ejm-35-285-2023, 2023
Ferdinando Bosi, Ritsuro Miyawaki, Frédéric Hatert, Marco Pasero, and Stuart J. Mills
Eur. J. Mineral., 35, 75–79, https://doi.org/10.5194/ejm-35-75-2023, https://doi.org/10.5194/ejm-35-75-2023, 2023
Dan Holtstam, Fernando Cámara, Andreas Karlsson, Henrik Skogby, and Thomas Zack
Eur. J. Mineral., 34, 451–462, https://doi.org/10.5194/ejm-34-451-2022, https://doi.org/10.5194/ejm-34-451-2022, 2022
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A new mineral has been discovered, an amphibole, with the name ferri-taramite, which has now been approved by the International Mineralogical Association. The paper discusses the significance of the discovery in relation to other amphiboles found worldwide. This taramite is unique in that it is from a skarn associated with ore and is not of magmatic origin. For the description we have used many methods, including X-ray diffraction, chemical analyses and several types of spectroscopy.
Cristian Biagioni, Marco E. Ciriotti, Georges Favreau, Daniela Mauro, and Federica Zaccarini
Eur. J. Mineral., 34, 365–374, https://doi.org/10.5194/ejm-34-365-2022, https://doi.org/10.5194/ejm-34-365-2022, 2022
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The paper reports the type description of the new mineral species graulichite-(La). This is a new addition to the dussertite group within the alunite supergroup, and its discovery improves our knowledge on the crystal chemistry of this important supergroup of minerals, having both technological and environmental applications.
Daniela Mauro, Cristian Biagioni, and Federica Zaccarini
Eur. J. Mineral., 33, 717–726, https://doi.org/10.5194/ejm-33-717-2021, https://doi.org/10.5194/ejm-33-717-2021, 2021
Short summary
Short summary
This work reports the full crystal-chemical characterization of gersdorffite from Contrada Zillì (Peloritani Mountains, Sicily, Italy). The structural type shown by gersdorffite (ordered polytype 213) and its chemistry agree with low-temperature crystallization conditions. Moreover, the chemical zoning of the studied crystals recorded changes in the crystallization physicochemical conditions. This zoning may be due to a multistage crystallization, related to the evolution of the ore deposits.
Yves Moëlo and Cristian Biagioni
Eur. J. Mineral., 32, 623–635, https://doi.org/10.5194/ejm-32-623-2020, https://doi.org/10.5194/ejm-32-623-2020, 2020
Short summary
Short summary
The plagionite group is a family of complex sulfides (
lead-antimony sulfosalts) encountered in various Pb-Cu-Zn ore deposits. Analysis of these crystal structures confirms a systematic Pb-versus-Sb substitution in two adjacent cation positions. Such a substitution varies according not only to the Pb / Sb ratio of each member but also, apparently, to the kinetics of crystallization. Re-examination of a Pb-free synthetic derivative permitted its redefinition as a Na-Sb sulfosalt.
Cited articles
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Short summary
Dutrowite is the first tourmaline supergroup minerals having Ti as a species-defining chemical constituent. Its finding improves our knowledge on the crystal chemistry of this important mineral group and allows us to achieve a better picture of the mechanisms favouring the incorporation of Ti.
Dutrowite is the first tourmaline supergroup minerals having Ti as a species-defining chemical...