Articles | Volume 37, issue 6
https://doi.org/10.5194/ejm-37-889-2025
https://doi.org/10.5194/ejm-37-889-2025
Research article
 | 
01 Dec 2025
Research article |  | 01 Dec 2025

Empirical electronic polarizabilities of iodine (I) and bromine (Br, Br7+) for the prediction of refractive indices

Shaghayegh Nezamabadi, Patrick A. Fuzon, Florian Kraus, and Reinhard X. Fischer

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Short summary
We conducted experimental and computational studies, compiling datasets of compounds with established refractive indices and supplementing them with our measurements of compounds containing I⁻, Br⁻, or Br7+. We calculated the electronic polarizabilities of these ions to estimate the mean refractive index of I- and Br-containing compounds. Results were compared to the Gladstone–Dale approach, confirming their reliability in predicting optical properties.
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