Articles | Volume 38, issue 5
https://doi.org/10.5194/ejm-38-635-2026
https://doi.org/10.5194/ejm-38-635-2026
Research article
 | 
20 Oct 2026
Research article |  | 20 Oct 2026

Experimental constraints on the stability of Mg-rich tourmaline and the boron concentration of hydrothermal fluids

Julien Fort, Stanislas Sizaret, Michel Pichavant, Arnault Lassin, Johann Tuduri, and Olivier Blein

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Cited articles

Acosta-Vigil, A., London, D., Morgan, G. B., and Dewers, T. A.: Solubility of excess alumina in hydrous granitic melts in equilibrium with peraluminous minerals at 700–800 °C and 200 MPa, and applications of the aluminum saturation index, Contrib. Mineral. Petrol., 146, 100–119, https://doi.org/10.1007/s00410-003-0486-6, 2003. 
Akinfiev, N. N., Voronin, M. V., Zotov, A. V., and Prokof'ev, V. Yu.: Experimental investigation of the stability of a chloroborate complex and thermodynamic description of aqueous species in the B-Na-Cl-O-H system up to 350 °C, Geochem. Int., 44, 867–878, https://doi.org/10.1134/S0016702906090035, 2006. 
Audétat, A., Günther, D., and Heinrich, C. A.: Causes for Large-Scale Metal Zonation around Mineralized Plutons: Fluid Inclusion LA-ICP-MS Evidence from the Mole Granite, Australia, Econ. Geol., 95, 1563–1581, https://doi.org/10.2113/gsecongeo.95.8.1563, 2000. 
Audétat, A., Pettke, T., Heinrich, C. A., and Bodnar, R. J.: Special Paper: The Composition of Magmatic-Hydrothermal Fluids in Barren and Mineralized Intrusions, Econ. Geol., 103, 877–908, https://doi.org/10.2113/gsecongeo.103.5.877, 2008. 
Bačík, P., Dikej, J., Fridrichová, J., Miglierini, M., and Števko, M.: Chemical composition and evolution of tourmaline-supergroup minerals from the Sb hydrothermal veins in Rožňava area, Western Carpathians, Slovakia, Mineral. Petrol., 111, 609–624, https://doi.org/10.1007/s00710-017-0507-1, 2017. 
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Short summary
This experimental study determines the minimum boron concentrations required to form tourmaline under hydrothermal conditions. Results show that temperature influences boron thresholds going from 2 wt % at 400 °C to 3.4 wt % B2O3 at 600 °C. Thermodynamic models are able to reproduce the same behavior, but the values show a mismatch if not refined to account for the chemistry of the experimental results. Those new constrains are of great help in predicting natural fluid–rock interactions and ore deposit formation.
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