Articles | Volume 36, issue 1
https://doi.org/10.5194/ejm-36-139-2024
https://doi.org/10.5194/ejm-36-139-2024
Research article
 | 
29 Jan 2024
Research article |  | 29 Jan 2024

Synthesis of jadarite in the Li2O–Na2O–B2O3–SiO2–NaCl–H2O system: FTIR, Raman, and Li and B K-edge XANES characterizations and theoretical calculations

Xiu-Zhen Xie, Huiyao Kuang, Eli Wiens, Reza Deevsalar, Ayetullah Tunc, Sarah Purdy, Lucia Zuin, John S. Tse, Jin-Xiao Mi, and Yuanming Pan

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Cited articles

Borojević Šoštarić, S. and Brenko, T.: The Miocene Western Balkan lithium-boron metallogenic zone, Mineral. Deposita, 58, 639–658, https://doi.org/10.1007/s00126-022-01151-x, 2023. 
Comboni, D., Battiston, T., Rumsey, M. S., Pagliaro, F., Lotti, P., Hanfland, M., and Gatta, D.: High-pressure behavior and phase transition of jadarite, a promising B and Li mineral commodity, J. Am. Ceram. Soc., 105, 7011–7021, https://doi.org/10.1111/jace.18659, 2022. 
Derkacheva, E. S., Krzhizhanovskaya, M. G., and Bubnova, R. S.: Thermal behavior of reedmergnerite NaBSi3O8 and searlesite NaBSi2O5(OH)2, Glass. Phys. Chem., 43, 459–463, https://doi.org/10.1134/S1087659617050030, 2017. 
Fleet, M. E. and Liu, X.: Boron K-edge XANES of boron oxides: tetrahedral B–O distances and near-surface alteration, Phys. Chem. Miner., 28, 421–427, https://doi.org/10.1007/s002690100173, 2001. 
Fleet, M. E. and Muthupari, S.: Boron K-edge XANES of borate and borosilicate minerals, Am. Mineral., 85, 1009–1021, https://doi.org/10.2138/am-2000-0716, 2000. 
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Short summary
This is the first successful synthesis of jadarite, a Li–B ore mineral. Synthetic jadarite was characterized by powder X-ray diffraction, Fourier transform infrared, Raman, and Li and B K-edge X-ray absorption near-edge structure. The results are evaluated by first-principles theoretical calculations. Our findings for jadarite in sediments derived from Li-rich alkaline brines under high-temperature diagenetic conditions have implications in the search for new Li–B deposits in sedimentary basins.