European Journal of Mineralogy
European Journal of Mineralogy
European Journal of Mineralogy
Articles | Volume 34, issue 6
Articles | Volume 34, issue 6
https://doi.org/10.5194/ejm-34-573-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/ejm-34-573-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 34, issue 6
Research article
 | 
09 Dec 2022
Research article |  | 09 Dec 2022

Non-destructive determination of the biotite crystal chemistry using Raman spectroscopy: how far we can go?

Stylianos Aspiotis, Jochen Schlüter, Günther J. Redhammer, and Boriana Mihailova

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Latest update: 23 Apr 2025
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Short summary
Combined Raman-scattering and wavelength-dispersive electron microprobe (WD-EMP) analyses of natural biotites expanding over the whole biotite solid-solution series demonstrate that the chemical composition of the MO6 octahedra, TO4 tetrahedra, and interlayer space can be non-destructively determined by Raman spectroscopy with relative uncertainties below 8 %. The content of critical minor elements such as Ti at the octahedral site can be quantified as well with a relative error of ~ 20 %.
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