Articles | Volume 38, issue 5
https://doi.org/10.5194/ejm-38-583-2026
https://doi.org/10.5194/ejm-38-583-2026
Research article
 | 
15 Oct 2026
Research article |  | 15 Oct 2026

New methods for Fourier transform infrared spectroscopy investigation and quantification of OH absorption in anisotropic nominally anhydrous minerals: the example of pyroxene

Nils B. Gies, Jörg Hermann, Georgia Cametti, and Sonja Aulbach

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Cited articles

Andrut, M., Wildner, M., Ingrin, J., and Beran, A.: Mechanisms of OH defect incorporation in naturally occurring, hydrothermally formed diopside and jadeite, Phys. Chem. Miner., 34, 543–549, https://doi.org/10.1007/s00269-007-0169-3, 2007. 
Asimow, P. D., Stein, L. C., Mosenfelder, J. L., and Rossman, G. R.: Quantitative polarized infrared analysis of trace OH in populations of randomly oriented mineral grains, Am. Mineral., 91, https://doi.org/10.2138/am.2006.1937, 2006. 
Aulbach, S., Höfer, H. E., and Gerdes, A.: High-Mg and Low-Mg Mantle eclogites from Koidu (West African Craton) linked by neoproterozoic ultramafic melt metasomatism of subducted archaean plateau-like oceanic crust, J. Petrol., 60, https://doi.org/10.1093/petrology/egz011, 2019. 
Aulbach, S., Stalder, R., Massuyeau, M., Stern, R. A., Ionov, D. A., and Korsakov, A. v.: Water in Omphacite and Garnet From Pristine Xenolithic Eclogite: T-X-fO2 Controls, Retentivity, and Implications for Electrical Conductivity and Deep H2O Recycling, Geochem. Geophy. Geosy., 24, https://doi.org/10.1029/2023GC011170, 2023. 
Aulbach, S., Gies, N. B., Linckens, J., Stalder, R., and Viljoen, F.: Inhibited hydrogen uptake in metasomatised cratonic eclogite, Contrib. Mineral. Petr., 179, 77, https://doi.org/10.1007/s00410-024-02157-6, 2024. 
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Short summary
This study presents new methods for enhancing Fourier transform infrared spectroscopy (FTIR) measurements to analyse the OH absorbance of anisotropic minerals. With new hardware and software solutions, large numbers of angle-resolved polarised spectra between 0 to 180° can be acquired, processed, and visualised. This allows us to identify spectral endmembers in the Si–O overtone region that can be used to find groups of mutually perpendicular spectra reducing uncertainty of H2O quantification.
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