Articles | Volume 38, issue 2
https://doi.org/10.5194/ejm-38-103-2026
https://doi.org/10.5194/ejm-38-103-2026
Research article
 | 
05 Mar 2026
Research article |  | 05 Mar 2026

Hydrogen diffusion in hydrous minerals from Raman and NanoSIMS mapping – implications for isotopic characterization of fluid–rock interactions

Bruno Reynard, Jannick Ingrin, Anne-Céline Ganzhorn, Julie Jonfal, Hélène Pilorgé, Clémentine Fellah, Nadège Hilairet, and Laurent Remusat

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Cited articles

Amiguet, E., Reynard, B., Caracas, R., Van de Moortèle, B., Hilairet, N., and Wang, Y.: Creep of phyllosilicates at the onset of plate tectonics, Earth and Planetary Science Letters, 345–348, 142–150, https://doi.org/10.1016/j.epsl.2012.06.033, 2012. 
Amiguet, E., van de Moortèle, B., Cordier, P., Hilairet, N., and Reynard, B.: Deformation mechanisms and rheology of serpentines in experiments and in nature, Journal of Geophysical Research, 119, https://doi.org/10.1002/2013JB010791, 2014. 
Bebout, G. E. and Penniston-Dorland, S. C.: Fluid and mass transfer at subduction interfaces – The field metamorphic record, Lithos, 240–243, 228–258, https://doi.org/10.1016/j.lithos.2015.10.007, 2016. 
Biermann, C. and Van Roermund, H. L. M.: Defect structures in naturally deformed clinoamphiboles – a TEM study, Tectonophysics, 95, 267–278, https://doi.org/10.1016/0040-1951(83)90072-0, 1983. 
Bosi, F.: Tourmaline crystal chemistry, American Mineralogist, 103, 298–306, https://doi.org/10.2138/am-2018-6289, 2018. 
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Short summary
Interactions between minerals and water are fundamental to many geological processes on Earth, in meteorites, and on other planetary bodies, for instance, in the development of plate tectonics. In this study, we experimentally determine how quickly hydrogen isotopes are exchanged between minerals and fluids. We then explore how exchange rates can inform us about past interactions between rocks and water on the Earth and in meteorites using hydrogen isotope measurements in natural minerals.
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